2 research outputs found
Novel Technology for the Removal of Fe and Al from Spent Li-Ion Battery Leaching Solutions by a Precipitation–Complexation Process
The conventional neutralization method for removing impurities
Fe(III) and Al(III) from spent Li-ion battery (LIB) leaching solutions
has encountered problems of low impurity removal efficiency or high
loss of valuable metals. In this study, highly selective and effective
separation of Fe(III) and Al(III) from spent LIB leaching solutions
was achieved by the precipitation–complexation technology.
It was found that almost all Fe(III) together with most of the Al(III)
could be removed by preferential precipitation using NaHCO3 neutralization under an equilibrium pH of 3.3 at 95 °C. Phytic
acid, as a selectively complexing agent, was then introduced to completely
remove the residual Al(III) from Fe-removed solutions with an Al/PA
molar ratio of 3:1 at 60 °C. As a result, more than 99.5% Fe(III)
and 97.08% Al(III) could be removed from the actual solutions, with
a total loss of Ni, Co, Mn, and Li of only 1.1%. Furthermore, the
obtained Al-phytates could be decomposed to form Al(PO3)3 products at 1000 °C. The whole process not only
realized the efficient removal of Al(III) and Fe(III) at low pH with
minimal loss of Ni, Co, Mn, and Li but also reduced the emission of
wastes and utilized the Al resources
Polysaccharide-Based Composite Hydrogel with Hierarchical Microstructure for Enhanced Vascularization and Skull Regeneration
Critical-size skull defects caused by trauma, infection,
and tumor
resection raise great demands for efficient bone substitutes. Herein,
a hybrid cross-linked hierarchical microporous hydrogel scaffold (PHCLS)
was successfully assembled by a multistep procedure, which involved
(i) the preparation of poly(lactic-co-glycolic)/nanohydroxyapatite
(PLGA-HAP) porous microspheres, (ii) embedding the spheres in a solution
of dopamine-modified hyaluronic acid and collagen I (Col I) and cross-linking
via dopamine polyphenols binding to (i) Col I amino groups (via Michael
addition) and (ii) PLGA-HAP (via calcium ion chelation). The introduction
of PLGA-HAP not only improved the diversity of pore size and pore
communication inside the matrix but also greatly enhanced the compressive
strength (5.24-fold, 77.5 kPa) and degradation properties to construct
a more stable mechanical structure. In particular, the PHCLS (200
mg, nHAP) promoted the proliferation, infiltration, and angiogenic
differentiation of bone marrow mesenchymal stem cells in vitro, as
well as significant ectopic angiogenesis and mineralization with a
storage modulus enhancement of 2.5-fold after 30 days. Meanwhile,
the appropriate matrix microenvironment initiated angiogenesis and
early osteogenesis by accelerating endogenous stem cell recruitment
in situ. Together, the PHCLS allowed substantial skull reconstruction
in the rabbit cranial defect model, achieving 85.2% breaking load
strength and 84.5% bone volume fractions in comparison to the natural
cranium, 12 weeks after implantation. Overall, this study reveals
that the hierarchical microporous hydrogel scaffold provides a promising
strategy for skull defect treatment