Fruit volatile analysis using an electronic nose.

Numerous and diverse physiological changes occur during fruit ripening, including the development of a specific volatile blend that characterizes fruit aroma. Maturity at harvest is one of the key factors influencing the flavor quality of fruits and vegetables. The validation of robust methods that rapidly assess fruit maturity and aroma quality would allow improved management of advanced breeding programs, production practices and postharvest handling. Over the last three decades, much research has been conducted to develop so-called electronic noses, which are devices able to rapidly detect odors and flavors. Currently there are several commercially available electronic noses able to perform volatile analysis, based on different technologies. The electronic nose used in our work (zNose, EST, Newbury Park, CA, USA), consists of ultra-fast gas chromatography coupled with a surface acoustic wave sensor (UFGC-SAW). This technology has already been tested for its ability to monitor quality of various commodities, including detection of deterioration in apple; ripeness and rot evaluation in mango; aroma profiling of thymus species; C(6) volatile compounds in grape berries; characterization of vegetable oil and detection of adulterants in virgin coconut oil. This system can perform the three major steps of aroma analysis: headspace sampling, separation of volatile compounds, and detection. In about one minute, the output, a chromatogram, is produced and, after a purging cycle, the instrument is ready for further analysis. The results obtained with the zNose can be compared to those of other gas-chromatographic systems by calculation of Kovats Indices (KI). Once the instrument has been tuned with an alkane standard solution, the retention times are automatically converted into KIs. However, slight changes in temperature and flow rate are expected to occur over time, causing retention times to drift. Also, depending on the polarity of the column stationary phase, the reproducibility of KI calculations can vary by several index units. A series of programs and graphical interfaces were therefore developed to compare calculated KIs among samples in a semi-automated fashion. These programs reduce the time required for chromatogram analysis of large data sets and minimize the potential for misinterpretation of the data when chromatograms are not perfectly aligned. We present a method for rapid volatile compound analysis in fruit. Sample preparation, data acquisition and handling procedures are also discussed

Global Projections of Household Numbers Using Age Determined Ratios

A new method based upon age determined population ratios is described and used to estimate household population intensities (households per person). Using an additive and a bounded model household projections are given to 2050 for the world and to 2030 for seven fertility transition subgroups (cohorts) of the countries of the world. Based upon United Nations 2002 Revision data, from an estimated 1.56 billion households at 2000, household growth to 2030 is projected to be an additional 1.1 billion households, whether population increase is 1.3 billion persons under the United Nations low fertility variant or 2.7 billion persons under the high fertility variant. At that date over one third of all households are projected to be Chinese or Indian. By 2050 it is projected that there will be 3.3 billion households with a 95 per cent confidence interval on modelling error only of ± 0.5 billion. This compares with 3.2 billion in the Habitat: Global Report on Human Settlements 1996. The apparent similarity of total household growth under various scenarios conceals a wide range in the growth of household intensities across fertility transition cohorts. It is suggested that models, projections and error be reviewed biennially and that household and population projections be produced jointly.Household projections, world, age ratios, fertility

The value of psychological flexibility: Examining psychological mechanisms underpinning a cognitive behavioural therapy intervention for burnout

Little is known of the mechanisms by which interventions for burnout work. Employees of a UK government department were randomly assigned to either a worksite group-based CBT intervention called Acceptance and Commitment Therapy (ACT; n=43), which aimed to increase participants' psychological flexibility, or a waiting list control group (n=57). The ACT group received three half-day sessions of training spread over two and a half months. Data were collected at baseline (T1), at the beginning of the second (T2) and third (T3) workshops, and at six months' follow up (T4). Consistent with ACT theory, analyses revealed that, in comparison to the control group, a significant increase in psychological flexibility from T2 to T3 in the ACT group mediated the subsequent T2 to T4 decrease in emotional exhaustion in that group. Consistent with a theory of emotional burnout development, this significant decrease in emotional exhaustion from T2 to T4 in the ACT group appeared to prevent the significant T3 to T4 increase in depersonalization seen in the control group. Strain also decreased from T2 to T3 in the ACT group only, but no mediator of that improvement was identified. Implications for theory and practice in the fields of ACT and emotional burnout are discussed

Mindfulness and meditation in the workplace: An acceptance and commitment therapy approach

There is a wide-range and growing body of evidence that mental health and behavioural effectiveness are influenced more by how people interact with their thoughts and feelings than by their form (e.g., how negative they are) or frequency. Research has demonstrated this key finding in a wide-range of areas. For example, in chronic pain, psychosocial disability is predicted more by the experiential avoidance of pain than by the degree of pain (McCracken, 1998). A number of therapeutic approaches have been developed that share this key insight: distress tolerance (e.g., Brown, Lejuez, Kahler, & Strong, 2002; Schmidt, Richey, Cromer, & Buckner, 2007), thought suppression (e.g., Wenzlaff & Wegner, 2000), and mindfulness (Baer, 2003). It is also central to a number of the newer contextual cognitive behaviour therapy (CBT) approaches to treatment, such as mindfulness based cognitive therapy (MBCT; Segal, Williams, & Teasdale, 2001), dialectical behaviour therapy (DBT; Linehan, 1993), metacognitive therapy (Wells, 2000), and acceptance and commitment therapy (ACT; Hayes, Strosahl, & Wilson, 1999). The purpose of this chapter is to describe how ACT conceptualises mindfulness and tries to enhance it in the pursuit of promoting mental health and behavioural effectiveness (e.g., productivity at work). To this end, we discuss ACT’s key construct of psychological flexibility, which involves mindfulness, and how it has led to a somewhat different approach not only to conceptualising mindfulness, but also how we try to enhance it in the workplace. In so doing, we hope to show that whilst formal meditation practice is valued in ACT, it is only one strategy that is used to promote mindfulness, as well as psychological flexibility more generally

Externally Dispersed Interferometry for Precision Radial Velocimetry

Externally Dispersed Interferometry (EDI) is the series combination of a fixed-delay field-widened Michelson interferometer with a dispersive spectrograph. This combination boosts the spectrograph performance for both Doppler velocimetry and high resolution spectroscopy. The interferometer creates a periodic spectral comb that multiplies against the input spectrum to create moire fringes, which are recorded in combination with the regular spectrum. The moire pattern shifts in phase in response to a Doppler shift. Moire patterns are broader than the underlying spectral features and more easily survive spectrograph blurring and common distortions. Thus, the EDI technique allows lower resolution spectrographs having relaxed optical tolerances (and therefore higher throughput) to return high precision velocity measurements, which otherwise would be imprecise for the spectrograph alone.Comment: 7 Pages, White paper submitted to the AAAC Exoplanet Task Forc

A quantum-mechanical Maxwell's demon

A Maxwell's demon is a device that gets information and trades it in for thermodynamic advantage, in apparent (but not actual) contradiction to the second law of thermodynamics. Quantum-mechanical versions of Maxwell's demon exhibit features that classical versions do not: in particular, a device that gets information about a quantum system disturbs it in the process. In addition, the information produced by quantum measurement acts as an additional source of thermodynamic inefficiency. This paper investigates the properties of quantum-mechanical Maxwell's demons, and proposes experimentally realizable models of such devices.Comment: 13 pages, Te

Locating Overlap Information in Quantum Systems

When discussing the black hole information problem the term ``information flow'' is frequently used in a rather loose fashion. In this article I attempt to make this notion more concrete. I consider a Hilbert space which is constructed as a tensor product of two subspaces (representing for example inside and outside the black hole). I discuss how the system has the capacity to contain information which is in NEITHER of the subspaces. I attempt to quantify the amount of information located in each of the two subspaces, and elsewhere, and analyze the extent to which unitary evolution can correspond to ``information flow''. I define the notion of ``overlap information'' which appears to be well suited to the problem.Comment: 25 pages plain LaTeX, no figures. Imperial/TP/93-94/2

Asymmetric quantum error correction via code conversion

In many physical systems it is expected that environmental decoherence will exhibit an asymmetry between dephasing and relaxation that may result in qubits experiencing discrete phase errors more frequently than discrete bit errors. In the presence of such an error asymmetry, an appropriately asymmetric quantum code - that is, a code that can correct more phase errors than bit errors - will be more efficient than a traditional, symmetric quantum code. Here we construct fault tolerant circuits to convert between an asymmetric subsystem code and a symmetric subsystem code. We show that, for a moderate error asymmetry, the failure rate of a logical circuit can be reduced by using a combined symmetric asymmetric system and that doing so does not preclude universality.Comment: 5 pages, 8 figures, presentation revised, figures and references adde

Mindfulness and meditation in the workplace: An acceptance and commitment therapy approach

There is a wide-ranging and growing body of evidence that mental health and behavioral effectiveness are influenced more by how people interact with their thoughts and feelings than by their form (e.g., how negative they are) or frequency. Research has demonstrated this key finding in a wide range of areas. For example, in chronic pain, psychosocial disability is predicted more by the experiential avoidance of pain than by the degree of pain (McCracken 1998). A number of therapeutic approaches have been developed that share this key insight: Distress tolerance (e.g., Brown et al. 2002; Schmidt et al. 2007), thought suppression (e.g., Wenzlaff and Wegner 2000), and mindfulness (Baer 2003). It is also central to a number of the newer contextual cognitive behavior therapy (CBT) approaches to treatment, such as mindfulness-based cognitive therapy (MBCT; Segal et al. 2002), dialectical behavior therapy (DBT; Linehan 1993), metacognitive therapy (Wells 2011), and acceptance and commitment therapy (ACT; Hayes et al. 1999). The purpose of this chapter is to describe how ACT conceptualizes mindfulness and tries to enhance it in the pursuit of promoting mental health and behavioral effectiveness (e.g., productivity at work). To this end, we discuss ACT’s key construct of psychological flexibility, which involves mindfulness, and how it has led to a somewhat different approach not only to conceptualizing mindfulness, but also to how we try to enhance it in the workplace. In so doing, we hope to show that whilst formal meditation practice is valued in ACT, it is only one strategy that is used to promote mindfulness, as well as psychological flexibility more generally

Quantum Approach to a Derivation of the Second Law of Thermodynamics

We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the average over the respective path in Hilbert-space. We then show that for typical (degenerate or non-degenerate) thermodynamical systems almost all states within the allowed region of Hilbert-space have a local von Neumann-entropy S close to the maximum and a purity P close to its minimum, respectively. Typically thermodynamical systems should therefore obey the second law.Comment: 4 pages. Accepted for publication in Phys. Rev. Let