Measuring the Degree of Crystallinity in Semicrystalline Regioregular Poly(3-hexylthiophene)

By using a combination of wide-angle X-ray diffraction (WAXD), mass density, and ¹³C solid-state nuclear magnetic resonance (NMR) measurements, a quantification of the absolute degree of crystallinity in regioregular poly­(3-hexylthiophene) (rr-P3HT) is presented. A regiorandom P3HT (rra-P3HT), lacking long-range order, was used to separate the crystalline contribution from the total scattering in WAXD, thus yielding degrees of crystallinity in the range of 47–56% at room temperature for three different rr-P3HTs. For the same rr-P3HT with identical processing history, NMR yields degrees of crystallinity that are consistently ∼10% greater than that obtained by WAXD, which can only be explained by ordered chain segments in the amorphous phase. NMR results also suggest that rra-P3HT contains weakly ordered chain segments, which likely contribute to an underestimation of degree of crystallinity when determined from mass density measurements, if rra-P3HT is used to approximate a fully amorphous P3HT. The results shown in this study provide direct proof of three different types of P3HT chain segments: crystallites (i.e., long-range ordered chain packing), amorphous phase (i.e., disordered chain packing), and short-range ordered chain packing embedded in the amorphous phase. The presence of the short-range ordered chain packing is particularly important when correlating the morphology to macroscopic charge transport properties in P3HT-based devices. In general, those locally ordered chain segments, though not constituting a distinct phase, are believed to be of critical importance in determining the transport characteristics of conjugated semiconducting polymers with or without a distinct crystalline phase present

Enhanced Luminescence Performance of Quantum Wells by Coupling Piezo-Phototronic with Plasmonic Effects

With a promising prospect of light-emitting diodes as an attractive alternative to conventional light sources, remaining challenges still cannot be addressed owing to their limited efficiency. Among the continued scientific efforts, significant improvement on the emission efficiency has been achieved <i>via</i> either piezo-phototronic effect-based strain modulation or resonant excitation of plasmons in metallic nanostructures. Here, we present the investigation on the coupling process between piezo-phototronic effect and localized surface plasmonic resonance for enhancing the photoluminescence of InGaN/GaN quantum wells coated with Ag nanoparticles. The underlying physical mechanism of experimental results originates from tuning plasmonic resonance controlled by the shift of emission wavelength <i>via</i> piezo-phototronic effect, and it is further confirmed with the support of theoretical calculations. As a result, our research provides an approach to the integration of plasmonics with piezo-phototronic effect and brings widespread applications to high-efficiency artificial lighting, on-chip integrated plasmonic circuits, subwavelength optical communication, and micro-optoelectronic mechanical systems

Freestanding Flag-Type Triboelectric Nanogenerator for Harvesting High-Altitude Wind Energy from Arbitrary Directions

Wind energy at a high altitude is far more stable and stronger than that near the ground, but it is out of reach of the wind turbine. Herein, we develop an innovative freestanding woven triboelectric nanogenerator flag (WTENG-flag) that can harvest high-altitude wind energy from arbitrary directions. The wind-driven fluttering of the woven unit leads to the current generation by a coupled effect of contact electrification and electrostatic induction. Systematic study is conducted to optimize the structure/material parameters of the WTENG-flag to improve the power output. This 2D WTENG-flag can also be stacked in parallel connections in many layers for a linearly increased output. Finally, a self-powered high-altitude platform with temperature/humidity sensing/telecommunicating capability is demonstrated with the WTENG-flag as a power source. Due to the light weight, low cost, and easy scale-up, this WTENG-flag has great potential for applications in weather/environmental sensing/monitoring systems

Formation of a group of younger school age children using games and drama lessons (Project)

Time-lapse recordings demonstrating the lack of the intravascular rolling and adhesion of leukocytes in C3 −/− mice after intraventricular LPS injection (4 h). Rolling leukocytes were defined as those cells moving at a velocity less than that of erythrocytes. Cells were considered adherent if they remained stationary for at least 30 s in a distance of 100 μm. (MOV 750 kb

Supplementary document for Flexible GaN-based Microscale Light-Emitting Diodes with Batch Transfer by Wet Etching - 5978365.pdf

Experiment sections and some date result

Freestanding Flag-Type Triboelectric Nanogenerator for Harvesting High-Altitude Wind Energy from Arbitrary Directions

Wind energy at a high altitude is far more stable and stronger than that near the ground, but it is out of reach of the wind turbine. Herein, we develop an innovative freestanding woven triboelectric nanogenerator flag (WTENG-flag) that can harvest high-altitude wind energy from arbitrary directions. The wind-driven fluttering of the woven unit leads to the current generation by a coupled effect of contact electrification and electrostatic induction. Systematic study is conducted to optimize the structure/material parameters of the WTENG-flag to improve the power output. This 2D WTENG-flag can also be stacked in parallel connections in many layers for a linearly increased output. Finally, a self-powered high-altitude platform with temperature/humidity sensing/telecommunicating capability is demonstrated with the WTENG-flag as a power source. Due to the light weight, low cost, and easy scale-up, this WTENG-flag has great potential for applications in weather/environmental sensing/monitoring systems

Freestanding Flag-Type Triboelectric Nanogenerator for Harvesting High-Altitude Wind Energy from Arbitrary Directions

Wind energy at a high altitude is far more stable and stronger than that near the ground, but it is out of reach of the wind turbine. Herein, we develop an innovative freestanding woven triboelectric nanogenerator flag (WTENG-flag) that can harvest high-altitude wind energy from arbitrary directions. The wind-driven fluttering of the woven unit leads to the current generation by a coupled effect of contact electrification and electrostatic induction. Systematic study is conducted to optimize the structure/material parameters of the WTENG-flag to improve the power output. This 2D WTENG-flag can also be stacked in parallel connections in many layers for a linearly increased output. Finally, a self-powered high-altitude platform with temperature/humidity sensing/telecommunicating capability is demonstrated with the WTENG-flag as a power source. Due to the light weight, low cost, and easy scale-up, this WTENG-flag has great potential for applications in weather/environmental sensing/monitoring systems

Self-Healable, Stretchable, Transparent Triboelectric Nanogenerators as Soft Power Sources

Despite the rapid advancements of soft electronics, developing compatible energy devices will be the next challenge for their viable applications. Here, we report an energy-harnessing triboelectric nanogenerator (TENG) as a soft electrical power source, which is simultaneously self-healable, stretchable, and transparent. The nanogenerator features a thin-film configuration with buckled Ag nanowires/poly­(3,4-ethylenedioxythiophene) composite electrode sandwiched in room-temperature self-healable poly­(dimethylsiloxane) (PDMS) elastomers. Dynamic imine bonds are introduced in PDMS networks for repairing mechanical damages (94% efficiency), while the mechanical recovery of the elastomer is imparted to the buckled electrode for electrical healing. By adjusting the buckling wavelength of the electrode, the stretchability and transparency of the soft TENG can be tuned. A TENG (∼50% stretchabitliy, ∼73% transmittance) can recover the electricity genearation (100% healing efficiency) even after accidental cutting. Finally, the conversion of biomechanical energies into electricity (∼100 V, 327 mW/m²) is demonstrated by a skin-like soft TENG. Considering all these merits, this work suggests a potentially promising approach for next-generation soft power sources

Self-Healable, Stretchable, Transparent Triboelectric Nanogenerators as Soft Power Sources

Despite the rapid advancements of soft electronics, developing compatible energy devices will be the next challenge for their viable applications. Here, we report an energy-harnessing triboelectric nanogenerator (TENG) as a soft electrical power source, which is simultaneously self-healable, stretchable, and transparent. The nanogenerator features a thin-film configuration with buckled Ag nanowires/poly­(3,4-ethylenedioxythiophene) composite electrode sandwiched in room-temperature self-healable poly­(dimethylsiloxane) (PDMS) elastomers. Dynamic imine bonds are introduced in PDMS networks for repairing mechanical damages (94% efficiency), while the mechanical recovery of the elastomer is imparted to the buckled electrode for electrical healing. By adjusting the buckling wavelength of the electrode, the stretchability and transparency of the soft TENG can be tuned. A TENG (∼50% stretchabitliy, ∼73% transmittance) can recover the electricity genearation (100% healing efficiency) even after accidental cutting. Finally, the conversion of biomechanical energies into electricity (∼100 V, 327 mW/m²) is demonstrated by a skin-like soft TENG. Considering all these merits, this work suggests a potentially promising approach for next-generation soft power sources

Self-Healable, Stretchable, Transparent Triboelectric Nanogenerators as Soft Power Sources

Despite the rapid advancements of soft electronics, developing compatible energy devices will be the next challenge for their viable applications. Here, we report an energy-harnessing triboelectric nanogenerator (TENG) as a soft electrical power source, which is simultaneously self-healable, stretchable, and transparent. The nanogenerator features a thin-film configuration with buckled Ag nanowires/poly­(3,4-ethylenedioxythiophene) composite electrode sandwiched in room-temperature self-healable poly­(dimethylsiloxane) (PDMS) elastomers. Dynamic imine bonds are introduced in PDMS networks for repairing mechanical damages (94% efficiency), while the mechanical recovery of the elastomer is imparted to the buckled electrode for electrical healing. By adjusting the buckling wavelength of the electrode, the stretchability and transparency of the soft TENG can be tuned. A TENG (∼50% stretchabitliy, ∼73% transmittance) can recover the electricity genearation (100% healing efficiency) even after accidental cutting. Finally, the conversion of biomechanical energies into electricity (∼100 V, 327 mW/m²) is demonstrated by a skin-like soft TENG. Considering all these merits, this work suggests a potentially promising approach for next-generation soft power sources