An investigation into catalysts to improve the low temperature performance of an SCR

Selective catalytic reduction with NH3 is considered as one of the most effective technologies controlling NOx emission. Metal Fe based catalysts were used in the investigation to improve the low temperature performance of NOx conversion. The temperature range studied was between 150 degrees C and 350 degrees C with the interval of 50 degrees C. The honeycomb catalysts were prepared by an impregnation method. The study also included characterization of catalysts by BET, XRD, H2-TPR, SEM and XPS methods. It is found an increase in metal Fe content from 2 to 6 % wt. offers an improvement in the catalytic performance. However, a further increment in Fe content will result in a decrease in its performance. More than 90 % NOx conversion rate could be achieved over the Fe-based honeycomb catalyst at a low temperature by doping with Ni and Zr metal with different weights. Among all the catalysts studied, the mixed metal catalyst of Fe-Ni-Zr is found the most potential one, not only because of its higher NOx conversion rate at a low temperature, but also because of its wider operation temperature window. The effect of gas hourly space velocity (GHSV) was also investigated in the study and results show as GHSV increases that reduction of NOx is decreased

The c-differential properties of a class of power functions

Power functions with low $c$-differential uniformity have been widely studied not only because of their strong resistance to multiplicative differential attacks, but also low implementation cost in hardware. Furthermore, the $c$-differential spectrum of a function gives a more precise characterization of its $c$-differential properties. Let $f(x)=x^{\frac{p^n+3}{2}}$ be a power function over the finite field $\mathbb{F}_{p^{n}}$, where $p\neq3$ is an odd prime and $n$ is a positive integer. In this paper, for all primes $p\neq3$, by investigating certain character sums with regard to elliptic curves and computing the number of solutions of a system of equations over $\mathbb{F}_{p^{n}}$, we determine explicitly the $(-1)$-differential spectrum of $f$ with a unified approach. We show that if $p^n \equiv 3 \pmod 4$, then $f$ is a differentially $(-1,3)$-uniform function except for $p^n\in\{7,19,23\}$ where $f$ is an APcN function, and if $p^n \equiv 1 \pmod 4$, the $(-1)$-differential uniformity of $f$ is equal to $4$. In addition, an upper bound of the $c$-differential uniformity of $f$ is also given

A novel HVDC circuit breaker for HVDC application

Hybrid high voltage direct current circuit breakers (DCCBs) are capable of interrupting fault current within a few milliseconds, but this technology has high capital cost, especially in a meshed HVDC grid. To increase the economic competitiveness of hybrid DCCBs, this paper proposes a capacitor commutated dc circuit breaker (CCCB). The CCCB mainly comprises an auxiliary branch with a fast dis-connector in series with semiconductor devices and the main branch with the series connection of a dc capacitor and diode valves. This paper provides a detailed depiction of the CCCB. The topology and operating principles are discussed. The impact of snubber circuits and stray inductances on the commutation process is analyzed. The general sizing method for the main components in the CCCB is detailed. Reclosing to transmission lines with different operating conditions is studied. Several extended topologies are proposed to further reduce the semiconductor cost and on-state operation power loss. The power loss and cost of CCCB are assessed. Extensive simulations on PSCAD/EMTDC verified the dc fault isolation and reclosing of the CCCB

A single-end protection scheme for hybrid MMC HVDC grids considering the impacts of the active fault current-limiting control

In the hybrid modular multilevel converter (MMC) based high voltage direct current (HVDC) systems, the fault current can be actively suppressed by the converter itself, which endows a smaller requirement for current-limiting reactors (CLR) and a larger time margin for fault detection algorithms, comparing with the half-bridge MMC. But the robustness to fault resistance and noise disturbance of existing boundary protection schemes will be deteriorated with small CLRs. Moreover, the fast response of the fault current-limiting control will change the output DC voltage of hybrid MMC, which affects the fault characteristics and may cause mal-operation of existing protection algorithms. Thus, a single-end protection scheme considering the impacts of the active current-limiting control is proposed for the hybrid MMC based DC grids. The traveling-wave characteristics under different fault stages are analyzed to evaluate the impacts of the fault current-limiting control. In addition, a coordination protection strategy versus different fault conditions is adopted to improve reliability. Various cases in PSCAD/EMTDC are simulated to verify that the proposed method is robust to fault resistance, fault distance, power reversal, AC faults, and immune to noise

pH-sensitive polymeric micelles triggered drug release for extracellular and intracellular drug targeting delivery

AbstractMost of the conventional chemotherapeutic agents used for cancer chemotherapy suffer from multidrug resistance of tumor cells and poor antitumor efficacy. Based on physiological differences between the normal tissue and the tumor tissue, one effective approach to improve the efficacy of cancer chemotherapy is to develop pH-sensitive polymeric micellar delivery systems. The copolymers with reversible protonation–deprotonation core units or acid-liable bonds between the therapeutic agents and the micelle-forming copolymers can be used to form pH-sensitive polymeric micelles for extracellular and intracellular drug smart release. These systems can be triggered to release drug in response to the slightly acidic extracellular fluids of tumor tissue after accumulation in tumor tissues via the enhanced permeability and retention effect, or they can be triggered to release drug in endosomes or lysosomes by pH-controlled micelle hydrolysis or dissociation after uptake by cells via the endocytic pathway. The pH-sensitive micelles have been proved the specific tumor cell targeting, enhanced cellular internalization, rapid drug release, and multidrug resistance reversal. The multifunctional polymeric micelles combining extracellular pH-sensitivity with receptor-mediated active targeting strategies are of great interest for enhanced tumor targeting. The micelles with receptor-mediated and intracellular pH targeting functions are internalized via receptor-mediated endocytosis followed by endosomal-pH triggered drug release inside the cells, which reverses multidrug resistance. The pH sensitivity strategy of the polymeric micelles facilitates the specific drug delivery with reduced systemic side effects and improved chemotherapeutical efficacy, and is a novel promising platform for tumor-targeting drug delivery

Four-leg converters with improved common current sharing and selective voltage-quality enhancement for islanded microgrids

Four-leg dc-ac power converters are widely used for the power grids to manage grid voltage unbalance caused by the interconnection of single-phase or three-phase unbalanced loads. These converters can further be connected in parallel to increase the overall power rating. The control of these converters poses a particular challenge if they are placed far apart with no links between them (e.g., in islanded microgrids). This challenge is studied in this paper with each four-leg converter designed to have improved common current sharing and selective voltage-quality enhancement. The common current sharing, including zero sequence component, is necessary since loads are spread over the microgrid and they are hence the common responsibility of all converters. The voltage-quality enhancement consideration should however be more selective since different loads have different sensitivity levels towards voltage disturbances. Converters connected to the more sensitive load buses should therefore be selectively triggered for compensation when voltage unbalances at their protected buses exceed the predefined thresholds. The proposed scheme is therefore different from conventional centralized schemes protecting only a common bus. Simulation and experimental results obtained have verified the effectiveness of the proposed scheme when applied to a four-wire islanded microgrid

Comparison of electromagnetic performance of scpm wind power generators with different topologies

This paper focuses on the comparison of electromagnetic performance of the superconducting permanent magnet (SCPM) generators with two different topologies. The torque capabilities of the two generators are first investigated. The peak torque is largely restricted by the material characteristics of the superconducting (SC) and the permanent magnet. The SCPM generators with iron-cored rotor and iron-cored stator topology (IRIST) is superior to the one with iron-cored rotor and air-cored stator topology in terms of torque capability. Furthermore, the flux density, line electromotive force, torque and its torque ripple, and the efficiency of the designed generators are evaluated by using numerical model. The simulation results confirm that IRIST has higher output torque and efficiency with the penalty of higher harmonics and torque ripples

Study on the mixing performance of static mixers in selective catalytic reduction (SCR) systems

Selective catalytic reduction (SCR) is a promising technique for reducing nitrogen oxide (NOx) emissions from diesel engines. Static mixers are widely used in SCR systems before reactors to promote the mixing of ammonia and exhaust streams. This work aims to investigate the effects of the location of static mixers and the volume ratio of two species on mixing quality using the computational fluid dynamics (CFD) method. The simulation results show that a more homogenous ammonia distribution can be achieved at the exit of the pipe if static mixers are placed close to the ammonia injection point or if more ammonia is injected. Another phenomenon found in the study is that the mixing performance of an identical static mixer may behave discrepantly under different flow conditions if using B and C as the evaluating indexes for mixing homogenization

An adaptive fault current limiting control for MMC and its application in DC grid

This paper proposes an adaptive fault current limiting control (AFCLC) for modular multilevel converters (MMC). Without introducing extra current limiting devices, this control scheme enables fast fault current suppression during DC faults. The AFCLC will be triggered automatically once DC faults occur. By adaptively reducing the output DC voltages of MMCs, the fault current can be suppressed. Compared with the existing current limiting methods, the proposed AFCLC has a better performance on fault current limiting, since it only depends on the real-time operating condition and no fault detection delay is imposed. Firstly, the principle of the proposed AFCLC together with the mathematical analysis is disclosed. Then, the sensitivity analysis of the impact of key control parameters on the current limiting effect is investigated. Finally, the effectiveness of AFCLC is demonstrated in a four-terminal HVDC grid test model. The simulation results show that the proposed AFCLC can reduce the interrupted current and energy absorption of a DCCB from 10.39 kA and 38.24 MJ to 4.62 kA and 8.32 MJ, respectively. The simulation results also prove that the AFCLC will not affect the accuracy of the DC fault detection algorithms under DC faults

Electrochemically Inert g-C3N4 Promotes Water Oxidation Catalysis

Electrode surface wettability is critically important for heterogeneous electrochemical reactions taking place in aqueous and nonaqueous media. Herein, electrochemically inert g-C 3 N 4 (GCN) is successfully demonstrated to significantly enhance water oxidation by constructing a superhydrophilic catalyst surface and promoting substantial exposure of active sites. As a proof-of-concept application, superhydrophilic GCN/Ni(OH) 2 (GCNN) hybrids with monodispersed Ni(OH) 2 nanoplates strongly anchored on GCN are synthesized for enhanced water oxidation catalysis. Owing to the superhydrophilicity of functionalized GCN, the surface wettability of GCNN (contact angle 0°) is substantially improved as compared with bare Ni(OH) 2 (contact angle 21°). Besides, GCN nanosheets can effectively suppress Ni(OH) 2 aggregation to help expose more active sites. Benefiting from the well-defined catalyst surface, the optimal GCNN hybrid shows significantly enhanced electrochemical performance over bare Ni(OH) 2 nanosheets, although GCN is electrochemically inert. In addition, similar catalytic performance promotion resulting from wettability improvement induced by incorporation of hydrophilic GCN is also successfully demonstrated on Co(OH) 2 . The present results demonstrate that, in addition to developing new catalysts, building efficient surface chemistry is also vital to achieve extraordinary water oxidation performance