Coupled anharmonic oscillators: the Rayleigh-Ritz approach versus the collocation approach

For a system of coupled anharmonic oscillators we compare the convergence rate of the variational collocation approach presented recently by Amore and Fernandez (2010 Phys.Scr.81 045011) with the one obtained using the optimized Rayleigh-Ritz (RR) method. The monotonic convergence of the RR method allows us to obtain more accurate results at a lower computational cost.Comment: 7 pages, 1 figur

The optimized Rayleigh-Ritz scheme for determining the quantum-mechanical spectrum

The convergence of the Rayleigh-Ritz method with nonlinear parameters optimized through minimization of the trace of the truncated matrix is demonstrated by a comparison with analytically known eigenstates of various quasi-solvable systems. We show that the basis of the harmonic oscillator eigenfunctions with optimized frequency ? enables determination of boundstate energies of one-dimensional oscillators to an arbitrary accuracy, even in the case of highly anharmonic multi-well potentials. The same is true in the spherically symmetric case of V (r) = {\omega}2r2 2 + {\lambda}rk, if k > 0. For spiked oscillators with k < -1, the basis of the pseudoharmonic oscillator eigenfunctions with two parameters ? and {\gamma} is more suitable, and optimization of the latter appears crucial for a precise determination of the spectrum.Comment: 22 pages,8 figure

Second bound state of the positronium molecule and biexcitons

A new, hitherto unknown bound state of the positronium molecule, with orbital angular momentum L=1 and negative parity is reported. This state is stable against autodissociation even if the masses of the positive and negative charges are not equal. The existence of a similar state in two-dimension has also been investigated. The fact that the biexcitons have a second bound state may help the better understanding of their binding mechanism.Comment: Latex, 8 pages, 2 Postscript figure

The helium trimer with soft-core potentials

The helium trimer is studied using two- and three-body soft-core potentials. Realistic helium-helium potentials present an extremely strong short-range repulsion and support a single, very shallow, bound state. The description of systems with more than two helium atoms is difficult due to the very large cancellation between kinetic and potential energy. We analyze the possibility of describing the three helium system in the ultracold regime using a gaussian representation of a widely used realistic potential, the LM2M2 interaction. However, in order to describe correctly the trimer ground state a three-body force has to be added to the gaussian interaction. With this potential model the two bound states of the trimer and the low energy scattering helium-dimer phase shifts obtained with the LM2M2 potential are well reproduced.Comment: 15 pages, 3 figures, submitted to Few-Body System

An accurate analytic representation of the water pair potential

Contains fulltext : 75521.pdf (publisher's version ) (Open Access)16 p

Predictions for water clusters from a first-principles two- and three-body force field

Contains fulltext : 133224.pdf (publisher's version ) (Open Access