Spin-Orbit Coupling in Iridium-Based 5d Compounds Probed by X-ray Absorption Spectroscopy

We have performed x-ray absorption spectroscopy (XAS) measurements on a series of Ir-based 5d transition metal compounds, including Ir, IrCl3, IrO2, Na2IrO3, Sr2IrO4, and Y2Ir2O7. By comparing the intensity of the "white-line" features observed at the Ir L2 and L3 absorption edges, it is possible to extract valuable information about the strength of the spin-orbit coupling in these systems. We observe remarkably large, non-statistical branching ratios in all Ir compounds studied, with little or no dependence on chemical composition, crystal structure, or electronic state. This result confirms the presence of strong spin-orbit coupling effects in novel iridates such as Sr2IrO4, Na2IrO3, and Y2Ir2O7, and suggests that even simple Ir-based compounds such as IrO2 and IrCl3 may warrant further study. In contrast, XAS measurements on Re-based 5d compounds, such as Re, ReO2, ReO3, and Ba2FeReO6, reveal statistical branching ratios and negligible spin-orbit coupling effects.Comment: 9 pages, 4 figure

Mars atmospheric dust properties: A synthesis of Mariner 9, Viking, and Phobos observations

We have modified a doubling-and-adding code to reanalyze the Mariner 9 IRIS spectra of Mars atmospheric dust as well as Viking IRTM EPF sequences in the 7, 9, and 20 micron channels. The code is capable of accurate emission/ absorption/scattering radiative transfer calculations over the 5-30 micron wavelength region for variable dust composition and particle size inputs, and incorporates both the Viking IRTM channel weightings and the Mariner 9 IRIS wavelength resolution for direct comparisons to these datasets. We adopt atmospheric temperature profiles according to the algorithm of Martin (1986) in the case of the Viking IRTM comparisons, and obtained Mariner 9 IRIS temperature retrievals from the 15 micron CO2 band for the case of the IRIS comparisons. We consider palagonite as the primary alternative to the montmorillonite composition of Mars atmospheric dust, based on several considerations. Palagonite absorbs in the ultraviolet and visible wavelength region due to its Fe content. Palagonite is also, in principal, consistent with the observed lack of clays on the Mars surface. Furthermore, palagonite does not display strong, structured absorption near 20 microns as does montmorillonite (in conflict with the IRIS observations). We propose that a palagonite composition with particle sizes roughly one-half that of the Toon et al. (1977) determination provide a much improved model to Mars atmospheric dust. Since palagonite is a common weathering product of terrrestrial basalts, it would not be unreasonable for palagonite to be a major surface component for Mars. The lack of even a minor component of Al-rich clays on the surface of Mars could be consistent with a palagonite composition for Mars dust if the conditions for basalt weathering on Mars were sufficiently anhydrous. Variations in palagonite composition could also lead to the inability of the modeled palagonite to fit the details of the 9 micron absorbtion indicated by the IRIS observations

Singlet-Triplet Excitations in the Unconventional Spin-Peierls System TiOBr

We have performed time-of-flight neutron scattering measurements on powder samples of the unconventional spin-Peierls compound TiOBr using the fine-resolution Fermi chopper spectrometer (SEQUOIA) at the SNS. These measurements reveal two branches of magnetic excitations within the commensurate and incommensurate spin-Peierls phases, which we associate with n = 1 and n = 2 triplet excitations out of the singlet ground state. These measurements represent the first direct measure of the singlet-triplet energy gap in TiOBr, which is determined to be Eg = 21.2 +/- 1.0 meV.Comment: 5 pages, 4 figures, submitted for publicatio

The song remains the same although the instruments are changing: complications following selective non-operative management of blunt spleen trauma: a retrospective review of patients at a level I trauma centre from 1996 to 2007

BACKGROUND: Despite a widespread shift to selective non-operative management (SNOM) for blunt splenic trauma, there remains uncertainty regarding the role of adjuncts such as interventional radiological techniques, the need for follow-up imaging, and the incidence of long-term complications. We evaluated the success of SNOM (including splenic artery embolization, SAE) for the management of blunt splenic injuries in severely injured patients. METHODS: Retrospective review (1996-2007) of the Alberta Trauma Registry and health records for blunt splenic trauma patients, aged 18 and older, with injury severity scores of 12 or greater, admitted to the Foothills Medical Centre. RESULTS: Among 538 eligible patients, 150 (26%) underwent early operative intervention. The proportion of patients managed by SNOM rose from 50 to 78% over the study period, with an overall success rate of SNOM of 87%, while injury acuity remained unchanged over time. Among SNOM failures, 65% underwent surgery within 24 hours of admission. Splenic arterial embolization (SAE) was used in only 7% of patients managed non-operatively, although at least 21% of failed SNOM had contrast extravasation potentially amenable to SAE. Among Calgary residents undergoing SNOM, hospital readmission within six months was required in three (2%), all of whom who required emergent intervention (splenectomy 2, SAE 1) and in whom none had post-discharge follow-up imaging. Overall, the use of post-discharge follow-up CT imaging was low following SNOM (10%), and thus no CT images identified occult hemorrhage or pseudoaneurysm. We observed seven cases of delayed splenic rupture in our population which occurred from five days to two months following initial injury. Three of these occurred in the post-discharge period requiring readmission and intervention. CONCLUSIONS: SNOM was the initial treatment strategy for most patients with blunt splenic trauma with 13% requiring subsequent operative intervention intended for the spleen. Cases of delayed splenic rupture occurred up to two months following initial injury. The low use of both follow-up imaging and SAE make assessment of the utility of these adjuncts difficult and adherence to formalized protocols will be required to fully assess the benefit of multi-modality management strategies

Temporal and spatial mapping of atmospheric dust opacity and surface albedo on Mars

The Mariner 9 and Viking missions provided abundant evidence that eolian processes are active over much of the surface of Mars. Past studies have demonstrated that variations in regional albedo and wind streak patterns are indicative of sediment transport through a region, while thermal inertia data (derived from the Viking Infrared Thermal Mapper (IRTM) datasets) are indicative of the degree of surface mantling by dust deposits. We are making use of the method developed by T. Z. Martin to determine dust opacity from IRTM thermal observations. We have developed a radiative transfer model that allows corrections for the effects of atmospheric dust loading on observations of surface albedo to be made. This approach to determining 'dust-corrected surface albedo' incorporates the atmospheric dust opacity, the single-scattering albedo and particle phase function of atmospheric dust, the bidirectional reflectance of the surface, and accounts for variable lighting and viewing geometry

Asymptotic Behaviour of Inhomogeneous String Cosmologies

The asymptotic behaviour at late times of inhomogeneous axion-dilaton cosmologies is investigated. The space-times considered here admit two abelian space-like Killing vectors. These space-times evolve towards an anisotropic universe containing gravitational radiation. Furthermore, a peeling-off behaviour of the Weyl tensor and the antisymmetric tensor field strength is found. The relation to the pre-big-bang scenario is briefly discussed.Comment: 15 pages, Late

Investigation of Aromatic/Aliphatic Polyimides as Dispersants for Single Wall Carbon Nanotubes

Novel aromatic/aliphatic polyimides were prepared from 2,7-diamino-9,9'- dioctylfluorene (AFDA) and aromatic dianhydrides. Upon investigating the effectiveness of these polyimides for dispersing single wall carbon nanotubes (SWNTs) in solution, three were discovered to disperse SWNTs in N,N-dimethylacetamide (DMAc). Two of these polyimides, one from 3,3',4,4'-oxydiphthalic anhydride (ODPA) and one from symmetric 3,3',4,4'-biphenyltetracarboxylic dianhydride (s-BPDA), were used to prepare nanocomposites. Homogeneous polyimide/SWNT suspensions from both polymers were used in the preparation of films and fibers containing up to 1 wt% SWNTs. The samples were thermally treated to remove residual solvent and the films were characterized for SWNT dispersion by optical and high resolution scanning electron microscopy (HRSEM). Electrical and mechanical properties of the films were also determined. Electrospun fibers were examined by HRSEM to characterize SWNT alignment and orientation

Numerical Study of Inhomogeneous Pre-Big-Bang Inflationary Cosmology

We study numerically the inhomogeneous pre-big-bang inflation in a spherically symmetric space-time. We find that a large initial inhomogeneity suppresses the onset of the pre-big-bang inflation. We also find that even if the pre-big-bang inflationary stage is realized, the initial inhomogeneities are not homogenized. Namely, during the pre-big-bang inflation ``hairs''(irregularities) do not fall, in sharp contrast to the usual (potential energy dominated) inflation where initial inhomogeneity and anisotropy are damped and thus the resulting universe is less sensitive to initial conditions.Comment: 12 pages + 14 figures, to be published in Phys.Rev.