3,091 research outputs found
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Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu
We have investigated the role of surface roughening on the CO2 reduction reaction (CO2RR) over Cu. The activity and product selectivity of Cu surfaces roughened by plasma pretreatment in Ar, O2, or N2 were compared with that of electrochemically polished Cu samples. Differences in total and product current densities, the ratio of current densities for HER (the hydrogen evolution reaction) to CO2RR, and the ratio of current densities for C2+ to C1 products depend on the electrochemically active surface and are nearly independent of plasma composition. Theoretical analysis of an electropolished and roughened Cu surface reveals a higher fraction of undercoordinated Cu sites on the roughened surface, sites that bind CO preferentially. Roughened surfaces also contain square sites similar to those on a Cu(100) surface but with neighboring step sites, which adsorb OC-COH, a precursor to C2+ products. These findings explain the increases in the formation of oxygenates and hydrocarbons relative to CO and the ratio of oxygenates to hydrocarbons observed with increasing surface roughness
Boundaries of Semantic Distraction: Dominance and Lexicality Act at Retrieval
Three experiments investigated memory for semantic information with the goal of determining boundary conditions for the manifestation of semantic auditory distraction. Irrelevant speech disrupted the free recall of semantic category-exemplars to an equal degree regardless of whether the speech coincided with presentation or test phases of the task (Experiment 1) and occurred regardless of whether it comprised random words or coherent sentences (Experiment 2). The effects of background speech were greater when the irrelevant speech was semantically related to the to-be-remembered material, but only when the irrelevant words were high in output dominance (Experiment 3). The implications of these findings in relation to the processing of task material and the processing of background speech is discussed
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Barriers to enrollment in a randomized controlled trial of hydrocortisone for cardiovascular insufficiency in term and late preterm newborn infants.
ObjectiveTo analyze reasons for low enrollment in a randomized controlled trial (RCT) of the effect of hydrocortisone for cardiovascular insufficiency on survival without neurodevelopmental impairment (NDI) in term/late preterm newborns.Study designThe original study was a multicenter RCT. Eligibility: ⩾34 weeks' gestation, <72 h old, mechanically ventilated, receiving inotrope. Primary outcome was NDI at 2 years; infants with diagnoses at high risk for NDI were excluded. This paper presents an analysis of reasons for low patient enrollment.ResultsTwo hundred and fifty-seven of the 932 otherwise eligible infants received inotropes; however, 207 (81%) had exclusionary diagnoses. Only 12 infants were randomized over 10 months; therefore, the study was terminated. Contributing factors included few eligible infants after exclusions, open-label steroid therapy and a narrow enrollment window.ConclusionDespite an observational study to estimate the population, very few infants were enrolled. Successful RCTs of emergent therapy may require fewer exclusions, a short-term primary outcome, waiver of consent and/or other alternatives
Insulators and imprinting from flies to mammals
The nuclear factor CTCF has been shown to be necessary for the maintenance of genetic imprinting at the mammalian H19/Igf2 locus. MacDonald and colleagues now report in BMC Biology that the mechanisms responsible for maintaining the imprinted state in Drosophila may be evolutionarily conserved and that CTCF may also play a critical role in this process
Holographic Anomalous Conductivities and the Chiral Magnetic Effect
We calculate anomaly induced conductivities from a holographic gauge theory
model using Kubo formulas, making a clear conceptual distinction between
thermodynamic state variables such as chemical potentials and external
background fields. This allows us to pinpoint ambiguities in previous
holographic calculations of the chiral magnetic conductivity. We also calculate
the corresponding anomalous current three-point functions in special kinematic
regimes. We compare the holographic results to weak coupling calculations using
both dimensional regularization and cutoff regularization. In order to
reproduce the weak coupling results it is necessary to allow for singular
holographic gauge field configurations when a chiral chemical potential is
introduced for a chiral charge defined through a gauge invariant but
non-conserved chiral density. We argue that this is appropriate for actually
addressing charge separation due to the chiral magnetic effect.Comment: 17 pages, 1 figure. v2: 18 pages, 1 figure, discussion clarified
throughout the text, references added, version accepted for publication in
JHE
Convergence properties of decays in chiral perturbation theory
Theoretical efforts to describe and explain the decays reach
far back in time. Even today, the convergence of the decay widths and some of
the Dalitz plot parameters seems problematic in low energy QCD. In the
framework of resummed CHPT, we explore the question of compatibility of
experimental data with a reasonable convergence of a carefully defined chiral
series, where NNLO remainders are assumed to be small. By treating the
uncertainties in the higher orders statistically, we numerically generate a
large set of theoretical predictions, which are then confronted with
experimental information. In the case of the decay widths, the experimental
values can be reconstructed for a reasonable range of the free parameters and
thus no tension is observed, in spite of what some of the traditional
calculations suggest. The Dalitz plot parameters and can be described
very well too. When the parameters and are concerned, we find a
mild tension for the whole range of the free parameters, at less than 2
C.L. This can be interpreted in two ways - either some of the higher order
corrections are indeed unexpectedly large or there is a specific configuration
of the remainders, which is, however, not completely improbable. Also, the
distribution of the theoretical uncertainties is found to be significantly
non-gaussian, so the consistency cannot be simply judged by the 1 error
bars.Comment: 57 pages, 5 figure
Argumentation in school science : Breaking the tradition of authoritative exposition through a pedagogy that promotes discussion and reasoning
The value of argumentation in science education has become internationally recognised and has been the subject of many research studies in recent years. Successful introduction of argumentation activities in learning contexts involves extending teaching goals beyond the understanding of facts and concepts, to include an emphasis on cognitive and metacognitive processes, epistemic criteria and reasoning. The authors focus on the difficulties inherent in shifting a tradition of teaching from one dominated by authoritative exposition to one that is more dialogic, involving small-group discussion based on tasks that stimulate argumentation. The paper builds on previous research on enhancing the quality of argument in school science, to focus on how argumentation activities have been designed, with appropriate strategies, resources and modelling, for pedagogical purposes. The paper analyses design frameworks, their contexts and lesson plans, to evaluate their potential for enhancing reasoning through foregrounding the processes of argumentation. Examples of classroom dialogue where teachers adopt the frameworks/plans are analysed to show how argumentation processes are scaffolded. The analysis shows that several layers of interpretation are needed and these layers need to be aligned for successful implementation. The analysis serves to highlight the potential and limitations of the design frameworks
Anomalies and the chiral magnetic effect in the Sakai-Sugimoto model
In the chiral magnetic effect an imbalance in the number of left- and
right-handed quarks gives rise to an electromagnetic current parallel to the
magnetic field produced in noncentral heavy-ion collisions. The chiral
imbalance may be induced by topologically nontrivial gluon configurations via
the QCD axial anomaly, while the resulting electromagnetic current itself is a
consequence of the QED anomaly. In the Sakai-Sugimoto model, which in a certain
limit is dual to large-N_c QCD, we discuss the proper implementation of the QED
axial anomaly, the (ambiguous) definition of chiral currents, and the
calculation of the chiral magnetic effect. We show that this model correctly
contains the so-called consistent anomaly, but requires the introduction of a
(holographic) finite counterterm to yield the correct covariant anomaly.
Introducing net chirality through an axial chemical potential, we find a
nonvanishing vector current only before including this counterterm. This seems
to imply the absence of the chiral magnetic effect in this model. On the other
hand, for a conventional quark chemical potential and large magnetic field,
which is of interest in the physics of compact stars, we obtain a nontrivial
result for the axial current that is in agreement with previous calculations
and known exact results for QCD.Comment: 35 pages, 4 figures, v2: added comments about frequency-dependent
conductivity at the end of section 4; references added; version to appear in
JHE
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