4,610 research outputs found
Orientation and Motion of Water Molecules at Air/Water Interface
Analysis of SFG vibrational spectra of OH stretching bands in four
experimental configurations shows that orientational motion of water molecule
at air/water interface is libratory within a limited angular range. This
picture is significantly different from the previous conclusion that the
interfacial water molecule orientation varies over a broad range within the
vibrational relaxation time, the only direct experimental evidence for
ultrafast and broad orientational motion of a liquid interface by Wei et al.
[Phys. Rev. Lett. 86, 4799, (2001)] using single SFG experimental
configuration
- …