Old inspires new: activation and stabilization of iodine in diene-based rubbers.

In 1920, Hermann Staudinger put forward the concept that rubber is composed of isoprene units, which has been considered as the beginning of “macromolecular science” or “polymer science.” The past 100 years’ development of polymer science has witnessed the greatness and foresight of this ground breaking theory. On the occasion of the 100th anniversary of the birth of polymer science, this paper is dedicated to recalling a piece of research history on rubbe

Dynamic Analysis of a Phytoplankton-Fish Model with Biological and Artificial Control

We investigate a nonlinear model of the interaction between phytoplankton and fish, which uses a pair of semicontinuous systems with biological and artificial control. First, the existence of an order-1 periodic solution to the system is analyzed using a Poincaré map and a geometric method. The stability conditions of the order-1 periodic solution are obtained by a theoretical mathematical analysis. Furthermore, based on previous analysis, we investigate the bifurcation in the order-1 periodic solution and prove that the order-1 periodic solution breaks up an order-1 periodic solution at least. In addition, the transcritical bifurcation of the system is described. Finally, we provide a series of numerical results that illustrate the feasibility of the theoretical results. Based on the theoretical and numerical results, we analyzed the feasibility of biological and artificial control, which showed that biological and artificial methods can control phytoplankton blooms. These results are expected to be useful for the study of phytoplankton dynamics in aquatic ecosystems

Stability and Hopf Bifurcation Analysis of a Nutrient-Phytoplankton Model with Delay Effect

A delay differential system is investigated based on a previously proposed nutrient-phytoplankton model. The time delay is regarded as a bifurcation parameter. Our aim is to determine how the time delay affects the system. First, we study the existence and local stability of two equilibria using the characteristic equation and identify the condition where a Hopf bifurcation can occur. Second, the formulae that determine the direction of the Hopf bifurcation and the stability of periodic solutions are obtained using the normal form and the center manifold theory. Furthermore, our main results are illustrated using numerical simulations

Nonlinear Dynamics of a Nutrient-Plankton Model

We investigated a nonlinear model of the interaction between nutrients and plankton, which was addressed using a pair of reaction-advection-diffusion equations. Based on numerical analysis, we studied a model without diffusion and sinking terms, and we found that the phytoplankton density (a stable state) increased with the increase of nutrient density. We analyzed the model using a linear analysis technique and found that the sinking of phytoplankton could affect the system. If the sinking velocity exceeded a certain critical value, the stable state became unstable and the wavelength of phytoplankton increased with the increase of sinking velocity. Furthermore, band patterns were also produced by our model, which was affected by the diffusion and sinking of phytoplankton. Thus, the change in the diffusion and sinking of phytoplankton led to different spatial distributions of phytoplankton. All of these results are expected to be useful in the study of plankton dynamics in aquatic ecosystems

Statistical Properties of High-Speed Train Wireless Channels in Different Scenarios

The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.In this paper, we compare the statistical properties of high-speed train (HST) wireless channels in different scenarios using a generic non-stationary HST channel model that has been verified by channel measurements (Ghazal et al., 2015). We mainly focus our comparison and analysis on the three most common HST scenarios, i.e., the rural area, cutting, and viaduct scenarios. Several channel statistical properties such as the temporal autocorrelation function (ACF), space cross-correlation function (CCF), and space- Doppler (SD) power spectrum density (PSD) are investigated. The impacts of different scenario- specific parameters on the channel statistical properties are also studied via numerical analysis

Engineering nanomedicines using stimuli-responsive biomaterials

The ability to engineer particles has the potential to shift the paradigm in the creation of new medicines and diagnostics. Complete control over particle characteristics, such as size, shape, mechanical property, and surface chemistry, can enable rapid translation and facilitate the US Food and Drug Administration (FDA) approval of particle technologies for the treatment of cancer, infectious diseases, diabetes, and a host of other major illnesses. The incorporation of natural and artificial external stimuli to trigger the release of drugs enables exquisite control over the release profiles of drugs in a given environment. In this article, we examine several readily scalable top-down methods for the fabrication of shape-specific particles that utilize stimuli-responsive biomaterials for controlled drug delivery. Special attention is given to Particle Replication In Nonwetting Templates (PRINT®) technology and the application of novel triggered-release synthetic and natural polymers

Channel Measurements and Models for High-Speed Train Wireless Communication Systems in Tunnel Scenarios: A Survey

The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.The rapid developments of high-speed trains (HSTs) introduce new challenges to HST wireless communication systems. Realistic HST channel models play a critical role in designing and evaluating HST communication systems. Due to the length limitation, bounding of tunnel itself, and waveguide effect, channel characteristics in tunnel scenarios are very different from those in other HST scenarios. Therefore, accurate tunnel channel models considering both large-scale and small-scale fading characteristics are essential for HST communication systems. Moreover, certain characteristics of tunnel channels have not been investigated sufficiently. This article provides a comprehensive review of the measurement campaigns in tunnels and presents some tunnel channel models using various modeling methods. Finally, future directions in HST tunnel channel measurements and modeling are discussed

High throughput Single-cell Cultivation on Microfluidic Streak Plates

This paper describes the microfluidic streak plate (MSP), a facile method for high-throughput microbial cell separation and cultivation in nanoliter sessile droplets. The MSP method builds upon the conventional streak plate technique by using microfluidic devices to generate nanoliter droplets that can be streaked manually or robotically onto petri dishes prefilled with carrier oil for cultivation of single cells. In addition, chemical gradients could be encoded in the droplet array for comprehensive dose-response analysis. The MSP method was validated by using single-cell isolation of Escherichia coli and antimicrobial susceptibility testing of Pseudomonas aeruginosa PAO1. The robustness of the MSP work flow was demonstrated by cultivating a soil community that degrades polycyclic aromatic hydrocarbons. Cultivation in droplets enabled detection of the richest species diversity with better coverage of rare species. Moreover, isolation and cultivation of bacterial strains by MSP led to the discovery of several species with high degradation efficiency, including four Mycobacterium isolates and a previously unknown fluoranthene-degrading Blastococcus species

Rapidly-Dissolvable Microneedle Patches Via a Highly Scalable and Reproducible Soft Lithography Approach

Microneedle devices for transdermal drug delivery have recently become an attractive method to overcome the diffusion-limiting epidermis and effectively transport therapeutics to the body. Here, we demonstrate the fabrication of highly reproducible and completely dissolvable polymer microneedles on flexible water-soluble substrates. These biocompatible microneedles (made by using a soft lithography process known as PRINT) showed efficacy in piercing both murine and human skin samples and delivering a fluorescent drug surrogate to the tissue

Tuning Amphiphilicity of Particles for Controllable Pickering Emulsion

Pickering emulsions with the use of particles as emulsifiers have been extensively used in scientific research and industrial production due to their edge in biocompatibility and stability compared with traditional emulsions. The control over Pickering emulsion stability and type plays a significant role in these applications. Among the present methods to build controllable Pickering emulsions, tuning the amphiphilicity of particles is comparatively effective and has attracted enormous attention. In this review, we highlight some recent advances in tuning the amphiphilicity of particles for controlling the stability and type of Pickering emulsions. The amphiphilicity of three types of particles including rigid particles, soft particles, and Janus particles are tailored by means of different mechanisms and discussed here in detail. The stabilization-destabilization interconversion and phase inversion of Pickering emulsions have been successfully achieved by changing the surface properties of these particles. This article provides a comprehensive review of controllable Pickering emulsions, which is expected to stimulate inspiration for designing and preparing novel Pickering emulsions, and ultimately directing the preparation of functional materials