Influence of Palm Oil Fuel Ash and W/B Ratios on Compressive Strength, Water Permeability, and Chloride Resistance of Concrete

This research studies the effects of W/B ratios and palm oil fuel ash (POFA) on compressive strength, water permeability, and chloride resistance of concrete. POFA was ground until the particles retained on sieve number 325 were less than 5% by weight. POFA was used to partially replace OPC at rates of 15, 25, and 35% by weight of binder. The water to binder (W/B) ratios of concrete were 0.40 and 0.50. The compressive strength, water permeability, and chloride resistance of concrete were investigated up to 90 days. The results showed that POFA concrete with W/B ratio of 0.40 had the compressive strengths ranging from 45.8 to 55.9 MPa or 82–94% of OPC concrete at 90 days, while POFA concrete with W/B ratio of 0.50 had the compressive strengths of 33.9–41.9 MPa or 81–94% of OPC concrete. Furthermore, the compressive strength of concrete incorporation of ground POFA at 15% was the same as OPC concrete. The water permeability coefficient and the chloride ion penetration of POFA concrete were lower than OPC concrete when both types of concrete had the same compressive strengths. The findings also indicated that water permeability and chloride ion penetration of POFA concrete were significantly reduced compared to OPC concrete

Properties of concrete made from industrial wastes containing calcium carbide residue palm oil fuel ash rice husk-bark ash and recycled aggregates

บทคัดย่อคอนกรีตนี้ถูกทำขึ้น โดยใช้วัสดุเหลือทิ้งอุตสาหกรรมทั้งในวัสดุประสานและมวลรวมกากแคลเซียมคาร์-ไบด์ (CCR) ผสมแยกกับเถ้าปาล์มน้ำมัน (PA) และเถ้าแกลบเปลือกไม้ (RA) นำมาใช้เป็นวัสดุประสานแทนที่ปูนซีเมนต์ในส่วนผสมคอนกรีต นอกจากนี้มวลรวมรีไซเคิลถูกนำมาใช้แทนที่มวลรวมธรรมชาติเพื่อที่หล่อตัวอย่างคอนกรีต (คอนกรีต CCR-PA และ CCR-RA) สมบัติของคอนกรีต ได้แก่ กำลังอัด การแทรกซึมของคลอไรด์ และการซึมของน้ำผ่านคอนกรีตได้รับการประเมินและเปรียบเทียบกับคอนกรีตควบคุม (คอนกรีต CON) ผลการวิจัยพบว่าวัสดุประสาน CCR-PA และ CCR-RA สามารถนำมาใช้เป็นสารยึดเกาะในคอนกรีตที่ใช้มวลรวมรีไซเคิล แม้ว่าวัสดุประสาน CCR-PA และ CCR-RA มีหรือไม่มีปูนซีเมนต์ การพัฒนากำลังอัดของคอนกรีต CCR-PA และ CCR-RA คล้ายกับคอนกรีต CON นอกจากนี้วัสดุประสาน CCR-PA และ CCR-RA สามารถปรับปรุงการแทรกซึมของคลอไรด์และการซึมของน้ำผ่านคอนกรีตได้อย่างมีประสิทธิภาพ ผลการวิจัยยังชี้ให้เห็นว่าคอนกรีต CCR-PA และ CCR-RA สามารถใช้เป็นคอนกรีตที่เป็นมิตรต่อสิ่งแวดล้อมชนิดใหม่ เพราะคอนกรีตเหล่านี้สามารถลดการปล่อยก๊าซคาร์บอนไดออกไซด์และลดปัญหาสิ่งแวดล้อมAbstractThis concrete was made by using several industrial wastes in both binder and aggregates. Calcium carbide residue (CCR) mixed separately with palm oil fuel ash (PA) and rice husk-bark ash (RA), and was used as a binder instead of Portland cement in the concrete mixture. Furthermore, recycled aggregates were fully replaced natural aggregates in order to cast concrete specimens (CCR-PA and CCR-RA concretes). Concrete properties namely compressive strength, chloride migration, and water permeability of CCR-PA and CCR-RA concretes were evaluated and compared with the conventional concrete (CON concrete). The results indicated that CCR-PA and CCR-RA binders could be used as a new cementitious material in recycled aggregate concrete, even though the CCR-PA and CCR-RA binders contained no Portland cement. The characteristic compressive strength of CCR-PA and CCR-RA concretes developed similar to CON concrete. Moreover, CCR-PA and CCR-RA binders in the mixtures were effectively improving the chloride migration and water permeability of recycled aggregate concretes. These results also suggested that CCR-PA and CCR-RA concretes can be used as a new environmental friendly concrete because of these concretes can reduce as much as CO2 emissions and environmental problems

Evaluation of Heat Evolution of Pastes Containing High Volume of Ground River Sand and Ground Granulated Blast Furnace Slag

This paper investigated the heat evolution of pastes containing inert and active materials with different particle sizes. Ground river sand was used as an inert material while ground granulated blast furnace (GGBF) slag was used as an active material. Ground river sand (GRS) and GGBF slag were ground to have the same particle size and were used separately as a replacement of Portland cement type I at rates of 50 – 70 % by weight of the binder. Heat evolution of pastes containing GRS and GGBF slag was measured using an isothermal conduction calorimeter up to 72 h. The results showed that GRS with different particle sizes had a slight effect on the heat evolution of pastes. GGBF slag with median particle size d50 of 4.4 μm and d50 of 17.8 μm had a small effect on the heat evolution of pastes during the first 24 h, and the pastes also had very low heat evolution for up to 72 h. At the same replacement rate of Portland cement, however, the heat evolution due to the slag reaction was slightly increased when the particle size of the GGBF slag was decreased. Finally, the higher is the cement replacement by GGBF slag, the higher is the slag reaction

Development of Concrete Paving Blocks Prepared from Waste Materials without Portland Cement

This experiment used three types of waste materials: calcium carbide residue, fly ash, and recycled concrete aggregate to develop concrete paving blocks. The blocks had calcium carbide residue and fly ash as a binder without ordinary Portland cement (OPC) and combined with 100 % of recycled concrete aggregate. The concrete paving blocks were 10 × 10 × 20 cm and were formed using a pressure of 6 or 8 MPa. The binder-to-aggregate ratio was held constant at 1:3 by weight, while the water-to-binder ratios were 0.30, 0.35, and 0.40. The effects of the water-to-binder ratios and fineness of the binder on the compressive strength, flexural strength, abrasion resistance, and water absorption of the concrete paving blocks were determined and compared with those of TIS 827 and ASTM C1319 standards. The results revealed that by applying this procedure, we were able to produce an excellence concrete paving block without using OPC. The compressive strength of the concrete paving blocks made from these waste materials was 41.4 MPa at 28 days and increased to 45.3 MPa at 60 days. Therefore, these waste materials can be used as raw materials to manufacture concrete paving blocks without OPC that meet the requirements of 40 MPa and 35 MPa specified by the TIS 827 and ASTM C1319 standards, respectively.DOI: http://dx.doi.org/10.5755/j01.ms.24.1.17566</p

Evaluation of Strengths from Cement Hydration and Slag Reaction of Mortars Containing High Volume of Ground River Sand and GGBF Slag

This paper investigates the cement hydration, and the slag reaction contributes to the compressive strengths of mortars mixed with ground river sand (GRS) and ground-granulated blast furnace (GGBF) slag with different particle sizes. GRS (inert material) and GGBF slag (reactive material) were ground separately until the median particle sizes of 32 ± 1, 18 ± 1, and 5 ± 1 micron and used to replace Portland cement (PC) in large amount (40–60%) by weight of the binder. The results showed that, at the early age, the compressive strength obtained from the cement hydration was higher than that obtained from the slag reaction. The results of compressive strength also indicated that the GGBF slag content and particle size play important roles in the slag reaction at the later ages, whereas cement hydration is more prominent at the early ages. Although the results could be expected from the use of GGBF slag to replace PC in mortar or concrete, this study had presented the values of the compressive strength along with ages and the finenesses of GGBF slag that contributed from cement hydration and from GGBF slag reaction

Factors affecting compressive strength and expansion due to alkali-silica reaction of fly ash-based alkaline activated mortar

The development of environmentally friendly alkaline-activated materials (AAMs) holds promise, as AAMs can be derived from waste materials. This study aims to investigate the factors influencing (i) compressive strength and (ii) expansion due to alkali-silica reaction (ASR) in AAMs. These factors include alkaline concentration, heat curing conditions, fineness of fly ash, and the liquid alkaline-to-binder (L/B) ratio. The findings indicate that the higher concentrations of NaOH solution led to an increase in AAM compressive strength due to the enhanced dissolution and polymerization rates in a more alkaline environment. Heat curing stimulated chemical reactions and structure formation, while the reduced water content resulted in lower porosity and higher compressive strength in the hardened cement. Finer fly ash yielded greater compressive strength than coarser ash, as its smaller spherical particles contributed to denser and firmer structures. The presence of calcium minerals, from both Ordinary Portland Cement (OPC) and high-calcium fly ash, bolstered the strength of hardened products. Moreover, calcium minerals like CaO, Ca(OH)2, and CaSO4 were found to induce ASR expansion by promoting gel formation, leading to later-stage expansion in the hardened cement or concrete. However, finely milled fly ash as a precursor significantly reduced ASR expansion in AAMs, by approximately 40% compared to ordinary Portland cement. This study provides valuable insights for civil engineers for better understanding of AAM behavior and makes contributions to the safety and sustainability of cement and concrete systems

Influence of Asphalt Emulsion Inclusion on Fly Ash/Hydrated Lime Alkali-Activated Material

Supplementary cementitious materials have been widely used to reduce the greenhouse gas emissions caused by ordinary Portland cement (OPC), including in the construction of road bases. In addition, the use of OPC in road base stabilization is inefficient due to its moisture sensitivity and lack of flexibility. Therefore, this study investigates the effect of hybrid alkali-activated materials (H-AAM) on flexibility and water prevention when used as binders while proposing a new and sustainable material. A cationic asphalt emulsion (CAE) was applied to increase this cementless material’s resistance to moisture damage and flexibility. The physical properties and structural formation of this H-AAM, consisting of fly ash, hydrated lime, and sodium hydroxide, were examined. The results revealed that the addition of CAE decreased the material’s mechanical strength due to its hindrance of pozzolanic reactions and alkali activations. This study revealed decreases in the cementitious product’s peak in the x-ray diffraction analysis (XRD) tests and the number of tetrahedrons detected in the Fourier transform infrared spectroscopy analysis (FTIR) tests. The scanning electron microscope (SEM) images showed some signs of asphalt films surrounding hybrid alkali-activated particles and even some unreacted FA particles, indicating incomplete chemical reactions in the study material’s matrix. However, the H-AAM was still able to meet the minimum road base strength requirement of 1.72 MPa. Furthermore, the toughness and flexibility of the H-AAM were enhanced by CAE. Notably, adding 10% and 20% CAE by weight to the hybrid alkali-activated binder produced a significant advantage in terms of water absorption, which can be explained by its influence on the material’s consolidation of its matrices, resulting in significant void reductions. Hence, the outcomes of this study might reveal an opportunity for developing a new stabilizing agent for road bases with water-prevention properties and flexibility that remains faithful to the green construction material concept

Influences of Silica Fume on Compressive Strength and Chemical Resistances of High Calcium Fly Ash-Based Alkali-Activated Mortar

Although elevated temperature curing can increase the compressive strength of alkali-activated mortar, its field applications are still limited. In this study, alkali-activated mortars were prepared using high calcium fly ash (FA) as a precursor. Small amounts of silica fume were used to partially replace high calcium fly ash at 3&ndash;9% by weight to increase the strength of alkali-activated mortar. All mixtures had a liquid to binder ratio of 0.60 and sand to binder ratio of 2.75 by weight. A ratio of NaOH to Na2SiO3 solution was kept at 2:1 by weight. Mortar flow was also held between 105&ndash;115 using a superplasticizer. Compressive strength and durability were investigated in terms of acid and sulfate resistance. The effects of silica fume addition and curing temperature on compressive strength were found to be significant. The optimum content of silica fume was 6%, providing compressive strength as high as that of alkali-activated mortars cured at 45 &deg;C. The weight loss of alkali-activated mortar due to sulfuric acid attack decreased with increasing silica fume content and curing temperature. All alkali-activated mortars were found to have a better performance than (ordinary) Portland cement (OPC) mortars and mortars containing 40% FA. Alkali-activated mortars immersed in magnesium sulfate solutions had compressive strength that decreased with an increase in curing temperature. The expansion of alkali-activated mortar due to sodium sulfate attack increased with increasing silica fume content, and the expansion decreased with increased curing temperature. All alkali-activated mortars performed better than OPC mortars after 98 days of sulfate attack

Characteristics of Waste Iron Powder as a Fine Filler in a High-Calcium Fly Ash Geopolymer

Geopolymer (GP) has been applied as an environmentally-friendly construction material in recent years. Many pozzolanic wastes, such as fly ash (FA) and bottom ash, are commonly used as source materials for synthesizing geopolymer. Nonetheless, many non-pozzolanic wastes are often applied in the field of civil engineering, including waste iron powder (WIP). WIPs are massively produced as by-products from iron and steel industries, and the production rate increases every year. As an iron-based material, WIP has properties of heat induction and restoration, which can enhance the heat curing process of GP. Therefore, this study aimed to utilize WIP in high-calcium FA geopolymer to develop a new type of geopolymer and examine its properties compared to the conventional geopolymer. Scanning electron microscopy and X-ray diffraction were performed on the geopolymers. Mechanical properties, including compressive strength and flexural strength, were also determined. In addition, setting time and temperature monitoring during the heat curing process were carried out. The results indicated that the addition of WIP in FA geopolymer decreased the compressive strength, owing to the formation of tetrahydroxoferrate (II) sodium or Na2[Fe(OH)4]. However, a significant increase in the flexural strength of GP with WIP addition was detected. A flexural strength of 8.5 MPa was achieved by a 28-day sample with 20% of WIP addition, nearly three times higher than that of control

Investigation of Strength and Microstructural Characteristics of Blended Cement-Admixed Clay with Bottom Ash

This research presents an experimental study of the strength and microstructural characteristics of cement-bottom ash-admixed Bangkok clay, paying special attention to the efficiency of adding up the bottom ash (BA) of different finesses as a cementitious material and the role played by BA in enhancing the strength of the mixture. The obtained results were discussed with cemented clay mixed with other industrial ashes (i.e., fly ash and risk husk ash). The pozzolanic reaction and packing effect of BA on strength development were also discussed with tests of mixtures with insoluble material. The experimental study was performed through unconfined compression (UC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) tests. The obtained results demonstrate that the BA could be advantageously supplemented as cementitious material into the cement-admixed clay mixture to improve the strength characteristic. The finer particle size of BA could be beneficial for achieving a high strength due to the pozzolanic reaction and packing effects. By adding up a BA content of larger than 15% when the base cement content is not less than 20%, the strength of the mixture increased efficiently with the increasing BA content. Compared with fly ash of a similar grain size, the higher efficiency of BA is obtained when a BA content of greater than 15% is considered. Finally, the microstructure and changes in elemental composition/distribution were analyzed by TGA and SEM tests to explain the mechanism to improve the strength of cement–BA-admixed clay