61,246 research outputs found
THEORETICAL STUDIES OF BILIPROTEIN CHROMOPHORES AND RELATED BILE PIGMENTS BY MOLECULAR ORBITAL AND RAMACHANDRAN TYPE CALCULATIONS
Ramachandran calculations have been used to gain insight into steric hindrance in bile
pigments related to biliprotein chromophores. The high optical activity of denatured phycocyanin, as
compared to phycoerythrin, has been related to the asymmetric substitution at ring A, which shifts the
equilibrium towards the P-helical form of the chromophore. Geometric effects on the electronic structures
and transitions have then been studied by molecular orbital calculations for several conjugation
systems including the chromophores of phycocyanin. phytochrome P,, cations, cation radicals and
tautomeric forms. For these different chromophores some general trends can be deduced. For instance,
for a given change in the gross shape (e.g. either unfolding of the molecule from a cyclic-helical to a fully
extended geometry, or upon out-of-plane twists of the pyrrole ring A) of the molecules under study, the
predicted absorption spectra all change in a simikar way. Nonetheless, there are characteristic distinctions
between the different n-systems, both in the transition energies and the charge distribution, which
can be related to their known differences in spectroscopic properties and their reactivity
Drastic Reduction of Shot Noise in Semiconductor Superlattices
We have found experimentally that the shot noise of the tunneling current
through an undoped semiconductor superlattice is reduced with respect to the
Poissonian noise value , and that the noise approaches 1/3 of that value
in superlattices whose quantum wells are strongly coupled. On the other hand,
when the coupling is weak or when a strong electric field is applied to the
superlattice the noise becomes Poissonian. Although our results are
qualitatively consistent with existing theories for one-dimensional mulitple
barriers, the theories cannot account for the dependence of the noise on
superlattice parameters that we have observed.Comment: 4 Pages, 3Figure
Writing Electronic Devices on Paper with Carbon Nanotube Ink
The normal paper used in any printer is among the cheapest flexible organic
materials that exist. We demonstrate that we can print on paper high-frequency
circuits tunable with an applied dc voltage. This is possible with the help of
an ink containing functionalized carbon nanotubes and water. After the water is
evaporated from the paper, the nanotubes remain steadily imprinted on paper,
showing a semiconducting behaviour and tunable electrical properties
Shockley-Ramo theorem and long-range photocurrent response in gapless materials
Scanning photocurrent maps of gapless materials, such as graphene, often
exhibit complex patterns of hot spots positioned far from current-collecting
contacts. We develop a general framework that helps to explain the unusual
features of the observed patterns, such as the directional effect and the
global character of photoresponse. We show that such a response is captured by
a simple Shockley-Ramo-type approach. We examine specific examples and show
that the photoresponse patterns can serve as a powerful tool to extract
information about symmetry breaking, inhomogeneity, chirality, and other local
characteristics of the system.Comment: 7 pgs, 3 fg
Tensor coupling effects on spin symmetry in anti-Lambda spectrum of hypernuclei
The effects of -tensor coupling on the spin
symmetry of spectra in -nucleus systems have
been studied with the relativistic mean-field theory. Taking
C+ as an example, it is found that the tensor coupling
enlarges the spin-orbit splittings of by an order of magnitude
although its effects on the wave functions of are negligible.
Similar conclusions has been observed in -nucleus of different
mass regions, including O+, Ca+ and
Pb+. It indicates that the spin symmetry in
anti-lambda-nucleus systems is still good irrespective of the tensor coupling.Comment: 12 pages, 3 figures
Geometric Phase, Hannay's Angle, and an Exact Action Variable
Canonical structure of a generalized time-periodic harmonic oscillator is
studied by finding the exact action variable (invariant). Hannay's angle is
defined if closed curves of constant action variables return to the same curves
in phase space after a time evolution. The condition for the existence of
Hannay's angle turns out to be identical to that for the existence of a
complete set of (quasi)periodic wave functions. Hannay's angle is calculated,
and it is shown that Berry's relation of semiclassical origin on geometric
phase and Hannay's angle is exact for the cases considered.Comment: Submitted to Phys. Rev. Lett. (revised version
The Oblique Corrections from Heavy Scalars in Irreducible Representations
The contributions to , , and from heavy scalars in any irreducible
representation of the electroweak gauge group are
obtained. We find that in the case of a heavy scalar doublet there is a slight
difference between the parameter we have obtained and that in previous
works.Comment: 6 pages, 2 axodraw figures; minor changes, references update
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