54 research outputs found

    Palladium-Catalyzed Oxidative Domino Carbocyclization- Carbonylation-Alkynylation of Enallenes

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    An oxidative carbocyclization-carbonylation-alkynylation reaction cascade has been developed using catalytic amounts of palladium(II) salts. The domino reaction proceeds efficiently, giving the corresponding ynones in good to excellent yields under operationally simple conditions. A wide range of aromatic and aliphatic terminal alkynes with various functional groups are tolerated under the reaction conditions.AuthorCount:2;</p
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