1,714 research outputs found
Prediction of long and short time rheological behavior in soft glassy materials
We present an effective time approach to predict long and short time
rheological behavior of soft glassy materials from experiments carried out over
practical time scales. Effective time approach takes advantage of relaxation
time dependence on aging time that allows time-aging time superposition even
when aging occurs over the experimental timescales. Interestingly experiments
on variety of soft materials demonstrate that the effective time approach
successfully predicts superposition for diverse aging regimes ranging from
sub-aging to hyper-aging behaviors. This approach can also be used to predict
behavior of any response function in molecular as well as spin glasses.Comment: 13 pages, 4 figure
Stress release mechanisms for Cu on Pd(111) in the submonolayer and monolayer regimes
We study the strain relaxation mechanisms of Cu on Pd(111) up to the
monolayer regime using two different computational methodologies, basin-hopping
global optimization and energy minimization with a repulsive bias potential.
Our numerical results are consistent with experimentally observed
layer-by-layer growth mode. However, we find that the structure of the Cu layer
is not fully pseudomorphic even at low coverages. Instead, the Cu adsorbates
forms fcc and hcp stacking domains, separated by partial misfit dislocations.
We also estimate the minimum energy path and energy barriers for transitions
from the ideal epitaxial state to the fcc-hcp domain pattern.Comment: 4 pages, 4 figure
Non-covalent interactions across organic and biological subsets of chemical space: Physics-based potentials parametrized from machine learning
Classical intermolecular potentials typically require an extensive
parametrization procedure for any new compound considered. To do away with
prior parametrization, we propose a combination of physics-based potentials
with machine learning (ML), coined IPML, which is transferable across small
neutral organic and biologically-relevant molecules. ML models provide
on-the-fly predictions for environment-dependent local atomic properties:
electrostatic multipole coefficients (significant error reduction compared to
previously reported), the population and decay rate of valence atomic
densities, and polarizabilities across conformations and chemical compositions
of H, C, N, and O atoms. These parameters enable accurate calculations of
intermolecular contributions---electrostatics, charge penetration, repulsion,
induction/polarization, and many-body dispersion. Unlike other potentials, this
model is transferable in its ability to handle new molecules and conformations
without explicit prior parametrization: All local atomic properties are
predicted from ML, leaving only eight global parameters---optimized once and
for all across compounds. We validate IPML on various gas-phase dimers at and
away from equilibrium separation, where we obtain mean absolute errors between
0.4 and 0.7 kcal/mol for several chemically and conformationally diverse
datasets representative of non-covalent interactions in biologically-relevant
molecules. We further focus on hydrogen-bonded complexes---essential but
challenging due to their directional nature---where datasets of DNA base pairs
and amino acids yield an extremely encouraging 1.4 kcal/mol error. Finally, and
as a first look, we consider IPML in denser systems: water clusters,
supramolecular host-guest complexes, and the benzene crystal.Comment: 15 pages, 9 figure
The Glassy Wormlike Chain
We introduce a new model for the dynamics of a wormlike chain in an
environment that gives rise to a rough free energy landscape, which we baptise
the glassy wormlike chain. It is obtained from the common wormlike chain by an
exponential stretching of the relaxation spectrum of its long-wavelength
eigenmodes, controlled by a single stretching parameter. Predictions for
pertinent observables such as the dynamic structure factor and the
microrheological susceptibility exhibit the characteristics of soft glassy
rheology and compare favourably with experimental data for reconstituted
cytoskeletal networks and live cells. We speculate about the possible
microscopic origin of the stretching, implications for the nonlinear rheology,
and the potential physiological significance of our results.Comment: 12 pages, 8 figures. Minor correction
Deceptive signals of phase transitions in small magnetic clusters
We present an analysis of the thermodynamic properties of small transition
metal clusters and show how the commonly used indicators of phase transitions
like peaks in the specific heat or magnetic susceptibility can lead to
deceptive interpretations of the underlying physics. The analysis of the
distribution of zeros of the canonical partition function in the whole complex
temperature plane reveals the nature of the transition. We show that signals in
the magnetic susceptibility at positive temperatures have their origin at zeros
lying at negative temperatures.Comment: 4 pages, 5 figures, revtex4, for further information see
http://www.smallsystems.d
Energy Landscape and Global Optimization for a Frustrated Model Protein
The three-color (BLN) 69-residue model protein was designed to exhibit frustrated folding. We investigate the energy landscape of this protein using disconnectivity graphs and compare it to a Go model, which is designed to reduce the frustration by removing all non-native attractive interactions. Finding the global minimum on a frustrated energy landscape is a good test of global optimization techniques, and we present calculations evaluating the performance of basin-hopping and genetic algorithms for this system.Comparisons are made with the widely studied 46-residue BLN protein.We show that the energy landscape of the 69-residue BLN protein contains several deep funnels, each of which corresponds to a different β-barrel structure
Aging in a Colloidal Glass in Creep Flow: Time-Stress Superposition
In this work, we study ageing behavior of aqueous laponite suspension, a
model soft glassy material, in creep. We observe that viscoelastic behavior is
time dependent and is strongly influenced by the deformation field; the effect
is known to arise due to ageing and rejuvenation. We show that irrespective of
strength of deformation field (shear stress) and age, when imposed time-scale
is normalized with dominating relaxation mode of the system, universal ageing
behavior is obtained demonstrating time-stress superposition; the phenomena
that may be generic in variety of soft materials.Comment: 10 pages, 4 figure
Classification of phase transitions in small systems
We present a classification scheme for phase transitions in finite systems
like atomic and molecular clusters based on the Lee-Yang zeros in the complex
temperature plane. In the limit of infinite particle numbers the scheme reduces
to the Ehrenfest definition of phase transitions and gives the right critical
indices. We apply this classification scheme to Bose-Einstein condensates in a
harmonic trap as an example of a higher order phase transitions in a finite
system and to small Ar clusters.Comment: 12 pages, 4 figures, accepted for publication in Phys. Rev. Let
An investigation of standard thermodynamic quantities as determined via models of nuclear multifragmentation
Both simple and sophisticated models are frequently used in an attempt to
understand how real nuclei breakup when subjected to large excitation energies,
a process known as nuclear multifragmentation. Many of these models assume
equilibriumthermodynamics and produce results often interpreted as evidence of
a phase transition. This work examines one class of models and employs standard
thermodynamical procedure to explore the possible existence and nature of a
phase transition. The role of various terms, e.g. Coulomb and surface energy,
is discussed.Comment: 19 two-column format pages with 24 figure
Structural Transitions and Global Minima of Sodium Chloride Clusters
In recent experiments on sodium chloride clusters structural transitions
between nanocrystals with different cuboidal shapes were detected. Here we
determine reaction pathways between the low energy isomers of one of these
clusters, (NaCl)35Cl-. The key process in these structural transitions is a
highly cooperative rearrangement in which two parts of the nanocrystal slip
past one another on a {110} plane in a direction. In this way the
nanocrystals can plastically deform, in contrast to the brittle behaviour of
bulk sodium chloride crystals at the same temperatures; the nanocrystals have
mechanical properties which are a unique feature of their finite size. We also
report and compare the global potential energy minima for (NaCl)NCl- using two
empirical potentials, and comment on the effect of polarization.Comment: extended version, 13 pages, 8 figures, revte
- …