A Green Bank Telescope Survey of Large Galactic HII Regions

As part of our ongoing HII Region Discovery Survey (HRDS), we report the Green Bank Telescope detection of 148 new angularly-large Galactic HII regions in radio recombination line (RRL) emission. Our targets are located at a declination greater than -45deg., which corresponds to 266deg. > l > -20deg. at b = 0deg. All sources were selected from the WISE Catalog of Galactic HII Regions, and have infrared angular diameters >260''. The Galactic distribution of these "large" HII regions is similar to that of the previously-known sample of Galactic HII regions. The large HII region RRL line width and peak line intensity distributions are skewed toward lower values compared with that of previous HRDS surveys. We discover 7 sources with extremely narrow RRLs <10 km/s. If half the line width is due to turbulence, these 7 sources have thermal plasma temperatures <1100 K. These temperatures are lower than any measured for Galactic HII regions, and the narrow line components may arise instead from partially ionized zones in the HII region photo-dissociation regions. We discover G039.515+00.511, one of the most luminous HII regions in the Galaxy. We also detect the RRL emission from three HII regions with diameters >100 pc, making them some of the physically largest known HII regions in the Galaxy. This survey completes the HRDS HII region census in the Northern sky, where we have discovered 887 HII regions and more than doubled the previously-known census of Galactic HII regions.Comment: Accepted in ApJ

High-Mass Star Formation in the Outer Scutum-Centaurus Arm

The Outer Scutum-Centaurus (OSC) spiral arm is the most distant molecular spiral arm in the Milky Way, but until recently little was known about this structure. Discovered by Dame and Thaddeus (2011), the OSC lies $\sim$15 kpc from the Galactic Center. Due to the Galactic warp, it rises to nearly 4$^{\circ}$ above the Galactic Plane in the first Galactic quadrant, leaving it unsampled by most Galactic plane surveys. Here we observe HII region candidates spatially coincident with the OSC using the Very Large Array to image radio continuum emission from 65 targets and the Green Bank Telescope to search for ammonia and water maser emission from 75 targets. This sample, drawn from the WISE Catalog of Galactic HII Regions, represents every HII region candidate near the longitude-latitude (l,v) locus of the OSC. Coupled with their characteristic mid-infrared morphologies, detection of radio continuum emission strongly suggests that a target is a bona fide HII region. Detections of associated ammonia or water maser emission allow us to derive a kinematic distance and determine if the velocity of the region is consistent with that of the OSC. Nearly 60% of the observed sources were detected in radio continuum, and over 20% have ammonia or water maser detections. The velocities of these sources mainly place them beyond the Solar orbit. These very distant high-mass stars have stellar spectral types as early as O4. We associate high-mass star formation at 2 new locations with the OSC, increasing the total number of detected HII regions in the OSC to 12.Comment: 14 pages text and tables + 10 pages supplemental figure

Finding Distant Galactic H Ii Regions

The WISE Catalog of Galactic H ii Regions contains ~2000 H ii region candidates lacking ionized gas spectroscopic observations. All candidates have the characteristic H ii region mid-infrared morphology of WISE 12 emission surrounding 22 emission, and additionally have detected radio continuum emission. We here report Green Bank Telescope hydrogen radio recombination line and radio continuum detections in the X-band (9 GHz; 3 cm) of 302 WISE H ii region candidates (out of 324 targets observed) in the zone , Here we extend the sky coverage of our H ii region Discovery Survey, which now contains nearly 800 H ii regions distributed across the entire northern sky. We provide LSR velocities for the 302 detections and kinematic distances for 131 of these. Of the 302 new detections, 5 have coordinates consistent with the Outer Scutum–Centaurus Arm (OSC), the most distant molecular spiral arm of the Milky Way. Due to the Galactic warp, these nebulae are found at Galactic latitudes \u3e1° in the first Galactic quadrant, and therefore were missed in previous surveys of the Galactic plane. One additional region has a longitude and velocity consistent with the OSC but lies at a negative Galactic latitude (G039.183−01.422; −54.9 ). With Heliocentric distances \u3e22 kpc and Galactocentric distances \u3e16 kpc, the OSC H ii regions are the most distant known in the Galaxy. We detect an additional three H ii regions near whose LSR velocities place them at Galactocentric radii \u3e19 kpc. If their distances are correct, these nebulae may represent the limit to Galactic massive star formation

Activation of C–H Bonds in Pt^+ + x CH_4 Reactions, where x = 1–4: Identification of the Platinum Dimethyl Cation

Activation of C–H bonds in the sequential reactions of Pt^+ + x(CH_4/CD_4), where x = 1–4, have been investigated using infrared multiple photon dissociation (IRMPD) spectroscopy and theoretical calculations. Pt^+ cations are formed by laser ablation and exposed to controlled amounts of CH_4/CD_4 leading to [Pt,xC,(4x-2)H/D]^+ dehydrogenation products. Irradiation of these products in the 400–2100 cm^(–1) range leads to CH_4/CD_4 loss from the x = 3 and 4 products, whereas PtCH_2^+/PtCD_2^+ products do not decompose at all, and x = 2 products dissociate only when formed from a higher order product. The structures of these complexes were explored theoretically at several levels of theory with three different basis sets. Comparison of the experimental and theoretical results indicate that the species formed have a Pt(CH_3)_2^+(CH_4)_(x-2)/Pt(CD_3)_2^+(CD_4)_(x-2) binding motif for x = 2–4. Thus, reaction of Pt^+ with methane occurs by C–H bond activation to form PtCH_2^+, which reacts with an additional methane molecule by C–H bond activation to form the platinum dimethyl cation. This proposed reaction mechanism is consistent with theoretical explorations of the potential energy surface for reactions of Pt^+ with one and two methane molecules

Integrated stratigraphy of the Waitakian-Otaian Stage boundary stratotype, Early Miocene, New Zealand

The base of the type section of the Otaian Stage at Bluecliffs, South Canterbury, is recognised as the stratotype for the boundary between the Waitakian and Otaian Stages. Principal problems with the boundary are the restriction of existing bioevent proxies to shelf and upper slope environments and its uncertain age. These topics are addressed by a multidisplinary study of a 125 m section about the boundary, which examines its lithostratigraphy, depositional setting, biostratigraphy, correlation, and geochronology. The lower siltstone lithofacies (0-38.5 m) was deposited at upper bathyal depths (200-600 m) in a marginal basin which was partially sheltered from fully oceanic circulation by a submarine high and islands. The site was covered by cool-temperate water and was probably adjacent to the Subtropical Convergence. This unit is succeeded by the banded lithofacies (38.5-106 m) and the upper siltstone lithofacies (basal 19 m studied). Paleodepth probably declined up-sequence, but deposition at shelf depths is not definitely indicated. A cyclic pattern of abundance spikes in benthic and planktonic foraminifera commences 9 m above base and extends to 73 m in the banded lithofacies. Oxygen isotope excursions (up to 2.08%) in Euuvigerina miozea and Cibicides novozelandicus are greatest within the interval containing the abundance spikes. The stage boundary occurs in the banded lithofacies at the highest abundance spike (73 m). Although condensed intervals might affect the completeness of the section, they are not associated with sedimentary discontinuities, and we consider that the section is suitable as a biostratigraphic reference. Spores, pollens, dinoflagellates, calcareous nannofossils, foraminifera, bryozoans, and ostracods are preserved near the boundary, but molluscs principally occur higher, in the shallower upper siltstone lithofacies. Siliceous microfossils are rare. There is considerable scope for further biostratigraphic research. The primary event marking the boundary at 73 m is the appearance of the benthic foraminifer Ehrenbergina marwicki. This is a distinctive and widely distributed event but is restricted to shelf and upper bathyal environments. Supplementary events in planktonic foraminifera and calcareous nannofossils were researched. Highest occurrences of Globigerina brazieri and G. euapertura are recorded at 47 and 58 m. There is a marked decline in relative abundance of Paragloborotalia spp. at 62 m. Helicosphaera carteri becomes more abundant than H. euphratis between 56 and 87 m. These events are not exact proxies for the boundary but they may usefully indicate proximity to it. They occur in the interval of prominent spikes in foraminiferal abundance. The Waitakian-Otaian boundary is dated at 21.7 Ma by strontium isotopes. Stable primary remanence could not be determined in a pilot paleomagnetic study of Bluecliffs specimens. However, specimens trended towards reversed polarity, and remagnetisation great circle analysis will allow directions to be calculated in future collections

Galactic synchrotron distribution derived from 152 HII region absorption features in the full GLEAM survey

We derive the synchrotron distribution in the Milky Way disc from H II region absorption observations over -40° &lt; l &lt; 40° at six frequencies of 76.2, 83.8, 91.5, 99.2, 106.9, and 114.6 MHz with the GaLactic and Extragalactic All-sky Murchison widefield array survey (GLEAM). We develop a new method of emissivity calculation by taking advantage of the Haslam et al. (1981) map and known spectral indices, which enable us to simultaneously derive the emissivity and the optical depth of H II regions at each frequency. We show our derived synchrotron emissivities based on 152 absorption features of H II regions using both the method previously adopted in the literature and our improved method. We derive the synchrotron emissivity from H II regions to the Galactic edge along the line of sight and, for the first time, derive the emissivity from H II regions to the Sun. These results provide direct information on the distribution of the Galactic magnetic field and cosmic ray electrons for future modelling