37,671 research outputs found
Growth of Epitaxial Oxide Thin Films on Graphene
The transfer process of graphene onto the surface of oxide substrates is well known. However, for many devices, we require high quality oxide thin films on the surface of graphene. This step is not understood. It is not clear why the oxide should adopt the epitaxy of the underlying oxide layer when it is deposited on graphene where there is no lattice match. To date there has been no explanation or suggestion of mechanisms which clarify this step. Here we show a mechanism, supported by first principles simulation and structural characterisation results, for the growth of oxide thin films on graphene. We describe the growth of epitaxial SrTiO3 (STO) thin films on a graphene and show that local defects in the graphene layer (e.g. grain boundaries) act as bridgepillar spots that enable the epitaxial growth of STO thin films on the surface of the graphene layer. This study, and in particular the suggestion of a mechanism for epitaxial growth of oxides on graphene, offers new directions to exploit the development of oxide/graphene multilayer structures and devices
The Electromagnetic Self-Energy Contribution to M_p - M_n and the Isovector Nucleon Magnetic Polarizability
We update the determination of the isovector nucleon electromagnetic
self-energy, valid to leading order in QED. A technical oversight in the
literature concerning the elastic contribution to Cottingham's formula is
corrected and modern knowledge of the structure functions is used to precisely
determine the inelastic contribution. We find \delta M_{p-n}^\gamma =
1.30(03)(47) MeV. The largest uncertainty arises from a subtraction term
required in the dispersive analysis, which can be related to the isovector
magnetic polarizability. With plausible model assumptions, we can combine our
calculation with additional input from lattice QCD to constrain this
polarizability as: \beta_{p-n} = -0.87(85) x 10^{-4} fm^3.Comment: 5 pages, version accepted for publication in PR
Magnetic excitations in vanadium spinels
We study magnetic excitations in vanadium spinel oxides AVO (A=Zn,
Mg, Cd) using two models: first one is a superexchange model for vanadium S=1
spins, second one includes in addition spin-orbit coupling, and crystal
anisotropy. We show that the experimentally observed magnetic ordering can be
obtained in both models, however the orbital ordering is different with and
without spin-orbit coupling and crystal anisotropy. We demonstrate that this
difference strongly affects the spin-wave excitation spectrum above the
magnetically ordered state, and argue that the neutron measurement of such
dispersion is a way to distinguish between the two possible orbital orderings
in AVO.Comment: accepted in Phys. Rev.
Cofactor regeneration by a soluble pyridine nucleotide transhydrogenase for biological production of hydromorphone
We have applied the soluble pyridine nucleotide transhydrogenase of Pseudomonas fluorescens to a cell-free system for the regeneration of the nicotinamide cofactors NAD and NADP in the biological production of the important semisynthetic opiate drug hydromorphone. The original recombinant whole-cell system suffered from cofactor depletion resulting from the action of an NADP(+)-dependent morphine dehydrogenase and an NADH-dependent morphinone reductase. By applying a soluble pyridine nucleotide transhydrogenase, which can transfer reducing equivalents between NAD and NADP, we demonstrate with a cell-free system that efficient cofactor cycling in the presence of catalytic amounts of cofactors occurs, resulting in high yields of hydromorphone. The ratio of morphine dehydrogenase, morphinone reductase, and soluble pyridine nucleotide transhydrogenase is critical for diminishing the production of the unwanted by-product dihydromorphine and for optimum hydromorphone yields. Application of the soluble pyridine nucleotide transhydrogenase to the whole-cell system resulted in an improved biocatalyst with an extended lifetime. These results demonstrate the usefulness of the soluble pyridine nucleotide transhydrogenase and its wider application as a tool in metabolic engineering and biocatalysis
Systematic derivation of a surface polarization model for planar perovskite solar cells
Increasing evidence suggests that the presence of mobile ions in perovskite
solar cells can cause a current-voltage curve hysteresis. Steady state and
transient current-voltage characteristics of a planar metal halide
CHNHPbI perovskite solar cell are analysed with a drift-diffusion
model that accounts for both charge transport and ion vacancy motion. The high
ion vacancy density within the perovskite layer gives rise to narrow Debye
layers (typical width 2nm), adjacent to the interfaces with the transport
layers, over which large drops in the electric potential occur and in which
significant charge is stored. Large disparities between (I) the width of the
Debye layers and that of the perovskite layer (600nm) and (II) the ion
vacancy density and the charge carrier densities motivate an asymptotic
approach to solving the model, while the stiffness of the equations renders
standard solution methods unreliable. We derive a simplified surface
polarisation model in which the slow ion dynamic are replaced by interfacial
(nonlinear) capacitances at the perovskite interfaces. Favourable comparison is
made between the results of the asymptotic approach and numerical solutions for
a realistic cell over a wide range of operating conditions of practical
interest.Comment: 32 pages, 7 figure
Powertrain dynamics and control of a two speed dual clutch transmission for electric vehicles
© 2016 Elsevier Ltd The purpose of this paper is to demonstrate the application of torque based powertrain control for multi-speed power shifting capable electric vehicles. To do so simulation and experimental studies of the shift transient behaviour of dual clutch transmission equipped electric vehicle powertrains is undertaken. To that end a series of power-on and power-off shift control strategies are then developed for both up and down gear shifts, taking note of the friction load requirements to maintain positive driving load for power-on shifting. A mathematical model of an electric vehicle powertrain is developed including a DC equivalent circuit model for the electric machine and multi-body dynamic model of the powertrain system is then developed and integrated with a hydraulic clutch control system model. Integral control of the powertrain is then performed through simulations on the develop powertrain system model for each of the four shift cases. These simulation results are then replicated on a full scale powertrain test rig. To evaluate the performance of results shift duration and vehicle jerk are used as metrics to demonstrate that the presented strategies are effective for shift control in electric vehicles. Qualitative comparison of both theoretical and experimental results demonstrates reasonable agreement between simulated and experimental outcomes
Investigating the source of Planck-detected AME: high resolution observations at 15 GHz
The Planck 28.5 GHz maps were searched for potential Anomalous Microwave
Emission (AME) regions on the scale of or smaller, and several
new regions of interest were selected. Ancillary data at both lower and higher
frequencies were used to construct spectral energy distributions (SEDs), which
seem to confirm an excess consistent with spinning dust models. Here we present
higher resolution observations of two of these new regions with the Arcminute
Microkelvin Imager Small Array (AMI SA) between 14 and 18 GHz to test for the
presence of a compact (10 arcmin or smaller) component. For
AME-G107.1+5.2, dominated by the {\sc Hii} region S140, we find evidence for
the characteristic rising spectrum associated with the either the spinning dust
mechanism for AME or an ultra/hyper-compact \textsc{Hii} region across the AMI
frequency band, however for AME-G173.6+2.8 we find no evidence for AME on
scales of arcmin.Comment: 13 pages, 8 figures, 4 tables. Submitted to Advances in Astronomy AME
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