Thermal pulse energy harvesting

This paper presents a new method to enhance thermal energy harvesting with pulsed heat transfer. By creating a phase shift between the hot and cold sides of an energy harvester, periodically pulsed heat flow can allow an available temperature gradient to be concentrated over a heat engine during each thermal pulse, rather than divided between the heat engine and a heat sink. This effect allows the energy harvester to work at maximum power and efficiency despite an otherwise unfavorable heat engine–heat sink thermal resistance ratio. In this paper, the analysis of a generalized energy harvester model and experiments with a mechanical thermal switch demonstrate how the pulse mode can improve the efficiency of a system with equal engine and heat sink thermal resistances by over 80%, although at reduced total power. At a 1:2 engine–sink resistance ratio, the improvement can simultaneously exceed 60% in power and 15% in efficiency. The thermal pulse strategy promises to enhance the efficiency and power density of a variety of systems that convert thermal energy, from waste heat harvesters to the radioisotope power systems on many spacecraft

A linear mixed model analysis of the APOE4 gene with the logical memory test total score in Alzheimer’s disease

Linear mixed model (LMM) has the advantage of modeling the corelated data. Alzheimer’s disease (AD) is a chronic neurogenerative disease that affects the brain of the subject. No study was found to study the longitudinal effect of apolipoprotein E epsilon 4 (APOE4) genotype on the logical memory test total score in AD. A longitudinal data of 844 with AD, 2167 with cognitive normal (CN), and 4472 with mild cognitive impairment (MCI) participants who underwent logical memory examination test in the Alzheimer\u27s Disease Neuroimaging Initiative (ADNI) were investigated. Episodic memory of the study participants was monitored based on a short story told to the participants and then participants asked to recall what was told. The multivariate LMM was used to determine the longitudinal changes in the logical memory test total score adjusting for age and sex. The Akaike information criterion (AIC) statistic and the Bayesian information criterion (BIC) statistic were used to select the best covariance structure. The repeated measures longitudinal analysis was performed using PROC MIXED in SAS 9.4. Both AIC and BIC statistics favor the unstructured correlated structure (UN). Using a UN model in the LMM, the APOE gene was is significantly associated with logical memory test total score (pUN covariance structure is the best. This study provided the first evidence of the effect of APOE4 genotype on the logical memory related to AD

Modeling and optimization of hybrid solar thermoelectric systems with thermosyphons

We present the modeling and optimization of a new hybrid solar thermoelectric (HSTE) system which uses a thermosyphon to passively transfer heat to a bottoming cycle for various applications. A parabolic trough mirror concentrates solar energy onto a selective surface coated thermoelectric to produce electrical power. Meanwhile, a thermosyphon adjacent to the back side of the thermoelectric maintains the temperature of the cold junction and carries the remaining thermal energy to a bottoming cycle. Bismuth telluride, lead telluride, and silicon germanium thermoelectrics were studied with copper–water, stainless steel–mercury, and nickel–liquid potassium thermosyphon-working fluid combinations. An energy-based model of the HSTE system with a thermal resistance network was developed to determine overall performance. In addition, the HSTE system efficiency was investigated for temperatures of 300–1200 K, solar concentrations of 1–100 suns, and different thermosyphon and thermoelectric materials with a geometry resembling an evacuated tube solar collector. Optimizations of the HSTE show ideal system efficiencies as high as 52.6% can be achieved at solar concentrations of 100 suns and bottoming cycle temperatures of 776 K. For solar concentrations less than 4 suns, systems with thermosyphon wall thermal conductivities as low as 1.2 W/mK have comparable efficiencies to that of high conductivity material thermosyphons, i.e. copper, which suggests that lower cost materials including glass can be used. This work provides guidelines for the design, as well as the optimization and selection of thermoelectric and thermosyphon components for future high performance HSTE systems.United States. Dept. of Energy. Office of Basic Energy Sciences (MIT S3TEC Center, an Energy Frontier Research Center)Natural Sciences and Engineering Research Council of Canad

Growth Dynamics During Dropwise Condensation on Nanostructured Superhydrophobic Surfaces

Condensation on superhydrophobic nanostructured surfaces offers new opportunities for enhanced energy conversion, efficient water harvesting, and high performance thermal management. Such surfaces are designed to be Cassie stable, which minimize contact line pinning and allow for passive shedding of condensed water droplets at sizes smaller than the capillary length. In this work, we investigated in situ water condensation on superhydrophobic nanostructured surfaces using environmental scanning electron microscopy (ESEM). The "Cassie stable" surfaces consisted of silane coated silicon nanopillars with diameters of 300 nm, heights of 6.1 μm, and spacings of 2 μm, but allowed droplets of distinct suspended (S) and partially wetting (PW) morphologies to coexist. With these experiments combined with thermal modeling of droplet behavior, the importance of initial growth rates and droplet morphology on heat transfer is elucidated. The effect of wetting morphology on heat transfer enhancement is highlighted with observed 6× higher initial growth rate of PW droplets compared to S droplets. Consequently, the heat transfer of the PW droplet is 4-6× higher than that of the S droplet. To compare the heat transfer enhancement, PW and S droplet heat transfer rates are compared to that of a flat superhydrophobic silane coated surface, showing a 56% enhancement for the PW morphology, and 71% degradation for the S morphology. This study provides insight into importance of local wetting morphology on droplet growth rate during superhydrophobic condensation, as well as the importance of designing CB stable surfaces with PW droplet morphologies to achieve enhanced heat transfer during dropwise condensation. Topics: Dynamics (Mechanics), CondensationUnited States. Department of Energy. Office of Science. Solid-State Solar Thermal Energy Conversion Cente

Capillary-Limited Evaporation From Well-Defined Microstructured Surfaces

Thermal management is increasingly becoming a bottleneck for a variety of high power density applications such as integrated circuits, solar cells, microprocessors, and energy conversion devices. The performance and reliability of these devices are usually limited by the rate at which heat can be removed from the device footprint, which averages well above 100 W/cm[superscript 2] (locally this heat flux can exceed 1000 W/cm[superscript 2]). State-of-the-art air cooling strategies which utilize the sensible heat are insufficient at these large heat fluxes. As a result, novel thermal management solutions such as via thin-film evaporation that utilize the latent heat of vaporization of a fluid are needed. The high latent heat of vaporization associated with typical liquidvapor phase change phenomena allows significant heat transfer with small temperature rise. In this work, we demonstrate a promising thermal management approach where square arrays of cylindrical micropillar arrays are used for thin-film evaporation. The microstructures control the liquid film thickness and the associated thermal resistance in addition to maintaining a continuous liquid supply via the capillary pumping mechanism. When the capillary-induced liquid supply mechanism cannot deliver sufficient liquid for phase change heat transfer, the critical heat flux is reached and dryout occurs. This capillary limitation on thin-film evaporation was experimentally investigated by fabricating well-defined silicon micropillar arrays using standard contact photolithography and deep reactive ion etching. A thin film resistive heater and thermal sensors were integrated on the back side of the test sample using e-beam evaporation and acetone lift-off. The experiments were carried out in a controlled environmental chamber maintained at the water saturation pressure of ≈3.5 kPa and ≈25 °C. We demonstrated significantly higher heat dissipation capability in excess of 100 W/cm[superscript 2]. These preliminary results suggest the potential of thin-film evaporation from microstructured surfaces for advanced thermal management applications.United States. Office of Naval ResearchNational Science Foundation (U.S.). Graduate Research Fellowship ProgramBattell

HEAT TRANSFER FLUIDS

The choice of heat transfer fluids has significant effects on the performance, cost, and reliability of solar thermal systems. In this chapter, we evaluate existing heat transfer fluids such as oils and molten salts based on a new figure of merit capturing the combined effects of thermal storage capacity, convective heat transfer characteristics, and hydraulic performance of the fluids. Thermal stability, freezing point, and safety issues are also discussed. Through a comparative analysis, we examine alternative options for solar thermal heat transfer fluids including water−steam mixtures (direct steam), ionic liquids/melts, and suspensions of nanoparticles (nanofluids), focusing on the benefits and technical challenges.Center for Clean Water and Clean Energy at MIT and KFUPM (Project 6918351)United States. Dept. of Energy. Office of Science (Solid-State Solar-Thermal Energy Conversion Center Award DE-SC0001299

Improved Thermal Transfer Efficiency for Planar Solar Thermophotovoltaic Devices

Solar thermophotovoltaic (STPV) devices provide conversion of solar energy to electrical energy through the use of an intermediate absorber/emitter module, which converts the broad solar spectrum to a tailored spectrum that is emitted towards a photovoltaic cell. While the use of an absorber/emitter device could potentially overcome the Shockley-Queisser limit of photovoltaic conversion, it also increases the number of heat loss mechanisms. One of the most prohibitive aspects of STPV conversion is the thermal transfer efficiency, which is a measure of how well solar energy is delivered to the emitter. Although reported thermophotovoltaic efficiencies (thermal to electric) have exceeded 10%, previously measured STPV conversion efficiencies are below 1%. In this work, we present the design and characterization of a nanostructured absorber for use in a planar STPV device with a high emitter-to-absorber area ratio. We used a process for spatially-selective growth of vertically aligned multi-walled carbon nanotube (MWCNT) forests on highly reflective, smooth tungsten (W) surfaces. We implemented these MWCNT/W absorbers in a TPV system with a one-dimensional photonic crystal emitter, which was spectrally paired with a low bandgap PV cell. A high fidelity, system-level model of the radiative transfer in the device was experimentally validated and used to optimize the absorber surface geometry. For an operating temperature of approximately 1200 K, we experimentally demonstrated a 100% increase in overall STPV efficiency using a 4 to 1 emitter-to-absorber area ratio (relative to a 1 to 1 area ratio), due to improved thermal transfer efficiency. By further increasing the solar concentration incident on the absorber surface, increased emitter-to-absorber area ratios will improve both thermal transfer and overall efficiencies for these planar devices. Topics: Solar energyUnited States. Department of Energy. Office of Basic Energy Sciences (MIT S3TEC Energy Research Frontier Center of the Department of Energy. DE-FG02-09ER46577)MIT Energy Initiativ

Wide-field Magnetic Field and Temperature Imaging using Nanoscale Quantum Sensors

The simultaneous imaging of magnetic fields and temperature (MT) is important in a range of applications, including studies of carrier transport, solid-state material dynamics, and semiconductor device characterization. Techniques exist for separately measuring temperature (e.g., infrared (IR) microscopy, micro-Raman spectroscopy, and thermo-reflectance microscopy) and magnetic fields (e.g., scanning probe magnetic force microscopy and superconducting quantum interference devices). However, these techniques cannot measure magnetic fields and temperature simultaneously. Here, we use the exceptional temperature and magnetic field sensitivity of nitrogen vacancy (NV) spins in conformally-coated nanodiamonds to realize simultaneous wide-field MT imaging. Our "quantum conformally-attached thermo-magnetic" (Q-CAT) imaging enables (i) wide-field, high-frame-rate imaging (100 - 1000 Hz); (ii) high sensitivity; and (iii) compatibility with standard microscopes. We apply this technique to study the industrially important problem of characterizing multifinger gallium nitride high-electron-mobility transistors (GaN HEMTs). We spatially and temporally resolve the electric current distribution and resulting temperature rise, elucidating functional device behavior at the microscopic level. The general applicability of Q-CAT imaging serves as an important tool for understanding complex MT phenomena in material science, device physics, and related fields

Evaporation-Induced Cassie Droplets on Superhydrophilic Microstructured Surfaces

A droplet deposited on a rough, lyophilic surface satisfying the imbibition condition, results in complete wetting. However, in this work, we demonstrate that this behavior can be altered by superheating the substrate such that droplets can reside in a non-wetting Cassie state due to evaporation. Photolithography and deep reactive ion etching were used to fabricate a well-defined silicon micropillar array with diameter, height, and center-to-center spacings of 5.3, 21.7 and 27.5 μm, respectively. Water droplets placed on this microstructured surface at room temperature demonstrated superhydrophilic behavior with liquid filling the voids between pillars resulting in a vanishing contact angle. However, when the microstructured surface was superheated above a critical value, the superhydrophilicity was lost and non-wetting Cassie droplets were formed. The superheat required to deposit a Cassie droplet (>75°C) was found to be significantly higher than that required to sustain an already deposited Cassie droplet (<35°C). Interestingly, the superheat required to sustain a Cassie droplet after the initial deposition was found to decrease with the square of the droplet radius. These observations where an inherently superhydrophilic structured surface turns into superhydrophobic at nominal superheats has implications for phase change based heat transfer applications where the loss of contact between the substrate and the heat transfer fluid can be detrimental to the device performance. Topics: Drops, EvaporationUnited States. Office of Naval Researc

Characterization of Lipid Membrane Properties for Tunable Electroporation

Lipid bilayers form nanopores on the application of an electric field. This process of electroporation can be utilized in different applications ranging from targeted drug delivery in cells to nano-gating membrane for engineering applications. However, the ease of electroporation is dependent on the surface energy of the lipid layers and thus directly related to the packing structure of the lipid molecules. 1,2- dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) lipid monolayers were deposited on a mica substrate using the Langmuir-Blodgett (LB) technique at different packing densities and analyzed using atomic force microscopy (AFM). The wetting behavior of these monolayers was investigated by contact angle measurement and molecular dynamics simulations. It was found that an equilibrium packing density of liquid-condensed (LC) phase DPPC likely exists and that water molecules can penetrate the monolayer displacing the lipid molecules. The surface tension of the monolayer in air and water was obtained along with its breakthrough force. Topics: Membranes, ElectroporationNational Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program