Why are Fluid Densities So Low in Carbon Nanotubes?

The equilibrium density of fluids under nanoconfinement can differ substantially from their bulk density. Using a mean-field approach to describe the energetic landscape near the carbon nanotube (CNT) wall, we obtain analytical results describing the lengthscales associated with the layering observed at the fluid-CNT interface. When combined with molecular simulation results for the fluid density in the layered region, this approach allows us to derive a closed-form prediction for the overall equilibrium fluid density as a function of the CNT radius that is in excellent agreement with molecular dynamics simulations. We also show how aspects of this theory can be extended to describe water confined within CNTs and find good agreement with results from the literature

A Universal Molecular-Kinetic Scaling Relation for Slip of a Simple Fluid at a Solid Boundary

Using the observation that slip in simple fluids at low and moderate shear rates is a thermally activated process driven by the shear stress in the fluid close to the solid boundary, we develop a molecular-kinetic model for simple fluid slip at solid boundaries. The proposed model, which is in the form of a universal scaling relation that connects slip and shear rate, reduces to the well known Navier-slip condition under low shear conditions, providing a direct connection between molecular parameters and the slip length. Molecular-dynamics simulations are in very good agreement with the predicted dependence of slip on system parameters, including the temperature and fluid-solid interaction strength. Connections between our model and previous work, as well as simulation and experimental results are explored and discussed

Biomechanical Model for Evaluation of Pediatric Upper Extremity Joint Dynamics During Wheelchair Mobility

Pediatric manual wheelchair users (MWU) require high joint demands on their upper extremity (UE) during wheelchair mobility, leading them to be at risk of developing pain and pathology. Studies have examined UE biomechanics during wheelchair mobility in the adult population; however, current methods for evaluating UE joint dynamics of pediatric MWU are limited. An inverse dynamics model is proposed to characterize three-dimensional UE joint kinematics and kinetics during pediatric wheelchair mobility using a SmartWheel instrumented handrim system. The bilateral model comprises thorax, clavicle, scapula, upper arm, forearm, and hand segments and includes the sternoclavicular, acromioclavicular, glenohumeral, elbow and wrist joints. A single 17 year-old male with a C7 spinal cord injury (SCI) was evaluated while propelling his wheelchair across a 15-meter walkway. The subject exhibited wrist extension angles up to 60°, large elbow ranges of motion and peak glenohumeral joint forces up to 10% body weight. Statistically significant asymmetry of the wrist, elbow, glenohumeral and acromioclavicular joints was detected by the model. As demonstrated, the custom bilateral UE pediatric model may provide considerable quantitative insight into UE joint dynamics to improve wheelchair prescription, training, rehabilitation and long-term care of children with orthopedic disabilities. Further research is warranted to evaluate pediatric wheelchair mobility in a larger population of children with SCI to investigate correlations to pain, function and transitional changes to adulthood

IMPACT OF STRATEGIC CHANGES ON THE PERFORMANCE OF TRUCKING FIRMS IN THE AGRICULTURAL COMMODITY TRANSPORTATION MARKET

Econometric models were developed to estimate factors that influence strategic changes and evaluate the impacts that strategic changes will have on the subsequent performance of agricultural commodity trucking firms. Results reveal that GDP and change in firm size will have positive impacts on strategic changes made by firms.Public Economics,

Fermions, Gauge Theories, and the Sinc Function Representation for Feynman Diagrams

We extend our new approach for numeric evaluation of Feynman diagrams to integrals that include fermionic and vector propagators. In this initial discussion we begin by deriving the Sinc function representation for the propagators of spin-1/2 and spin-1 fields and exploring their properties. We show that the attributes of the spin-0 propagator which allowed us to derive the Sinc function representation for scalar field Feynman integrals are shared by fields with non-zero spin. We then investigate the application of the Sinc function representation to simple QED diagrams, including first order corrections to the propagators and the vertex.Comment: 10 pages, Latex, 9 figure

Retrieve Optically Thick Ice Cloud Microphysical Properties by Using Airborne Dual-Wavelength Radar Measurements

An algorithm to retrieve optically thick ice cloud microphysical property profiles is developed by using the GSFC 9.6 GHz ER-2 Doppler Radar (EDOP) and the 94 GHz Cloud Radar System (CRS) measurements aboard the high-altitude ER-2 aircraft. In situ size distribution and total water content data from the CRYSTAL-FACE field campaign are used for the algorithm development. To reduce uncertainty in calculated radar reflectivity factors (Ze) at these wavelengths, coincident radar measurements and size distribution data are used to guide the selection of mass-length relationships and to deal with the density and non-spherical effects of ice crystals on the Ze calculations. The algorithm is able to retrieve microphysical property profiles of optically thick ice clouds, such as, deep convective and anvil clouds, which are very challenging for single frequency radar and lidar. Examples of retrieved microphysical properties for a deep convective clouds are presented, which show that EDOP and CRS measurements provide rich information to study cloud structure and evolution. Good agreement between IWPs derived from an independent submillimeter-wave radiometer, CoSSIR, and dual-wavelength radar measurements indicates accuracy of the IWC retrieved from the two-frequency radar algorithm

Analysis of Temperature Dependence for a Ratiometric Wavelength Measurement System Using SMS Fiber Structure Based Edged Filters

Temperature dependence of an edge filter based on singlemode-multimodesinglemode (SMS) fiber structure is investigated numerically and experimentally. The experimental results and numerical results are in good agreement within an operational temperature range from 10 to 40 oC. It is found that the thermo-optic coefficient (TOC) has a more significant effect on the temperature dependence of an SMS edge filter compared to the thermal expansion coefficient (TEC). In the ratiometric wavelength measurement using two SMS edge filters, a small temperature variation can induce the ratio variation and in turn the wavelength measurement error. It is found the SMS edge filter’s response to both wavelength and temperature is linear. It is proposed that self monitoring of temperature can be carried out using an updated ratiometric scheme. Selfmonitoring of the temperature reduces temperature induced wavelength error to ± 10.7 pm at 1545 nm, regardless of the ambient temperature variation

High-Sensitivity Salinity Sensor Based on Optical Microfiber Coil Resonator

In recent years, salinity sensing has attracted much attention in potential areas ranging from marine monitoring, marine circulation, marine climate and environment protection in oceanography [1–4]. Generally, traditional methods of salinity measurement have been based on electronic methods (electrochemical) to detect the existence of chlorine ions of the seawater [5,6]. However, this method is affected greatly from the harsh environment, such as high corrosivity, extreme temperature and strong electromagnetic interference and is not used widely in micro scale due to its large size and complex structure. Electrochemical sensors are also prone to cross-sensitivity from and can even be damaged by other species e.g. nitrates (from Agriculture) and Sulphuric compounds (e.g. from dissolved SO2) Therefore, there is a clear need for new sensors with compact size, high stability, good selectivity and electromagnetic immunity

Quantum transport theory for nanostructures with Rashba spin-orbital interaction

We report on a general theory for analyzing quantum transport through devices in the Metal-QD-Metal configuration where QD is a quantum dot or the device scattering region which contains Rashba spin-orbital and electron-electron interactions. The metal leads may or may not be ferromagnetic, they are assumed to weakly couple to the QD region. Our theory is formulated by second quantizing the Rashba spin-orbital interaction in spectral space (instead of real space), and quantum transport is then analyzed within the Keldysh nonequilibrium Green's function formalism. The Rashba interaction causes two main effects to the Hamiltonian: (i) it gives rise to an extra spin-dependent phase factor in the coupling matrix elements between the leads and the QD; (ii) it gives rise to an inter-level spin-flip term but forbids any intra-level spin-flips. Our formalism provides a starting point for analyzing many quantum transport issues where spin-orbital effects are important. As an example, we investigate transport properties of a Aharnov-Bohm ring in which a QD having Rashba spin-orbital and e-e interactions is located in one arm of the ring. A substantial spin-polarized conductance or current emerges in this device due to a combined effect of a magnetic flux and the Rashba interaction. The direction and strength of the spin-polarization are shown to be controllable by both the magnetic flux and a gate voltage.Comment: 12 pages, 8 figure

Variability Improvement by Interface Passivation and EOT Scaling of InGaAs Nanowire MOSFETs

High-performance InGaAs gate-all-around (GAA) nanowire MOSFETs with channel length ($L_{ch}$) down to 20 nm are fabricated by integrating a higher-k $LaAlO_3$-based gate-stack with an equivalent oxide thickness of 1.2nm. It is found that inserting an ultrathin (0.5 nm) $Al_2O_3$ interfacial layer between the higher k $LaAlO_3$ and InGaAs can significantly improve the interface quality and reduce device variation. As a result, a record low subthreshold swing of 63 mV/dec is demonstrated at sub-80-nm $L_{ch}$ for the first time, making InGaAs GAA nanowire devices a strong candidate for future low-power transistors.Chemistry and Chemical Biolog