การผลิตวัสดุดูดซับเสียงจากวัสดุผสม ยางโฟมธรรมชาติและเส้นใยธรรมชาติ

รายงานการวิจัย -- มหาวิทยาลัยเทคโนโลยีราชมงคลพระนคร, 2558This research work was to study the effect of surface treatment of natural fiber and the effects of type and content of natural fiber on the development of acoustic material from natural rubber foam /natural fiber composites. The surface treatment used for this research work was sodium hydroxide (NaOH) treatment. NaOH Concentrations and treatment times were varied from 0 to 15 %wt. and 0 to 30 min, respectively. Natural fibers used for this work were bagasse fiber (BF) and oil palm fiber (OPF). The suitable condition for surface treatment was estimated by fiber length and diameter (L/D) ratio and morphology of natural fiber. The result suggested that L/D ratios tended to increase when NaOH concentrations and/or treatment times increased except for NaOH concentration of 15 %wt. L/D ratios of OPF after surface treatment were changed more than those of BF. The suitable conditions of NaOH treatment for BF and OPF were NaOH concentration of 10 %wt. and surface treatment times of 30 and 10 min, respectively. The effects of fiber type and content on sound absorption properties of natural rubber foam /natural fiber composites were investigated by cell characteristics, sound absorption coefficient, DMA analysis and bulk density. Both treated BF and OPF with suitable treatment condition were varied from content of 0.0 to 10.0 %wt. The result showed that the cell size of composites tended to decrease with addition of natural fiber whereas number of foam cell per unit volume increased. After adding natural fiber more than 2.5 %wt., cell size of composite foam and number of foam cell per unit volume tended to change the inverse direction. Natural fiber in composites enhanced the sound absorption efficiency. Sound absorption coefficient of composites adding BF was more than that of composite adding OPF. The addition of natural fiber enhanced the elasticity of composites and that increased sound absorption efficiency. NaOH treatment led to creation of strong interfacial bonding between natural fiber and natural rubber and enhanced the sound absorption efficiency. Density of NR composite foam increased with increasing natural fiber content.Rajamangala University of Technology Phra Nakho

การปรับปรุงความเหนียวและความทนแรงกระแทกของพอลิแลกติกแอซิดโดยการใช้น้ำมันถั่วเหลืองที่ผ่านการดัดแปรและเส้นใยธรรมชาติ

รายงานวิจัย -- มหาวิทยาลัยเทคโนโลยีราชมงคลพระนคร, 2559This research work was to study the improvement of toughness and impact resistance of polylactic acid (PLA) with modified soybean oil (MSBO) and palm fiber (PF). The detail of this work was divided into three parts. The first was to find the suitable condition for modification of soybean oil with ozonolysis. The second and last parts were to study the effects of MSBO and PF contents on the properties of PLA, respectively. For oil modification, the reaction times were varied from 0 to 3 hours and the chemical changes in molecules of soybean oil were investigated by Nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopies. The result suggested that the most suitable condition for ozonolysis reaction was 2 hours considering the decrease in double bond between carbon atoms and the increase in hydroxyl group into molecular structure of MSBO. For the effect of MSBO content on mechanical properties, it was evaluated by tensile and impact testing. Differential scanning calorimeter (DSC) and scanning electron microscope (SEM) were used for thermal and morphology analyses. The result showed that elongation at break and impact strength of modified PLA by MSBO increased about 89 and 25 % compared to those of neat PLA, respectively. MSBO act as the efficient plasticizer for PLA considering the conversion of fracture behavior from brittle to ductile, good dispersions of MSBO droplets in PLA and the decrease of glass transition temperature (Tg) with addition of MSBO. The addition of PF improved the impact strength of modified PLA. Strong interfacial bonding between PLA and PF indicated MSBO being both coupling agent for PLA and natural fiber and plasticizer for PLA. For migration test, it was found that contents of released heavy metal and migrated chemical from specimens of PLA and PLA/PF composite were under the criteria according to Notification of the Ministry of Public Health (No. 295) B.E. 2548.Rajamangala University of Technology Phra Nakho