Incommensurate magnetic order in the alpha-Fe(Te,Se) superconductor systems

Magnetic spin fluctuations is one candidate to produce the bosonic modes that mediate the superconductivity in the ferrous superconductors. Up until now, all of the LaOFeAs and BaFe2As2 structure types have simple commensurate magnetic ground states, as result of nesting Fermi surfaces. This type of spin-density-wave (SDW) magnetic order is known to be vulnerable to shifts in the Fermi surface when electronic densities are altered at the superconducting compositions. Superconductivity has more recently been discovered in alpha-Fe(Te,Se), whose electronically active antifluorite planes are isostructural to the FeAs layers found in the previous ferrous superconductors and share with them the same quasi-two-dimensional electronic structure. Here we report neutron scattering studies that reveal a unique complex incommensurate antiferromagnetic order in the parent compound alpha-FeTe. When the long-range magnetic order is suppressed by the isovalent substitution of Te with Se, short-range correlations survive in the superconducting phase.Comment: 27 pages, 7 figures, 1 tabl

Superconductivity in a layered cobalt oxyhydrate Na0.31_{0.31}CoO2⋅_{2}\cdot1.3H2_{2}O

We report the electrical, magnetic and thermal measurements on a layered cobalt oxyhydrate Na$_{0.31}$CoO$_{2}\cdot$1.3H$_{2}$O. Bulk superconductivity at 4.3 K has been confirmed, however, the measured superconducting fraction is relatively low probably due to the sample's intrinsic two-dimensional characteristic. The compound exhibits weak-coupled and extreme type-II superconductivity with the average energy gap $\Delta_{a}(0)$ and the Ginzburg-Landau parameter $\kappa$ of $\sim$ 0.50 meV and $\sim$ 140, respectively. The normalized electronic specific heat data in the superconducting state well fit the $T^{3}$ dependence, suggesting point nodes for the superconducting gap structure.Comment: 4 pages, 3 figure

Reemerging superconductivity at 48 K across quantum criticality in iron chalcogenides

Pressure plays an essential role in the induction1 and control2,3 of superconductivity in iron-based superconductors. Substitution of a smaller rare-earth ion for the bigger one to simulate the pressure effects has surprisingly raised the superconducting transition temperature Tc to the record high 55 K in these materials4,5. However, Tc always goes down after passing through a maximum at some pressure and the superconductivity eventually tends to disappear at sufficiently high pressures1-3. Here we show that the superconductivity can reemerge with a much higher Tc after its destruction upon compression from the ambient-condition value of around 31 K in newly discovered iron chalcogenide superconductors. We find that in the second superconducting phase the maximum Tc is as high as 48.7 K for K0.8Fe1.70Se2 and 48 K for (Tl0.6Rb0.4)Fe1.67Se2, setting the new Tc record in chalcogenide superconductors. The presence of the second superconducting phase is proposed to be related to pressure-induced quantum criticality. Our findings point to the potential route to the further achievement of high-Tc superconductivity in iron-based and other superconductors.Comment: 20 pages and 7 figure

The AntAWS dataset: a compilation of Antarctic automatic weather station observations

A new meteorological dataset derived from records of Antarctic automatic weather stations (here called the AntAWS dataset) at 3 h, daily and monthly resolutions including quality control information is presented here. This dataset integrates the measurements of air temperature, air pressure, relative humidity, and wind speed and direction from 267 Antarctic AWSs obtained from 1980 to 2021. The AWS spatial distribution remains heterogeneous, with the majority of instruments located in near-coastal areas and only a few inland on the East Antarctic Plateau. Among these 267 AWSs, 63 have been operating for more than 20 years and 27 of them in excess of more than 30 years. Of the five meteorological parameters, the measurements of air temperature have the best continuity and the highest data integrity. The overarching aim of this comprehensive compilation of AWS observations is to make these data easily and widely accessible for efficient use in local, regional and continental studies; it may be accessed at 10.48567/key7-ch19 (Wang et al., 2022). This dataset is invaluable for improved characterization of the surface climatology across the Antarctic continent, to improve our understanding of Antarctic surface snow-Atmosphere interactions including precipitation events associated with atmospheric rivers and to evaluate regional climate models or meteorological reanalysis products

The AntAWS dataset: a compilation of Antarctic automatic weather station observations

A new meteorological dataset derived from records of Antarctic automatic weather stations (here called the AntAWS dataset) at 3 h, daily and monthly resolutions including quality control information is presented here. This dataset integrates the measurements of air temperature, air pressure, relative humidity, and wind speed and direction from 267 Antarctic AWSs obtained from 1980 to 2021. The AWS spatial distribution remains heterogeneous, with the majority of instruments located in near-coastal areas and only a few inland on the East Antarctic Plateau. Among these 267 AWSs, 63 have been operating for more than 20 years and 27 of them in excess of more than 30 years. Of the five meteorological parameters, the measurements of air temperature have the best continuity and the highest data integrity. The overarching aim of this comprehensive compilation of AWS observations is to make these data easily and widely accessible for efficient use in local, regional and continental studies; it may be accessed at https://doi.org/10.48567/key7-ch19 (Wang et al., 2022). This dataset is invaluable for improved characterization of the surface climatology across the Antarctic continent, to improve our understanding of Antarctic surface snow–atmosphere interactions including precipitation events associated with atmospheric rivers and to evaluate regional climate models or meteorological reanalysis products

Atomic-scale fingerprint of Mn dopant at the surface of Sr₃(Ru₁-xMnx)₂O₇

Chemical doping in materials is known to give rise to emergent phenomena. These phenomena are extremely difficult to predict a priori, because electron-electron interactions are entangled with local environment of assembled atoms. Scanning tunneling microscopy and low energy electron diffraction are combined to investigate how the local electronic structure is correlated with lattice distortion on the surface of Sr3(Ru1-xMnx)2O7, which has double-layer building blocks formed by (Ru/Mn)O6 octahedra with rotational distortion. The presence of doping-dependent tilt distortion of (Ru/Mn)O6 octahedra at the surface results in a C2v broken symmetry in contrast with the bulk C4v counterpart. It also enables us to observe two Mn sites associated with the octahedral rotation in the bulk through the chirality of local electronic density of states surrounding Mn, which is randomly distributed. These results serve as fingerprint of chemical doping on the atomic scale

Role of antiferromagnetic ordering in the (1×2) surface reconstruction of Ca(Fe(1-x)Co(x))2As2

Low energy electron diffraction, scanning tunneling microscopy and spectroscopy, and first-principles spin-dependent density functional theory are utilized to investigate the geometric, electronic, and magnetic structures of the stripe-ordered (1×2) surface of Ca(Fe1-xCox)2As2 (x=0, 0.075). The surface is terminated with a 50% Ca layer. Compared to the bulk, the surface Ca layer has a large inward relaxation (∼0.5  Å), and the underneath As-Fe2-As layer displays a significant buckling. First-principles calculations show that the (1×2) phase is stabilized by the bulk antiferromagnetic spin ordering through the spin-charge-lattice coupling. Strikingly, a superconducting gap (∼7  meV at 7.4 K) is observed to spatially coexist with the (1×2) phase (x=0.075 compound). This implies the coexistence of both superconductivity and AFM ordering at the surface

A Biocatalytic Platform for the Synthesis of Enantiopure Propargylic Alcohols and Amines

Propargylic alcohols and amines are versatile building blocks in organic synthesis. We demonstrate a straightforward enzymatic cascade to synthesize enantiomerically pure propargylic alcohols and amines from readily available racemic starting materials. In the first step, the peroxygenase from Agrocybe aegerita converted the racemic propargylic alcohols into the corresponding ketones, which then were converted into the enantiomerically pure alcohols using the (R)-selective alcohol dehydrogenase from Lactobacillus kefir or the (S)-selective alcohol dehydrogenase from Thermoanaerobacter brokii. Moreover, an enzymatic Mitsunobu-type conversion of the racemic alcohols into enantiomerically enriched propargylic amines using (R)-selective amine transaminase from Aspergillus terreus or (S)-selective amine transaminase from Chromobacterium violaceum was established. The one-pot two-step cascade reaction yielded a broad range of enantioenriched alcohol and amine products in 70-99% yield. BT/Biocatalysi