The triviality of the 61-stem in the stable homotopy groups of spheres

We prove that the 2-primary $\pi_{61}$ is zero. As a consequence, the Kervaire invariant element $\theta_5$ is contained in the strictly defined 4-fold Toda bracket $\langle 2, \theta_4, \theta_4, 2\rangle$. Our result has a geometric corollary: the 61-sphere has a unique smooth structure and it is the last odd dimensional case - the only ones are $S^1, S^3, S^5$ and $S^{61}$. Our proof is a computation of homotopy groups of spheres. A major part of this paper is to prove an Adams differential $d_3(D_3) = B_3$. We prove this differential by introducing a new technique based on the algebraic and geometric Kahn-Priddy theorems. The success of this technique suggests a theoretical way to prove Adams differentials in the sphere spectrum inductively by use of differentials in truncated projective spectra.Comment: 67 pages, minor changes, accepted versio

The special fiber of the motivic deformation of the stable homotopy category is algebraic

For each prime $p$, we define a $t$-structure on the category $\widehat{S^{0,0}}/\tau\text{-}\mathbf{Mod}_{harm}^b$ of harmonic $\mathbb{C}$-motivic left module spectra over $\widehat{S^{0,0}}/\tau$, whose MGL-homology has bounded Chow-Novikov degree, such that its heart is equivalent to the abelian category of $p$-completed $BP_*BP$-comodules that are concentrated in even degrees. We prove that $\widehat{S^{0,0}}/\tau\text{-}\mathbf{Mod}_{harm}^b$ is equivalent to $\mathcal{D}^b({{BP}_*{BP}\text{-}\mathbf{Comod}}^{{ev}})$ as stable $\infty$-categories equipped with $t$-structures. As an application, for each prime $p$, we prove that the motivic Adams spectral sequence for $\widehat{S^{0,0}}/\tau$, which converges to the motivic homotopy groups of $\widehat{S^{0,0}}/\tau$, is isomorphic to the algebraic Novikov spectral sequence, which converges to the classical Adams-Novikov $E_2$-page for the sphere spectrum $\widehat{S^0}$. This isomorphism of spectral sequences allows Isaksen and the second and third authors to compute the stable homotopy groups of spheres at least to the 90-stem, with ongoing computations into even higher dimensions.Comment: Accepted version, 85 page

Carbon Monoxide Oxidation Promoted by Surface Polarization Charges in a CuO/Ag Hybrid Catalyst.

Composite structures have been widely utilized to improve material performance. Here we report a semiconductor-metal hybrid structure (CuO/Ag) for CO oxidation that possesses very promising activity. Our first-principles calculations demonstrate that the significant improvement in this system's catalytic performance mainly comes from the polarized charge injection that results from the Schottky barrier formed at the CuO/Ag interface due to the work function differential there. Moreover, we propose a synergistic mechanism underlying the recovery process of this catalyst, which could significantly promote the recovery of oxygen vacancy created via the M-vK mechanism. These findings provide a new strategy for designing high performance heterogeneous catalysts