62,406 research outputs found
Charge Transfer in Partition Theory
The recently proposed Partition Theory (PT) [J.Phys.Chem.A 111, 2229 (2007)]
is illustrated on a simple one-dimensional model of a heteronuclear diatomic
molecule. It is shown that a sharp definition for the charge of molecular
fragments emerges from PT, and that the ensuing population analysis can be used
to study how charge redistributes during dissociation and the implications of
that redistribution for the dipole moment. Interpreting small differences
between the isolated parts' ionization potentials as due to environmental
inhomogeneities, we gain insight into how electron localization takes place in
H2+ as the molecule dissociates. Furthermore, by studying the preservation of
the shapes of the parts as different parameters of the model are varied, we
address the issue of transferability of the parts. We find good transferability
within the chemically meaningful parameter regime, raising hopes that PT will
prove useful in chemical applications.Comment: 12 pages, 16 figure
A novel method for the injection and manipulation of magnetic charge states in nanostructures
Realising the promise of next-generation magnetic nanotechnologies is
contingent on the development of novel methods for controlling magnetic states
at the nanoscale. There is currently demand for simple and flexible techniques
to access exotic magnetisation states without convoluted fabrication and
application processes. 360 degree domain walls (metastable twists in
magnetisation separating two domains with parallel magnetisation) are one such
state, which is currently of great interest in data storage and magnonics.
Here, we demonstrate a straightforward and powerful process whereby a moving
magnetic charge, provided experimentally by a magnetic force microscope tip,
can write and manipulate magnetic charge states in ferromagnetic nanowires. The
method is applicable to a wide range of nanowire architectures with
considerable benefits over existing techniques. We confirm the method's
efficacy via the injection and spatial manipulation of 360 degree domain walls
in Py and Co nanowires. Experimental results are supported by micromagnetic
simulations of the tip-nanowire interaction.Comment: in Scientific Reports (2016
Local and global statistical distances are equivalent on pure states
The statistical distance between pure quantum states is obtained by finding a
measurement that is optimal in a sense defined by Wootters. As such, one may
expect that the statistical distance will turn out to be different if the set
of possible measurements is restricted in some way. It nonetheless turns out
that if the restriction is to local operations and classical communication
(LOCC) on any multipartite system, then the statistical distance is the same as
it is without restriction, being equal to the angle between the states in
Hilbert space.Comment: 5 pages, comments welcom
First-principles investigation of 180-degree domain walls in BaTiO_3
We present a first-principles study of 180-degree ferroelectric domain walls
in tetragonal barium titanate. The theory is based on an effective Hamiltonian
that has previously been determined from first-principles
ultrasoft-pseudopotential calculations. Statistical properties are investigated
using Monte Carlo simulations. We compute the domain-wall energy, free energy,
and thickness, analyze the behavior of the ferroelectric order parameter in the
interior of the domain wall, and study its spatial fluctuations. An abrupt
reversal of the polarization is found, unlike the gradual rotation typical of
the ferromagnetic case.Comment: Revtex (preprint style, 13 pages) + 3 postscript figures. A version
in two-column article style with embedded figures is available at
http://electron.rutgers.edu/~dhv/preprints/index.html#pad_wal
Measuring the Generalized Friendship Paradox in Networks with Quality-dependent Connectivity
The friendship paradox is a sociological phenomenon stating that most people
have fewer friends than their friends do. The generalized friendship paradox
refers to the same observation for attributes other than degree, and it has
been observed in Twitter and scientific collaboration networks. This paper
takes an analytical approach to model this phenomenon. We consider a
preferential attachment-like network growth mechanism governed by both node
degrees and `qualities'. We introduce measures to quantify paradoxes, and
contrast the results obtained in our model to those obtained for an
uncorrelated network, where the degrees and qualities of adjacent nodes are
uncorrelated. We shed light on the effect of the distribution of node qualities
on the friendship paradox. We consider both the mean and the median to measure
paradoxes, and compare the results obtained by using these two statistics
Train of high-power femtosecond pulses: Probe wave in a gas of prepared atoms
We present a new method for generating a regular train of ultrashort optical
pulses in a prepared two-level medium. The train develops from incident
monochromatic probe radiation travelling in a medium of atoms, which are in a
quantum mechanical superposition of dressed internal states. In the frame of
used linear theory for the probe radiation, the energy of individual pulses is
an exponentially growing function of atom density and of interaction cross
section. Pulse repetition rate is determined by the generalized Rabi frequency
and can be around 1 THz and greater. We also show that the terms, extra to the
dipole approximation, endow the gas by a new property: non-saturating
dependence of refractive index on the dressing monochromatic field intensity.
Contribution of these nonsaturating terms can be compatible with the main
dipole approximation in the wavelength region of about ten micrometers (the
range of CO_2 laser) or larger
On Toroidal Horizons in Binary Black Hole Inspirals
We examine the structure of the event horizon for numerical simulations of
two black holes that begin in a quasicircular orbit, inspiral, and finally
merge. We find that the spatial cross section of the merged event horizon has
spherical topology (to the limit of our resolution), despite the expectation
that generic binary black hole mergers in the absence of symmetries should
result in an event horizon that briefly has a toroidal cross section. Using
insight gained from our numerical simulations, we investigate how the choice of
time slicing affects both the spatial cross section of the event horizon and
the locus of points at which generators of the event horizon cross. To ensure
the robustness of our conclusions, our results are checked at multiple
numerical resolutions. 3D visualization data for these resolutions are
available for public access online. We find that the structure of the horizon
generators in our simulations is consistent with expectations, and the lack of
toroidal horizons in our simulations is due to our choice of time slicing.Comment: Submitted to Phys. Rev.
Local Isoelectronic Reactivity of Solid Surfaces
The quantity w^N(r) = ( 1/ k^2 T_el)[partial n(r, T_el) / partial
T_el]_(v(r),N) is introduced as a convenient measure of the local isoelectronic
reactivity of surfaces. It characterizes the local polarizability of the
surface and it can be calculated easily. The quantity w^N(r) supplements the
charge transfer reactivity measured e.g. by the local softness to which it is
closely related. We demonstrate the applicability and virtues of the function
w^N(r) for the example of hydrogen dissociation and adsorption on Pd(100).Comment: RevTeX, 13 pages, 3 figures, to appear in Phys. Rev. Let
Heteronuclear ionizing collisions between laser-cooled metastable helium atoms
We have investigated cold ionizing heteronuclear collisions in dilute
mixtures of metastable (2 3S1) 3He and 4He atoms, extending our previous work
on the analogous homonuclear collisions [R. J. W. Stas et al., PRA 73, 032713
(2006)]. A simple theoretical model of such collisions enables us to calculate
the heteronuclear ionization rate coefficient, for our quasi-unpolarized gas,
in the absence of resonant light (T = 1.2 mK): K34(th) = 2.4*10^-10 cm^3/s.
This calculation is supported by a measurement of K34 using magneto-optically
trapped mixtures containing about 1*10^8 atoms of each species, K34(exp) =
2.5(8)*10^-10 cm^3/s. Theory and experiment show good agreement.Comment: 8 pages, 6 figure
High field magneto-transport in high mobility gated InSb/InAlSb quantum well heterostructures
We present high field magneto-transport data from a range of 30nm wide
InSb/InAlSb quantum wells. The low temperature carrier mobility of the samples
studied ranged from 18.4 to 39.5 m2V-1s-1 with carrier densities between
1.5x1015 and 3.28x1015 m-2. Room temperature mobilities are reported in excess
of 6 m2V-1s-1. It is found that the Landau level broadening decreases with
carrier density and beating patterns are observed in the magnetoresistance with
non-zero node amplitudes in samples with the narrowest broadening despite the
presence of a large g-factor. The beating is attributed to Rashba splitting
phenomenon and Rashba coupling parameters are extracted from the difference in
spin populations for a range of samples and gate biases. The influence of
Landau level broadening and spin-dependent scattering rates on the observation
of beating in the Shubnikov-de Haas oscillations is investigated by simulations
of the magnetoconductance. Data with non-zero beat node amplitudes are
accompanied by asymmetric peaks in the Fourier transform, which are
successfully reproduced by introducing a spin-dependent broadening in the
simulations. It is found that the low-energy (majority) spin up state suffers
more scattering than the high-energy (minority) spin down state and that the
absence of beating patterns in the majority of (lower density) samples can be
attributed to the same effect when the magnitude of the level broadening is
large
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