The bimodal color distribution of small Kuiper Belt objects

We conducted a two-night photometric survey of small Kuiper Belt objects (KBOs) near opposition using the wide-field Hyper Suprime-Cam instrument on the 8.2 m Subaru Telescope. The survey covered about 90 deg^2 of sky, with each field imaged in the g and i bands. We detected 356 KBOs, ranging in absolute magnitude from 6.5 to 10.4. Filtering for high-inclination objects within the hot KBO population, we show that the g-i color distribution is strongly bimodal, indicative of two color classes - the red and very red subpopulations. After categorizing objects into the two subpopulations by color, we present the first dedicated analysis of the magnitude distributions of the individual color subpopulations and demonstrate that the two distributions are roughly identical in shape throughout the entire size range covered by our survey. Comparing the color distribution of small hot KBOs with that of Centaurs, we find that they have similar bimodal shapes, thereby providing strong confirmation of previous explanations for the attested bimodality of Centaurs. We also show that the magnitude distributions of the two KBO color subpopulations and the two color subpopulations observed in the Jupiter Trojans are statistically indistinguishable. Finally, we discuss a hypothesis describing the origin of the KBO color bimodality based on our survey results.Comment: 9 pages, 6 figures, accepted for publication in AJ, supplemental table accessible on online journa

Multiband photometry of a Patroclus-Menoetius mutual event: Constraints on surface heterogeneity

We present the first complete multiband observations of a binary asteroid mutual event. We obtained high-cadence, high-signal-to-noise photometry of the UT 2018 April 9 inferior shadowing event in the Jupiter Trojan binary system Patroclus-Menoetius in four Sloan bands $-$ $g'$, $r'$, $i'$, and $z'$. We use an eclipse lightcurve model to fit for a precise mid-eclipse time and estimate the minimum separation of the two eclipsing components during the event. Our best-fit mid-eclipse time of $2458217.80943^{+0.00057}_{-0.00050}$ is 19 minutes later than the prediction of Grundy et al. (2018); the minimum separation between the center of Menoetius' shadow and the center of Patroclus is $72.5\pm0.7$ km $-$ slightly larger than the predicted 69.5 km. Using the derived lightcurves, we find no evidence for significant albedo variations or large-scale topographic features on the Earth-facing hemisphere and limb of Patroclus. We also apply the technique of eclipse mapping to place an upper bound of $\sim$0.15 mag on wide-scale surface color variability across Patroclus.Comment: 5 pages, 3 figures, accepted for publication in A

A hypothesis for the color bimodality of Jupiter Trojans

One of the most enigmatic and hitherto unexplained properties of Jupiter Trojans is their bimodal color distribution. This bimodality is indicative of two sub-populations within the Trojans, which have distinct size distributions. In this paper, we present a simple, plausible hypothesis for the origin and evolution of the two Trojan color sub-populations. In the framework of dynamical instability models of early Solar System evolution, which suggest a common primordial progenitor population for both Trojans and Kuiper belt objects, we use observational constraints to assert that the color bimodalities evident in both minor body populations developed within the primordial population prior to the onset of instability. We show that, beginning with an initial composition of rock and ices, location-dependent volatile loss through sublimation in this primordial population could have led to sharp changes in the surface composition with heliocentric distance. We propose that the depletion or retention of H$_{2}$S ice on the surface of these objects was the key factor in creating an initial color bimodality. Objects that retained H$_{2}$S on their surfaces developed characteristically redder colors upon irradiation than those that did not. After the bodies from the primordial population were scattered and emplaced into their current positions, they preserved this primordial color bimodality to the present day. We explore predictions of the volatile loss model - in particular, the effect of collisions within the Trojan population on the size distributions of the two sub-populations - and propose further experimental and observational tests of our hypothesisComment: 8 pages, 3 figures, accepted for publication in A

Non-Empirically Tuned Range-Separated DFT Accurately Predicts Both Fundamental and Excitation Gaps in DNA and RNA Nucleobases

Using a non-empirically tuned range-separated DFT approach, we study both the quasiparticle properties (HOMO-LUMO fundamental gaps) and excitation energies of DNA and RNA nucleobases (adenine, thymine, cytosine, guanine, and uracil). Our calculations demonstrate that a physically-motivated, first-principles tuned DFT approach accurately reproduces results from both experimental benchmarks and more computationally intensive techniques such as many-body GW theory. Furthermore, in the same set of nucleobases, we show that the non-empirical range-separated procedure also leads to significantly improved results for excitation energies compared to conventional DFT methods. The present results emphasize the importance of a non-empirically tuned range-separation approach for accurately predicting both fundamental and excitation gaps in DNA and RNA nucleobases.Comment: Accepted by the Journal of Chemical Theory and Computatio

Photometry of active Centaurs: Colors of dormant active Centaur nuclei

We present multiband photometric observations of nine Centaurs. Five of the targets are known active Centaurs (167P/CINEOS, 174P/Echeclus, P/2008 CL94, P/2011 S1, and C/2012 Q1), and the other four are inactive Centaurs belonging to the redder of the two known color subpopulations (83982 Crantor, 121725 Aphidas, 250112 2002 KY14, and 281371 2008 FC76). We measure the optical colors of eight targets and carry out a search for cometary activity. In addition to the four inactive Centaurs, three of the five active Centaurs showed no signs of activity at the time of observation, yielding the first published color measurements of the bare nuclei of 167P and P/2008 CL94 without possible coma contamination. Activity was detected on P/2011 S1 and C/2012 Q1, yielding relatively high estimated mass loss rates of $140\pm20$ and $250\pm40$ kg/s, respectively. The colors of the dormant nuclei are consistent with the previously-published colors, indicating that any effect of non-geometric scattering from Centaur dust or blanketing debris on the measured colors is minimal. The results of our observations are discussed in the context of the cause of Centaur activity and the color distributions of active and inactive Centaurs. We suggest that the relative paucity of red Centaurs with low-perihelion orbits may not be directly due to the blanketing of the surface by unweathered particulates, but could instead be a result of the higher levels of thermal processing on low-perihelion Centaurs in general.Comment: 13 pages, 4 figures, accepted for publication in A

Domestic Support Policies for Agriculture in Ecuador and the U.S.-Andean Countries Free Trade Agreement: An Applied General Equilibrium Assessment

For the past two years the United States and Colombia, Peru and Ecuador have being negotiating a Free Trade Agreement (FTA). One of the main concerns of Ecuador's farmers is the asymmetry that exists between U.S. and Ecuador agricultural sectors. U.S. agriculture is highly subsidized in products such as rice, corn, and soybeans, products that represent an important export and subsistence products for Ecuadorian farmers. To reduce any negative effect that the FTA may have, Ecuador's government is studying land-based payments for rice, corn, soybeans and livestock producers. This program would offer direct initial support to farmers' income after the FTA enters in full effect. The objectives of this paper were twofold. First, estimate the effects on the Ecuadorian economy, and especially on Ecuador's agriculture of the FTA. And second, study the viability of the domestic support program for agriculture proposed by the Ecuadorian government, as well as some alternative domestic support policies. We use a modified version of the GTAP global general equilibrium model specific for agriculture support, called GTAP-AGR. The results show that trade liberalization will negatively affect all agricultural sectors in Ecuador, except for the exporting sectors (bananas, coffee, cocoa, and flowers). Government subsidies are estimated to disproportionally help rice and soybeans producers, but they will not be enough for corn and livestock producers. We conclude that government subsidies should be extended to other sector such as sugar cane and cotton.International Relations/Trade,

Mass-spectrometric investigation of reaction of oxygen atoms with methane

Mass spectrometric investigation of oxygen atoms reacting with methan