A sustainable biochar catalyst synergized with copper heteroatoms and CO2 for singlet oxygenation and electron transfer routes

We have developed a wood waste-derived biochar as a sustainable graphitic carbon catalyst for environmental remediation through catalytic pyrolysis under the synergistic effects between Cu heteroatoms and CO2, which for the first time are found to significantly enhance the oxygen functionalities, defective sites, and highly ordered sp2-hybridized carbon matrix. The copper-doped graphitic biochars (Cu-GBCs) were further characterized by XRD, FTIR, Raman, XPS, etc., revealing that the modified specific surface area, pore structure, graphitization, and active sites (i.e., defective sites and ketonic group) on the Cu-GBCs corresponded to the synergistic Cu species loading and Cu-induced carbon-matrix reformation in CO2 environment during pyrolysis. The catalytic ability of Cu-GBCs was evaluated using the ubiquitous peroxydisulfate (PDS) activation system for the removal of various organic contaminants (i.e., rhodamine B, phenol, bisphenol A, and 4-chlorophenol), and gave the highest degradation rate of 0.0312 min-1 in comparison with those of pristine GBCs and N2-pyrolyzed Cu-GBCs ranging from 0.0056 to 0.0094 min-1. The synergistic effects were attributed to the encapsulated Cu heteroatoms, evolved ketonic groups, and abundant unconfined π electrons within the carbon lattice. According to scavenger experiments, ESR analysis, and two-chamber experiments, selective and sustainable non-radical pathways (i.e., singlet oxygenation and electron transfer) mediated by the Cu-induced metastable surface complex were achieved in the Cu-GBC/PDS system. This study offers the first insights into the efficacy, sustainability, and mechanistic roles of Cu-GBCs as an emerging carbon-based catalyst for green environmental remediation

Effect of Fuel-Injection Distance and Cavity Rear-Wall Height on the Flameholding Characteristics in a Mach 2.52 Supersonic Flow

The ethylene-fueled flameholding characteristics of a cavity-based scramjet combustor are experimentally and numerically investigated. The test facility used the air heater, which heats air from room temperature to total temperature 1477 K. A nozzle is installed behind the heater outlet to increase the air speed to Mach 2.52. Two cavity geometries with different rear-wall heights of 8 mm and 10 mm and two injection distances upstream of the cavities of 10 mm and 40 mm are compared to show the effect of these parameters. The CH* spontaneous emission images obtained by dual-camera synchronous shooting and the wall-pressure distribution obtained by a pressure-scan system are used to capture the flame dynamics. The global equivalence ratio range for different combination schemes is controlled from 0.14 to 0.27 in this paper. The results show that the conventional cavity (the rear-wall height is 10 mm) and the shorter injection distance can effectively decrease the lean blowoff limit of the combustor, while the rear-wall-expansion cavity (the rear-wall height is 8 mm) and the longer injection distance can effectively increase the rich blowoff limit. Compared with the injection distance, the rear-wall height of the cavity has little effect on the oscillation distribution of the shear layer-stabilized flame. However, the fuel-injection distance and cavity rear-wall height both have great influence on the spatial distribution of the flame

Effect of Fuel-Injection Distance and Cavity Rear-Wall Height on the Flameholding Characteristics in a Mach 2.52 Supersonic Flow

The ethylene-fueled flameholding characteristics of a cavity-based scramjet combustor are experimentally and numerically investigated. The test facility used the air heater, which heats air from room temperature to total temperature 1477 K. A nozzle is installed behind the heater outlet to increase the air speed to Mach 2.52. Two cavity geometries with different rear-wall heights of 8 mm and 10 mm and two injection distances upstream of the cavities of 10 mm and 40 mm are compared to show the effect of these parameters. The CH* spontaneous emission images obtained by dual-camera synchronous shooting and the wall-pressure distribution obtained by a pressure-scan system are used to capture the flame dynamics. The global equivalence ratio range for different combination schemes is controlled from 0.14 to 0.27 in this paper. The results show that the conventional cavity (the rear-wall height is 10 mm) and the shorter injection distance can effectively decrease the lean blowoff limit of the combustor, while the rear-wall-expansion cavity (the rear-wall height is 8 mm) and the longer injection distance can effectively increase the rich blowoff limit. Compared with the injection distance, the rear-wall height of the cavity has little effect on the oscillation distribution of the shear layer-stabilized flame. However, the fuel-injection distance and cavity rear-wall height both have great influence on the spatial distribution of the flame