2,201 research outputs found
Analysis of Dislocation Mechanism for Melting of Elements: Pressure Dependence
In the framework of melting as a dislocation-mediated phase transition we
derive an equation for the pressure dependence of the melting temperatures of
the elements valid up to pressures of order their ambient bulk moduli. Melting
curves are calculated for Al, Mg, Ni, Pb, the iron group (Fe, Ru, Os), the
chromium group (Cr, Mo, W), the copper group (Cu, Ag, Au), noble gases (Ne, Ar,
Kr, Xe, Rn), and six actinides (Am, Cm, Np, Pa, Th, U). These calculated
melting curves are in good agreement with existing data. We also discuss the
apparent equivalence of our melting relation and the Lindemann criterion, and
the lack of the rigorous proof of their equivalence. We show that the would-be
mathematical equivalence of both formulas must manifest itself in a new
relation between the Gr\"{u}neisen constant, bulk and shear moduli, and the
pressure derivative of the shear modulus.Comment: 19 pages, LaTeX, 9 eps figure
Fragility and compressibility at the glass transition
Isothermal compressibilities and Brillouin sound velocities from the
literature allow to separate the compressibility at the glass transition into a
high-frequency vibrational and a low-frequency relaxational part. Their ratio
shows the linear fragility relation discovered by x-ray Brillouin scattering
[1], though the data bend away from the line at higher fragilities. Using the
concept of constrained degrees of freedom, one can show that the vibrational
part follows the fragility-independent Lindemann criterion; the fragility
dependence seems to stem from the relaxational part. The physical meaning of
this finding is discussed. [1] T. Scopigno, G. Ruocco, F. Sette and G. Monaco,
Science 302, 849 (2003)Comment: 4 pages, 2 figures, 2 tables, 33 references. Slightly changed after
refereein
Why do ultrasoft repulsive particles cluster and crystallize? Analytical results from density functional theory
We demonstrate the accuracy of the hypernetted chain closure and of the
mean-field approximation for the calculation of the fluid-state properties of
systems interacting by means of bounded and positive-definite pair potentials
with oscillating Fourier transforms. Subsequently, we prove the validity of a
bilinear, random-phase density functional for arbitrary inhomogeneous phases of
the same systems. On the basis of this functional, we calculate analytically
the freezing parameters of the latter. We demonstrate explicitly that the
stable crystals feature a lattice constant that is independent of density and
whose value is dictated by the position of the negative minimum of the Fourier
transform of the pair potential. This property is equivalent with the existence
of clusters, whose population scales proportionally to the density. We
establish that regardless of the form of the interaction potential and of the
location on the freezing line, all cluster crystals have a universal Lindemann
ratio L = 0.189 at freezing. We further make an explicit link between the
aforementioned density functional and the harmonic theory of crystals. This
allows us to establish an equivalence between the emergence of clusters and the
existence of negative Fourier components of the interaction potential. Finally,
we make a connection between the class of models at hand and the system of
infinite-dimensional hard spheres, when the limits of interaction steepness and
space dimension are both taken to infinity in a particularly described fashion.Comment: 19 pages, 5 figures, submitted to J. Chem. Phys; new version: minor
changes in structure of pape
Quick Start Guide to Soil Methods for Ecologists
Increasingly biologists and ecologists are becoming aware of the vital importance of soil to processes observed above ground and are incorporating soil analyses into their research. Because of the dynamic and heterogeneous nature of soil, proper incorporation of soil analysis into ecological studies requires knowledge and planning. Unfortunately, many ecologists may not be current (or trained at all) in soil science.We provide this review, based on our cumulative \u3e60 years of work in soil science,to help familiarize researchers with essential information to appropriately incorporate soil analyses into ecological studies. Specifically, we provide a brief introduction into soils and then discuss issues related to soil sterilization, choosing a soil for a greenhouse project, sampling soils, and soil analyses
A conceptual basis for surveying fouling communities at exposed and protected sites at sea: Feasible designs with exchangeable test bodies for in-situ biofouling collection
The enhanced inertia load caused by biofouling on device components, such as the foundations of wind turbines or other structures at sea, modifies the hydrodynamic properties, and increases the stress to structures, predominantly in upper water layers with high impact from wave dynamics. This compromises the stability, functioning, operation as well as the durability of these devices especially in exposed environments. A main challenge is the quantification of the impact of hydrodynamic forces on irregular bodies being overgrown by soft- and hard-bodied biofouling organisms. Therefore, test bodies from the upper 1–5 m water depth and thus exposed to the strongest wave actions close to the surface shall be overgrown by biofouling and used in measurement trials in a wave and current flume. These measurements shall shed light on the varying roughness and its influence on the load bearing capacity of foundation piles. Consequently, the main aims of the present work were the development of two independent test stations as holding devices for artificial test bodies for the collection of biofouling organisms during field studies: a carrying unit floating at the surface in an exposed area (System A) and a sampling device with access from a land-based facility (System B). Both systems are relatively easy to access, exhibit straightforward handling, and are reasonable cost-effective. A Test Body Support Unit (TBSU, System A) was designed and mounted on a spare buoy to carry the test bodies (cylinders), which serve as substrate for the fouling. The system was sufficiently robust to withstand several periods of rough sea conditions over the first two years. This system can only be accessed by vessels. System B (MareLift) provided the robustness and functionality needed for areas exhibiting harsh conditions but can be operated from land. The here used test bodies (steel panels) exhibited a sound basis for the monitoring of succession processes in the biofouling development. System B offered the possibility to analyse two habitats (intertidal and subtidal) and revealed clear differences in the composition and development of their fouling communities. Overall, both systems provide advantages in obtaining standardized biofouling samples compared to previous approaches. Such test stations play an important role in the risk management of marine sectors as they could help characterising biofouling communities over different geographical areas. System A and B provide a sound basis for biofouling research but potentially also for other potential research approaches in exposed areas as they provide space for future developments
Analysis of the temperature-dependent quantum point contact conductance in view of the metal-insulator transition in two dimensions
The temperature dependence of the conductance of a quantum point contact has
been measured. The conductance as a function of the Fermi energy shows
temperature-independent fixed points, located at roughly multiple integers of
. Around the first fixed point at e/h, the experimental data for
different temperatures can been scaled onto a single curve. For pure thermal
smearing of the conductance steps, a scaling parameter of one is expected. The
measured scaling parameter, however, is significantly larger than 1. The
deviations are interpreted as a signature of the potential landscape of the
quantum point contact, and of the source-drain bias voltage. We relate our
results phenomenologically to the metal-insulator transition in two dimensions.Comment: 5 pages, 3 figure
Francisella tularensis Schu S4 lipopolysaccharide core sugar and o-antigen mutants are attenuated in a mouse model of tularemia
The virulence factors mediating Francisella pathogenesis are being investigated, with an emphasis on understanding how the organism evades innate immunity mechanisms. Francisella tularensis produces a lipopolysaccharide (LPS) that is essentially inert and a polysaccharide capsule that helps the organism to evade detection by components of innate immunity. Using an F. tularensis Schu S4 mutant library, we identified strains that are disrupted for capsule and O-antigen production. These serum-sensitive strains lack both capsule production and O-antigen laddering. Analysis of the predicted protein sequences for the disrupted genes (FTT1236 and FTT1238c) revealed similarity to those for waa (rfa) biosynthetic genes in other bacteria. Mass spectrometry further revealed that these proteins are involved in LPS core sugar biosynthesis and the ligation of O antigen to the LPS core sugars. The 50% lethal dose (LD(50)) values of these strains are increased 100- to 1,000-fold for mice. Histopathology revealed that the immune response to the F. tularensis mutant strains was significantly different from that observed with wild-type-infected mice. The lung tissue from mutant-infected mice had widespread necrotic debris, but the spleens lacked necrosis and displayed neutrophilia. In contrast, the lungs of wild-type-infected mice had nominal necrosis, but the spleens had widespread necrosis. These data indicate that murine death caused by wild-type strains occurs by a mechanism different from that by which the mutant strains kill mice. Mice immunized with these mutant strains displayed >10-fold protective effects against virulent type A F. tularensis challenge
Heterogeneities in Supercooled liquids: A Density Functional Study
A metastable state, characterized by a low degree of mass localization is
identified using Density Functional Theory. This free energy minimum, located
through the proper evaluation of the competing terms in the free energy
functional, is independent of the specific form of the DFT used. Computer
simulation results on particle motion indicate that this heterogeneous state
corresponds to the supercooled state.Comment: 10 pages, 6 figure
Fluctuations and phase transitions in Larkin-Ovchinnikov liquid crystal states of population-imbalanced resonant Fermi gas
Motivated by a realization of imbalanced Feshbach-resonant atomic Fermi
gases, we formulate a low-energy theory of the Fulde-Ferrell and the
Larkin-Ovchinnikov (LO) states and use it to analyze fluctuations, stability,
and phase transitions in these enigmatic finite momentum-paired superfluids.
Focusing on the unidirectional LO pair-density wave state, that spontaneously
breaks the continuous rotational and translational symmetries, we show that it
is characterized by two Goldstone modes, corresponding to a superfluid phase
and a smectic phonon. Because of the liquid-crystalline "softness" of the
latter, at finite temperature the 3d state is characterized by a vanishing LO
order parameter, quasi-Bragg peaks in the structure and momentum distribution
functions, and a "charge"-4, paired Cooper-pairs, off-diagonal-long-range
order, with a superfluid-stiffness anisotropy that diverges near a transition
into a nonsuperfluid state. In addition to conventional integer vortices and
dislocations the LO superfluid smectic exhibits composite half-integer
vortex-dislocation defects. A proliferation of defects leads to a rich variety
of descendant states, such as the "charge"-4 superfluid and Fermi-liquid
nematics and topologically ordered nonsuperfluid states, that generically
intervene between the LO state and the conventional superfluid and the
polarized Fermi-liquid at low and high imbalance, respectively. The fermionic
sector of the LO gapless superconductor is also quite unique, exhibiting a
Fermi surface of Bogoliubov quasiparticles associated with the Andreev band of
states, localized on the array of the LO domain-walls.Comment: 56 pages, 21 figure
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