Multiband photometry of a Patroclus-Menoetius mutual event: Constraints on surface heterogeneity

We present the first complete multiband observations of a binary asteroid mutual event. We obtained high-cadence, high-signal-to-noise photometry of the UT 2018 April 9 inferior shadowing event in the Jupiter Trojan binary system Patroclus-Menoetius in four Sloan bands $-$ $g'$, $r'$, $i'$, and $z'$. We use an eclipse lightcurve model to fit for a precise mid-eclipse time and estimate the minimum separation of the two eclipsing components during the event. Our best-fit mid-eclipse time of $2458217.80943^{+0.00057}_{-0.00050}$ is 19 minutes later than the prediction of Grundy et al. (2018); the minimum separation between the center of Menoetius' shadow and the center of Patroclus is $72.5\pm0.7$ km $-$ slightly larger than the predicted 69.5 km. Using the derived lightcurves, we find no evidence for significant albedo variations or large-scale topographic features on the Earth-facing hemisphere and limb of Patroclus. We also apply the technique of eclipse mapping to place an upper bound of $\sim$0.15 mag on wide-scale surface color variability across Patroclus.Comment: 5 pages, 3 figures, accepted for publication in A

Deep Uncertainty Surrounding Coastal Flood Risk Projections: A Case Study for New Orleans

Future sea-level rise drives severe risks for many coastal communities. Strategies to manage these risks hinge on a sound characterization of the uncertainties. For example, recent studies suggest that large fractions of the Antarctic ice sheet (AIS) may rapidly disintegrate in response to rising global temperatures, leading to potentially several meters of sea-level rise during the next few centuries. It is deeply uncertain, for example, whether such an AIS disintegration will be triggered, how much this would increase sea-level rise, whether extreme storm surges intensify in a warming climate, or which emissions pathway future societies will choose. Here, we assess the impacts of these deep uncertainties on projected flooding probabilities for a levee ring in New Orleans, Louisiana. We use 18 scenarios, presenting probabilistic projections within each one, to sample key deeply uncertain future projections of sea-level rise, radiative forcing pathways, storm surge characterization, and contributions from rapid AIS mass loss. The implications of these deep uncertainties for projected flood risk are thus characterized by a set of 18 probability distribution functions. We use a global sensitivity analysis to assess which mechanisms contribute to uncertainty in projected flood risk over the course of a 50-year design life. In line with previous work, we find that the uncertain storm surge drives the most substantial risk, followed by general AIS dynamics, in our simple model for future flood risk for New Orleans

Non-Empirically Tuned Range-Separated DFT Accurately Predicts Both Fundamental and Excitation Gaps in DNA and RNA Nucleobases

Using a non-empirically tuned range-separated DFT approach, we study both the quasiparticle properties (HOMO-LUMO fundamental gaps) and excitation energies of DNA and RNA nucleobases (adenine, thymine, cytosine, guanine, and uracil). Our calculations demonstrate that a physically-motivated, first-principles tuned DFT approach accurately reproduces results from both experimental benchmarks and more computationally intensive techniques such as many-body GW theory. Furthermore, in the same set of nucleobases, we show that the non-empirical range-separated procedure also leads to significantly improved results for excitation energies compared to conventional DFT methods. The present results emphasize the importance of a non-empirically tuned range-separation approach for accurately predicting both fundamental and excitation gaps in DNA and RNA nucleobases.Comment: Accepted by the Journal of Chemical Theory and Computatio

Primal and dual active-set methods for convex quadratic programming

Computational methods are proposed for solving a convex quadratic program (QP). Active-set methods are defined for a particular primal and dual formulation of a QP with general equality constraints and simple lower bounds on the variables. In the first part of the paper, two methods are proposed, one primal and one dual. These methods generate a sequence of iterates that are feasible with respect to the equality constraints associated with the optimality conditions of the primal-dual form. The primal method maintains feasibility of the primal inequalities while driving the infeasibilities of the dual inequalities to zero. The dual method maintains feasibility of the dual inequalities while moving to satisfy the primal inequalities. In each of these methods, the search directions satisfy a KKT system of equations formed from Hessian and constraint components associated with an appropriate column basis. The composition of the basis is specified by an active-set strategy that guarantees the nonsingularity of each set of KKT equations. Each of the proposed methods is a conventional active-set method in the sense that an initial primal- or dual-feasible point is required. In the second part of the paper, it is shown how the quadratic program may be solved as a coupled pair of primal and dual quadratic programs created from the original by simultaneously shifting the simple-bound constraints and adding a penalty term to the objective function. Any conventional column basis may be made optimal for such a primal-dual pair of shifted-penalized problems. The shifts are then updated using the solution of either the primal or the dual shifted problem. An obvious application of this approach is to solve a shifted dual QP to define an initial feasible point for the primal (or vice versa). The computational performance of each of the proposed methods is evaluated on a set of convex problems.Comment: The final publication is available at Springer via http://dx.doi.org/10.1007/s10107-015-0966-

Photometry of active Centaurs: Colors of dormant active Centaur nuclei

We present multiband photometric observations of nine Centaurs. Five of the targets are known active Centaurs (167P/CINEOS, 174P/Echeclus, P/2008 CL94, P/2011 S1, and C/2012 Q1), and the other four are inactive Centaurs belonging to the redder of the two known color subpopulations (83982 Crantor, 121725 Aphidas, 250112 2002 KY14, and 281371 2008 FC76). We measure the optical colors of eight targets and carry out a search for cometary activity. In addition to the four inactive Centaurs, three of the five active Centaurs showed no signs of activity at the time of observation, yielding the first published color measurements of the bare nuclei of 167P and P/2008 CL94 without possible coma contamination. Activity was detected on P/2011 S1 and C/2012 Q1, yielding relatively high estimated mass loss rates of $140\pm20$ and $250\pm40$ kg/s, respectively. The colors of the dormant nuclei are consistent with the previously-published colors, indicating that any effect of non-geometric scattering from Centaur dust or blanketing debris on the measured colors is minimal. The results of our observations are discussed in the context of the cause of Centaur activity and the color distributions of active and inactive Centaurs. We suggest that the relative paucity of red Centaurs with low-perihelion orbits may not be directly due to the blanketing of the surface by unweathered particulates, but could instead be a result of the higher levels of thermal processing on low-perihelion Centaurs in general.Comment: 13 pages, 4 figures, accepted for publication in A

Effect of trichlorofluoromethane and molecular chlorine on ozone formation by simulated solar radiation

Mixtures of air with either Cl2 or CFCl3 were photolyzed in a reaction chamber by simulated solar radiation. Ozone formation was temporarily inhibited by Cl2 and permanently inhibited by CFCl3. A chemical mechanism including gas phase and wall reactions is proposed to explain these results. The CFCl3 is assumed to be adsorbed on the chamber walls and to poison the sites for Cl destruction

Heavy Quarkonium Dissociation Cross Sections in Relativistic Heavy-Ion Collisions

Many of the hadron-hadron cross sections required for the study of the dynamics of matter produced in relativistic heavy-ion collisions can be calculated using the quark-interchange model. Here we evaluate the low-energy dissociation cross sections of $J/\psi$, $\psi'$, $\chi$, $\Upsilon$, and $\Upsilon'$ in collision with $\pi$, $\rho$, and $K$, which are important for the interpretation of heavy-quarkonium suppression as a signature for the quark gluon plasma. These comover dissociation processes also contribute to heavy-quarkonium suppression, and must be understood and incorporated in simulations of heavy-ion collisions before QGP formation can be established through this signature.Comment: 38 pages, in LaTe