Anion permselective membrane

The efforts on the synthesis of polymer anion redox membranes were mainly concentrated in two areas, membrane development and membrane fabrication. Membrane development covered the preparation and evaluation of experimental membranes systems with improved resistance stability and/or lower permeability. Membrane fabrication covered the laboratory scale production of prime candidate membranes in quantities of up to two hundred and sizes up to 18 inches x 18 inches (46 cm x 46 cm). These small (10 in x 11 in) and medium sized membranes were mainly for assembly into multicell units. Improvements in processing procedures and techniques for preparing such membrane sets lifted yields to over 90 percent

Anion permselective membrane

The synthesis and fabrication of polymeric anion permselective membranes for redox systems are discussed. Variations of the prime candidate anion membrane formulation to achieve better resistance and/or lower permeability were explored. Processing parameters were evaluated to lower cost and fabricate larger sizes. The processing techniques to produce more membranes per batch were successfully integrated with the fabrication of larger membranes. Membranes of about 107 cm x 51 cm were made in excellent yield. Several measurements were made on the larger sample membranes. Among the data developed were water transport and transference numbers for these prime candidate membranes at 20 C. Other work done on this system included characterization of a number of specimens of candidate membranes which had been returned after service lives of up to sixteen months. Work with new polymer constituents, with new N.P.'s, catalysts and backing fabrics is discussed. Some work was also done to evaluate other proportions of the ingredients of the prime candidate system. The adoption of a flow selectivity test at elevated temperature was explored

Proceedings of the 1st Space Plasma Computer Analysis Network (SCAN) Workshop

The purpose of the workshop was to identify specific cooperative scientific study topics within the discipline of Ionosphere Magnetosphere Coupling processes and to develop methods and procedures to accomplish this cooperative research using SCAN facilities. Cooperative scientific research was initiated in the areas of polar cusp composition, O+ polar outflow, and magnetospheric boundary morphology studies and an approach using a common metafile structure was adopted to facilitate the exchange of data and plots between the various workshop participants. The advantages of in person versus remote workshops were discussed also

Latest results on Jovian disk X-rays from XMM-Newton

We present the results of a spectral study of the soft X-ray emission (0.2-2.5 keV) from low-latitude (`disk') regions of Jupiter. The data were obtained during two observing campaigns with XMM-Newton in April and November 2003. While the level of the emission remained approximately the same between April and the first half of the November observation, the second part of the latter shows an enhancement by about 40% in the 0.2-2.5 keV flux. A very similar, and apparently correlated increase, in time and scale, was observed in the solar X-ray and EUV flux. The months of October and November 2003 saw a period of particularly intense solar activity, which appears reflected in the behaviour of the soft X-rays from Jupiter's disk. The X-ray spectra, from the XMM-Newton EPIC CCD cameras, are all well fitted by a coronal model with temperatures in the range 0.4-0.5 keV, with additional line emission from Mg XI (1.35 keV) and Si XIII (1.86 keV): these are characteristic lines of solar X-ray spectra at maximum activity and during flares. The XMM-Newton observations lend further support to the theory that Jupiter's disk X-ray emission is controlled by the Sun, and may be produced in large part by scattering, elastic and fluorescent, of solar X-rays in the upper atmosphere of the planet.Comment: 17 pages, 7 figures, accepted for publication in a special issue of Planetary and Space Scienc

Fast and Slow Water Ion Populations in the Enceladus Plume

Ion velocities have been measured during the Enceladus E3 and E5 flybys using the Cassini Plasma Spectrometer (CAPS) instrument on the Cassini spacecraft. Data from three sensors in the CAPS instrument have been examined from two flybys that occurred during 2008. Positive ion measurements from the CAPS Ion Beam Spectrometer and Ion Mass Spectrometer have been used to measure positive ion velocities. The CAPS Electron Spectrometer has been used to complement the positive ion findings with measurements of negative ion velocities. Two velocities for the positive ions are found, with the fast ions (2.3–5.8 km/s) originating from the high‐speed neutral gas emission and slow ions (0.2–2.2 km/s) associated with the low‐speed thermal gas emission from Enceladus. Negative ions were found to be near stationary or northerly traveling, implying a deceleration mechanism within the plume. A tentative detection of fast negative ions was also recorded for one of the flybys. These findings will aid in future modeling of plume dynamics

Nitrogen and Hydrogen Plasma Treatments of Multiwalled Carbon Nanotubes

This article investigates plasma treatment of vertically aligned multiwall carbon nanotube (CNT) films in different plasma environments for modification of surface chemistry and morphology. The surfaces of the CNTs were functionalized with a pulsed dc plasma treatment, where the power was directly applied to the nanotube film in low pressure argon/nitrogen and argon/hydrogen backgrounds. Optical emission spectroscopy was used to detect atomic and molecular excitations in the gas mixtures as well as in pure gases in the vicinity of the CNT films. In situx-ray photoelectron spectroscopy was performed on the treated samples to examine CNT surface chemistry after treatment. The analysis of CNT films after nitrogen and hydrogen treatment indicated formation of both C-N and C-H bonds, respectively. Correlations of the plasma characteristics to the surface chemistry and morphology of the CNT surfaces are discussed

Natural Connections Demonstration Project, 2012- 2016: Final Report

This report presents the key findings from the Natural Connections Demonstration Project, that aimed to encourage teachers to take curricular learning outdoors. The project was commissioned by DEFRA, Natural England and Historic England, and delivered by a team at Plymouth University. 125 schools contributed to the evaluation which found that: 1. schools most likely to engage with outdoor learning displayed strong leadership and were open-minded about trying new things 2. schools reported a statistically-significant increase in the amount of time spent on outdoor learning activity across the project 3. Schools adopted many different models of outdoor learning 4. Schools invested time, goodwill, energy and funding in outdoor learning 5. Over 90 per cent of responding schools agreed that outdoor learning was useful for curriculum delivery 6. Outdoor learning had positive impacts for teachers and pupils 7. the project model of distributed independent brokerage was found to have the capacity to unlock latent demand for outdoor learning in schools, and to support schools in embedding low-cost outdoor learning practice

DE 1 RIMS operational characteristics

The Retarding Ion Mass Spectrometer (RIMS) on the Dynamics Explorer 1 spacecraft observes both the thermal and superthermal (50 eV) ions of the ionosphere and inner magnetosphere. It is capable of measuring the detailed species distribution function of these ions in many cases. It was equipped with an integral electrometer to permit in-flight calibration of the detector sensitivities and variations thereof. A guide to understanding the RIMS data set is given. The reduction process from count rates to physical quantities is discussed in some detail. The procedure used to establish in-flight calibration is described, and results of a comparison with densities from plasma wave measurements are provided. Finally, a discussion is provided of various anomalies in the data set, including changes of channeltron efficiency with time, spin modulation of the axial sensor heads, apparent potential differences between the sensor heads, and failures of the radial head retarding potential sweep and of the -Z axial head aperture plane bias. Studies of the RIMS data set should be conducted only with a thorough awareness of the material presented here, or in collaboration with one of the scientists actively involved with RIMS data analysis