Quantification of metallic copper and nickel in their binary mixtures by voltammetry of immobilized microparticles

We report the use of voltammetry of immobilized microparticles for the quantification of metallic copper and nickel in their binary mixtures. Twenty-two electrolytes were investigated in order to obtain well-separated oxidation peaks. An experimental design strategy was employed to study the effect of the electrolyte concentration and the scan rate on the resolution of the oxidation peaks. With the optimum experimental parameters, a quantification was performed and the linear results of percentage of anodic currents in term of their relative amount in the binary mixture were obtained. Finally, the prediction of two mixture samples was performed and gave satisfactory results

A design view of capability

In order to optimise resource deployment in a rapid changing operational environment, capability has received increasing concerns in terms of maximising the utilisation of resources. As a result of such extant research, different domains were seen to endow different meanings to capability, indicating a lack of common understanding of the true nature of capability. This paper presents a design view of capability from design artefact knowledge perspective. Capability is defined as an intrinsic quality of an entity closely related to artefact behavioural and structural knowledge. Design artefact knowledge was categorised across expected, instantiated, and interpreted artefact knowledge spaces (ES, IsS, and ItS). Accordingly, it suggests that three types of capability exist in the three spaces, which can be used in employing resources. Moreover, Network Enabled Capability (NEC), the capability of a set of linked resources within a specific environment is discussed, with an example of how network resources are deployed in a Virtual Integration Platform (VIP)

Measuring Rural Poverty in China: a Case Study Approach

This paper measures rural poverty in Hubei Province and Inner Mongolia in China. The poverty lines we derived by Ravallion's method differ from the official Chinese poverty lines. The official pan-country poverty line underestimates rural poverty in Hubei Province and overestimates rural poverty in Inner Mongolia. Poverty determinants are estimated by Logit as well as Probit models. The study notes that factors such as living in a mountainous area, lack of better irrigation conditions, a large family size, few fixed assets, few land owned and sole dependence on agriculture as a livelihood source would make a rural household more vulnerable to poverty. On the other hand, a rural household whose members are either better educated or trained laborers would statistically be less poor. The growth-redistribution decomposition reveals that for all the three FGT indexes in Hubei province, income growth contributed much to the alleviation of poverty, while the redistribution or inequality effects counteracted the growth effects and worsened poverty. The poverty incidence decomposition results reveal that about one third of the growth effects had been counteracted by the redistribution effects. This implies that future anti-poverty programs should pay more attention to solving the inequality problem in China. Poverty dominance analysis also helps us better understand the poverty situation. It reveals that rural poverty in Inner Mongolia is more severe than that in Hubei, and that poverty incidence in Hubei has lessened from 1997 to 2003, which are the same findings as those drawn from deriving poverty lines.Rural Poverty Line, Poverty Determinants, Growth Redistribution Decomposition, Poverty Dominance, China

Low-mass Active Galactic Nuclei on the Fundamental Plane of Black Hole Activity

It is widely known that in active galactic nuclei (AGNs) and black hole X-ray binaries (BHXBs), there is a tight correlation among their radio luminosity ($L_R$), X-ray luminosity ($L_X$) and BH mass (\mbh), the so-called `fundamental plane' (FP) of BH activity. Yet the supporting data are very limited in the \mbh regime between stellar mass (i.e., BHXBs) and 10$^{6.5}$\,\msun\ (namely, the lower bound of supermassive BHs in common AGNs). In this work, we developed a new method to measure the 1.4 GHz flux directly from the images of the VLA FIRST survey, and apply it to the type-1 low-mass AGNs in the \cite{2012ApJ...755..167D} sample. As a result, we obtained 19 new low-mass AGNs for FP research with both \mbh\ estimates (\mbh \approx 10^{5.5-6.5}\,\msun), reliable X-ray measurements, and (candidate) radio detections, tripling the number of such candidate sources in the literature.Most (if not all) of the low-mass AGNs follow the standard radio/X-ray correlation and the universal FP relation fitted with the combined dataset of BHXBs and supermassive AGNs by \citet{2009ApJ...706..404G}; the consistency in the radio/X-ray correlation slope among those accretion systems supports the picture that the accretion and ejection (jet) processes are quite similar in all accretion systems of different \mbh. In view of the FP relation, we speculate that the radio loudness $\mathcal{R}$ (i.e., the luminosity ratio of the jet to the accretion disk) of AGNs depends not only on Eddington ratio, but probably also on \mbh.Comment: ApJ accepte

Decision-focussed resource modelling for design decision support

Resource management including resource allocation, levelling, configuration and monitoring has been recognised as critical to design decision making. It has received increasing research interests in recent years. Different definitions, models and systems have been developed and published in literature. One common issue with existing research is that the resource modelling has focussed on the information view of resources. A few acknowledged the importance of resource capability to design management, but none has addressed the evaluation analysis of resource fitness to effectively support design decisions. This paper proposes a decision-focused resource model framework that addresses the combination of resource evaluation with resource information from multiple perspectives. A resource management system constructed on the resource model framework can provide functions for design engineers to efficiently search and retrieve the best fit resources (based on the evaluation results) to meet decision requirements. Thus, the system has the potential to provide improved decision making performance compared with existing resource management systems

2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino} -3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior

The series of 2-{2,6-bis[di(4-fluorophenyl)methyl]-4-chlorophenylimino}-3- aryliminobutane derivatives (L1-L5) and their nickel(II) dibromide complexes (Ni1-Ni5) were synthesized, and all organic compounds were fully characterized by the Fourier transform infrared (FT-IR) and nuclear magnetic resonance (NMR) spectroscopy and by elemental analysis, while the nickel complexes were characterized by FT-IR spectroscopy, elemental analysis, as well as by single-crystal X-ray diffraction for two representative examples, namely Ni1 and Ni4. A distorted tetrahedral geometry was observed for these four-coordinate nickel complexes. Upon the activation with either Methylaluminoxane or modified methylaluminoxane as co-catalyst, all nickel complex precatalysts showed very high activity toward ethylene polymerization with activities of up to 10 7 g(PE)·mol -1 (Ni)·h -1 , and afforded highly branched polyethylene with a bimodal distribution. © 2014 Elsevier B.V

Probing massive neutrinos with the Minkowski functionals of the galaxy distribution

The characteristic signatures of massive neutrinos on large-scale structure (LSS), if fully captured, can be used to put a stringent constraint on their mass sum, $M_{\nu}$. Previous work utilizing N-body simulations has shown the Minkowski functionals (MFs) of LSS can reveal the imprints of massive neutrinos on LSS, provide important complementary information to two-point statistics and significantly improve constraints on $M_{\nu}$. In this work, we take a step forward and apply the statistics to the biased tracers of LSS, i.e. the galaxies, and in redshift space. We perform a Fisher matrix analysis and quantify the constraining power of the MFs by using the Molino mock galaxy catalogs, which are constructed based on the halo occupation distribution (HOD) framework with parameters for the SDSS $M_r < -21.5$ and -22 galaxy samples. We find the MFs give tighter constraints on all of the cosmological parameters that we consider than the power spectrum. The constraints on $\Omega_{\mathrm{m}}, \Omega_{\mathrm{b}}, h, n_s, \sigma_8$, and $M_\nu$ from the MFs are better by a factor of 1.9, 2.9, 3.7, 4.2, 2.5, and 5.7, respectively, after marginalizing over the HOD parameters. Specifically, for $M_{\nu}$, we obtain a 1$\sigma$ constraint of 0.059 eV with the MFs alone for a volume of only $\left(1 h^{-1} \mathrm{Gpc}\right)^3$.Comment: 33 pages, 5 + 4 figures, 4 tables. To be submitted to JCAP. Comments welcome. arXiv admin note: text overlap with arXiv:2204.0294