990 research outputs found
Structured Training for Neural Network Transition-Based Parsing
We present structured perceptron training for neural network transition-based
dependency parsing. We learn the neural network representation using a gold
corpus augmented by a large number of automatically parsed sentences. Given
this fixed network representation, we learn a final layer using the structured
perceptron with beam-search decoding. On the Penn Treebank, our parser reaches
94.26% unlabeled and 92.41% labeled attachment accuracy, which to our knowledge
is the best accuracy on Stanford Dependencies to date. We also provide in-depth
ablative analysis to determine which aspects of our model provide the largest
gains in accuracy
Revealing the Ion Chemistry Occurring in High Kinetic Energy-Ion Mobility Spectrometry: A Proof of Principle Study
Here, we present proof of principle studies to demonstrate how the product ions associated with the ion mobility peaks obtained from a High Kinetic Energy-Ion Mobility Spectrometer (HiKE-IMS) measurement of a volatile can be identified using a Proton Transfer Reaction/Selective Reagent Ion-Time-of-Flight-Mass Spectrometer (PTR/SRI-ToF-MS) when operating both instruments at the same reduced electric field value and similar humidities. This identification of product ions improves our understanding of the ion chemistry occurring in the ion source region of a HiKE-IMS. The combination of the two analytical techniques is needed, because in the HiKE-IMS three reagent ions (NO+, H3O+ and O2+•) are present at the same time in high concentrations in the reaction region of the instrument for reduced electric fields of 100 Td and above. This means that even with a mass spectrometer coupled to the HiKE-IMS, the assignment of the product ions to a given reagent ion to a high level of confidence can be challenging. In this paper, we demonstrate an alternative approach using PTR/SRI-ToF-MS that allows separate investigations of the reactions of the reagent ions NO+, H3O+ and O2+•. In this study, we apply this approach to four nitrile containing organic compounds, namely acetonitrile, 2-furonitrile, benzonitrile and acrylonitrile. Both the HiKE-IMS and the PTR/SRI-ToF-MS instruments were operated at a commonly used reduced electric field strength of 120 Td and with gas flows at the same humidities
Stable and unstable accretion in the classical T Tauri stars IM Lup and RU Lup as observed by MOST
Results of the time variability monitoring of the two classical T Tauri
stars, RU Lup and IM Lup, are presented. Three photometric data sets were
utilised: (1) simultaneous (same field) MOST satellite observations over four
weeks in each of the years 2012 and 2013, (2) multicolour observations at the
SAAO in April - May of 2013, (3) archival V-filter ASAS data for nine seasons,
2001 - 2009. They were augmented by an analysis of high-resolution,
public-domain VLT-UT2 UVES spectra from the years 2000 to 2012. From the MOST
observations, we infer that irregular light variations of RU Lup are caused by
stochastic variability of hot spots induced by unstable accretion. In contrast,
the MOST light curves of IM Lup are fairly regular and modulated with a period
of about 7.19 - 7.58 d, which is in accord with ASAS observations showing a
well defined 7.247+/-0.026 d periodicity. We propose that this is the
rotational period of IM Lup and is due to the changing visibility of two
antipodal hot spots created near the stellar magnetic poles during the stable
process of accretion. Re-analysis of RU Lup high-resolution spectra with the
Broadening Function approach reveals signs of a large polar cold spot, which is
fairly stable over 13 years. As the star rotates, the spot-induced depression
of intensity in the Broadening Function profiles changes cyclically with period
3.71058 d, which was previously found by the spectral cross-correlation method.Comment: 14 pages, 7 figures. Accepted by MNRA
Copious Amounts of Dust and Gas in a z=7.5 Quasar Host Galaxy
We present IRAM/NOEMA and JVLA observations of the quasar J1342+0928 at
z=7.54 and report detections of copious amounts of dust and [CII] emission in
the interstellar medium (ISM) of its host galaxy. At this redshift, the age of
the universe is 690 Myr, about 10% younger than the redshift of the previous
quasar record holder. Yet, the ISM of this new quasar host galaxy is
significantly enriched by metals, as evidenced by the detection of the [CII]
158micron cooling line and the underlying far-infrared (FIR) dust continuum
emission. To the first order, the FIR properties of this quasar host are
similar to those found at a slightly lower redshift (z~6), making this source
by far the FIR-brightest galaxy known at z>7.5. The [CII] emission is spatially
unresolved, with an upper limit on the diameter of 7 kpc. Together with the
measured FWHM of the [CII] line, this yields a dynamical mass of the host of
<1.5x10^11 M_sun. Using standard assumptions about the dust temperature and
emissivity, the NOEMA measurements give a dust mass of (0.6-4.3)x10^8 M_sun.
The brightness of the [CII] luminosity, together with the high dust mass, imply
active ongoing star formation in the quasar host. Using [CII]-SFR scaling
relations, we derive star formation rates of 85-545 M_sun/yr in the host,
consistent with the values derived from the dust continuum. Indeed, an episode
of such past high star formation is needed to explain the presence of ~10^8
M_sun of dust implied by the observations.Comment: 8 pages, 4 figures. Published in ApJ Letter
First measurements of high frequency cross-spectra from a pair of large Michelson interferometers
Measurements are reported of the cross-correlation of spectra of differential
position signals from the Fermilab Holometer, a pair of co-located 39 m long,
high power Michelson interferometers with flat, broadband frequency response in
the MHz range. The instrument obtains sensitivity to high frequency correlated
signals far exceeding any previous measurement in a broad frequency band
extending beyond the 3.8 MHz inverse light crossing time of the apparatus. The
dominant but uncorrelated shot noise is averaged down over
independent spectral measurements with 381 Hz frequency resolution to obtain
sensitivity to stationary
signals. For signal bandwidths kHz, the sensitivity to strain
or shear power spectral density of classical or exotic origin surpasses a
milestone where
is the Planck time.Comment: 5 pages, 3 figure
Interferometric Constraints on Quantum Geometrical Shear Noise Correlations
Final measurements and analysis are reported from the first-generation
Holometer, the first instrument capable of measuring correlated variations in
space-time position at strain noise power spectral densities smaller than a
Planck time. The apparatus consists of two co-located, but independent and
isolated, 40 m power-recycled Michelson interferometers, whose outputs are
cross-correlated to 25 MHz. The data are sensitive to correlations of
differential position across the apparatus over a broad band of frequencies up
to and exceeding the inverse light crossing time, 7.6 MHz. By measuring with
Planck precision the correlation of position variations at spacelike
separations, the Holometer searches for faint, irreducible correlated position
noise backgrounds predicted by some models of quantum space-time geometry. The
first-generation optical layout is sensitive to quantum geometrical noise
correlations with shear symmetry---those that can be interpreted as a
fundamental noncommutativity of space-time position in orthogonal directions.
General experimental constraints are placed on parameters of a set of models of
spatial shear noise correlations, with a sensitivity that exceeds the
Planck-scale holographic information bound on position states by a large
factor. This result significantly extends the upper limits placed on models of
directional noncommutativity by currently operating gravitational wave
observatories.Comment: Matches the journal accepted versio
High Kinetic Energy Ion Mobility Spectrometry- Mass Spectrometry investigations of four inhalation anaesthetics : isoflurane, enflurane, sevoflurane and desflurane
Here we report the first High Kinetic Energy-Ion Mobility Spectrometry-Mass Spectrometric (HiKE-IMSMS) investigations involving four fluranes; isoflurane, enflurane, sevoflurane and desflurane. Unlike standard (atmospheric pressure) IMS, HiKEIMS can detect these compounds in positive ion mode. This is because its low-pressure environment (similar to 14 mbar) and the associated short ion drift times in the HiKEIMS ensure the reagent ions O-2+(center dot) and H3O+ are present in the reaction region, and these can react with the fluranes by dissociative charge and proton transfer, respectively. However, their ion intensities are very dependent on the value of the reduced electric field (E/N) applied and the humidity of the air in the reaction region of the HiKE-IMS. In this paper we explore the potential use of HiKE-IMS for air quality control and breath analysis of fluranes. To help in the interpretation of the ion mobility spectra, and hence the ion-flurane chemistry occurring in reaction region, a HiKE-IMS was coupled to a Time-of-Flight Mass Spectrometer so that the m/z values of both the reagent and product ions that are contained within the various ion mobility peaks observed could be identified with a high level of confidence. The dependencies of the intensities of these ions as functions of E/N (30-115 Td) and humidity in the reaction region are reported. A number of product ions have been observed only under low humidity conditions (H2O volume-mixing ratio 100 ppm(v)), including CHF(2+)and CHFCl (+) for isoflurane and enflurane, CHF2(+), CF3(+) and C3H2F5O+ for desflurane, and CH3O+, CHF2+, C3H3F4O+, C4H3F6O+ and C4H3F6O+(H2O) for sevoflurane. It is interesting to note that CH3O+, CHF2+, CHFCl+ and CF3+ have shorter drift times than that measured for O-2(+center dot) This is explained by resonant charge transfer reaction processes occurring in the drift region: O-2(+center dot) + O-2 ? O-2+(center dot).O O-2 + O-2 +(center dot) (c) 2022 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).Peer reviewe
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