365 research outputs found

    Money and mental contents

    Get PDF
    It can be hard to see where money fits in the world. Money seems both real and imaginary, since it has obvious causal powers, but is also, just as obviously, something humans have just made up. Recent philosophical accounts of money have declared it to be real, but for very different reasons. John Searle and Francesco Guala disagree over whether money is just whatever acts like money, or just whatever people believe to be money. In developing their accounts of institutions as a part of social reality, each uses money as a paradigm institution, but they disagree on how institutions exist. Searle argues that the institution of money belongs to an ontological level separate from the physical world, held up by the collective intentions of a group, while Guala claims that money is a part of the ordinary physical world and is just whatever performs a “money-like function” in a group, regardless of what that group believes about it. Here, we argue that any purely functional account like Guala’s will be unable to capture the distinctive phenomenon of money, since monetary transactions are defined by the attitudes transactors hold toward them. Money will be obscured or misidentified if defined functionally. As we go on to show by examining recent work by Smit et al., belief in money does not require taking on all of Searle’s ontological commitments, but money and mental contents will stand or fall together

    Measurable Functions and Topolgical Algebra

    Full text link
    In this paper we show that if (X,A)(X,\mathcal{A}) is a measurable space and if YY is a topological model of a Lawvere theory T\mathcal{T} equipped with B\mathcal{B} the Borel σ\sigma-algebra on YY, then the set of B\mathcal{B}-measurable functions from XX to YY, Meas⁥(X,Y)\operatorname{Meas}(X,Y), is a set-theoretic model of T\mathcal{T}. As a corollary we give short proofs of the facts that the set of real-valued measurable functions on a measurable space XX is a ring and the set of complex-valued measurable functions from XX to C\mathbb{C} is a ring.Comment: 11 Page

    Electrocatalytic reactions of inorganic nitrogen-containing compounds

    Get PDF

    In situ microscopic investigation of ion migration on the surface of chromium coated steels

    Get PDF
    Cathodic spreading of electrolyte on two-layers chromium coatings electrodeposited from trivalent chromium electrolyte on steel was studied on the micro- and the macroscale. The behavior is discussed in view of results obtained on electrical conductivity as measured by current-sensing atomic force microscopy. The coatings were found to hinder electron transport. Heterogeneities observed in the electrical conductivity are correlated to heterogeneities of the electrolyte spreading behavior, studied using in situ scanning Kelvin probe force microscopy. In average, the kinetics of spreading observed at microscopic scales are similar to that observed using a scanning Kelvin probe at larger scales. The scanning Kelvin probe force microscopy is demonstrated as a robust in situ technique to follow electrolyte spreading and study microscopic defects/heterogeneities on the surface

    The Kinetics and Mechanism of Atmospheric Corrosion Occurring on Tin and Iron-Tin Intermetallic Coated Steels: II. Filiform Corrosion

    Get PDF
    This paper describes a systematic study into the initiation and propagation of filiform corrosion (FFC) on pure iron, pure tin and industrially important tin and iron-tin intermetallic (FeSn and FeSn2) coatings for packaging steels, as a function of coating weight. The time-dependent extent of FFC was determined optically. FFC was not observed on pure tin or tin coatings but was found to propagate at significantly reduced rates on the FeSn and FeSn2 intermetallic coatings, when compared to pure iron. An explanation of the findings is given, firstly, in terms of the open circuit potential (OCP) and the extent to which polarity of the galvanic corrosion cell formed between relevant phases permits FFC propagation, and secondly in terms of the relative susceptibility of the various phases to anodic dissolution. It is concluded that even when FFC is feasible thermodynamically, propagation rates may be negligible due to the low activity for anodic dissolution of tin and iron-tin intermetallics

    Importance Sampling for Credit Risk Monte Carlo Simulations using the Cross Entropy method

    Get PDF
    For this thesis, we applied the Cross Entropy method on a credit risk model for the ING wholesale lending portfolio and some synthetically created realistic portfolios. The Cross Entropy method is found to be able to find appropriate Importance Sampling parameters within a relative modest resource budget. With the new parameters, the standard deviation of the estimate that the losses will exceed the available buffer can be decreased with more than 95%. A similar reduction with regular Monte Carlo would require the number of scenarios to increase four hundred times. Alternative methods provide similar reductions, but these use numerical methods that are more complex to implement and require more resources to calculate. Further tests show that the method is robust to the parameters used in the Cross Entropy method (within reasonable limits), it is not influenced significantly by the constitution of the portfolio and that none of the problems occur that the scientific literature warns about (in particular the “degeneracy of the likelihood ratio”)

    Covalent polymer functionalization of graphene/graphene oxide and its application as anticorrosion materials

    Get PDF
    Research on grapheme-polymer composites as the promising ion barrier materials to tackle the corrosion issue is rapidly developing and attracts interests from both academia and industry. In this minireview, we highlight the covalent functionalization of graphene and its derivatives such as graphene oxide (GO) with polymer brushes, and their application in anticorrosion within the last 3 years. There are some recent excellent reviews published on single layer graphene and graphene-based polymer composites for anticorrosion. However, the covalent functionalization of graphene and GO with polymer brushes for application in anticorrosion has not been addressed in those reviews. In this review, we describe first the current state of the art of covalent functionalization of graphene/GO with polymer brushes. We then discuss the application of pristine graphene as anticorrosion material and its drawbacks which can be overcome by graphene-based polymer composites. Afterwards, we discuss in detail the recent progress and development of covalent polymer functionalized graphene/GO as anticorrosion coatings, reported within the last 3 years. Finally, as perspective, we will briefly summarize the work on composites of polymers with other two-dimensional (2D) materials as anticorrosion coatings. Herein, hexagonal boron nitride, the most studied 2D materials after graphene, and Ti3C2Tx MXene which is the rising star of 2D transition metal carbide/nitride will be discussed

    Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub>MXene Polymer Composites for Anticorrosion:An Overview and Perspective

    Get PDF
    [Image: see text] As the most studied two-dimensional (2D) material from the MXene family, Ti(3)C(2)T(x) has constantly gained interest from academia and industry. Ti(3)C(2)T(x) MXene has the highest electrical conductivity (up to 24,000 S cm(–1)) and one of the highest stiffness values with a Young’s modulus of ∌ 334 GPa among water-dispersible conductive 2D materials. The negative surface charge of MXene helps to disperse it well in aqueous and other polar solvents. This solubility across a wide range of solvents, excellent interface interaction, tunable surface functionality, and stability with other organic/polymeric materials combined with the layered structure of Ti(3)C(2)T(x) MXene make it a promising material for anticorrosion coatings. While there are many reviews on Ti(3)C(2)T(x) MXene polymer composites for catalysis, flexible electronics, and energy storage, to our knowledge, no review has been published yet on MXenes’ anticorrosion applications. In this brief report, we summarize the current progress and the development of Ti(3)C(2)T(x) polymer composites for anticorrosion. We also provide an outlook and discussion on possible ways to improve the exploitation of Ti(3)C(2)T(x) polymer composites as anticorrosive materials. Finally, we provide a perspective beyond Ti(3)C(2)T(x) MXene composition for the development of future anticorrosion coatings
    • 

    corecore