Nonlinear screening theory of the Coulomb glass

A nonlinear screening theory is formulated to study the problem of gap formation and its relation to glassy freezing in classical Coulomb glasses. We find that a pseudo-gap ("plasma dip") in a single-particle density of states begins to open already at temperatures comparable to the Coulomb energy. This phenomenon is shown to reflect the emergence of short range correlations in a liquid (plasma) phase, a process which occurs even in the absence of disorder. Glassy ordering emerges when disorder is present, but this occurs only at temperatures more then an order of magnitude lower, which is shown to follow from nonlinear screening of the Coulomb interaction. Our result suggest that the formation of the "plasma dip" at high temperatures is a process distinct from the formation of the Efros-Shklovskii (ES) pseudo-gap, which in our model emerges only within the glassy phase.Comment: 5 pages, 2 figures, accepted for publication to Phys. Rev. Let

Glassy dynamics in geometrically frustrated Coulomb liquids without disorder

We show that introducing long-range Coulomb interactions immediately lifts the massive ground state degeneracy induced by geometric frustration for electrons on quarter-filled triangular lattices in the classical limit. Important consequences include the stabilization of a stripe-ordered crystalline (global) ground state, but also the emergence of very many low-lying metastable states with amorphous "stripe-glass" spatial structures. Melting of the stripe order thus leads to a frustrated Coulomb liquid at intermediate temperatures, showing remarkably slow (viscous) dynamics, with very long relaxation times growing in Arrhenius fashion upon cooling, as typical of strong glass formers. On shorter time scales, the system falls out of equilibrium and displays the aging phenomena characteristic of supercooled liquids above the glass transition. Our results show remarkable similarity with the recent observations of charge-glass behavior in ultra-clean triangular organic materials of the $\theta$-(BEDT-TTF)$_2$ family.Comment: 5 pages,4 figure

Critical role of electronic correlations in determining crystal structure of transition metal compounds

The choice that a solid system "makes" when adopting a crystal structure (stable or metastable) is ultimately governed by the interactions between electrons forming chemical bonds. By analyzing 6 prototypical binary transition-metal compounds we demonstrate here that the orbitally-selective strong $d$-electron correlations influence dramatically the behavior of the energy as a function of the spatial arrangements of the atoms. Remarkably, we find that the main qualitative features of this complex behavior can be traced back to simple electrostatics, i.e., to the fact that the strong $d$-electron correlations influence substantially the charge transfer mechanism, which, in turn, controls the electrostatic interactions. This result advances our understanding of the influence of strong correlations on the crystal structure, opens a new avenue for extending structure prediction methodologies to strongly correlated materials, and paves the way for predicting and studying metastability and polymorphism in these systems.Comment: Main text: 8 pages, 4 figures, 1 table; Supplemental material: 2 pages, 1 figure, 2 table

The origin of Mooij correlations in disordered metals

Sufficiently disordered metals display systematic deviations from the behavior predicted by semi-classical Boltzmann transport theory. Here the scattering events from impurities or thermal excitations can no longer be considered as additive independent processes, as asserted by Matthiessen's rule following from this picture. In the intermediate region between the regime of good conduction and that of insulation, one typically finds a change of sign of the temperature coefficient of resistivity (TCR), even at elevated temperature spanning ambient conditions, a phenomenology that was first identified by Mooij in 1973. Traditional weak coupling approaches to identify relevant corrections to the Boltzmann picture focused on long distance interference effects such as "weak localization", which are especially important in low dimensions (1D, 2D) and close to the zero temperature limit. Here we formulate a strong-coupling approach to tackle the interplay of strong disorder and lattice deformations (phonons) in bulk three-dimensional metals at high temperatures. We identify a polaronic mechanism of strong disorder renormalization, which describes how a lattice locally responds to the relevant impurity potential. This mechanism, which quantitatively captures the Mooij regime, is physically distinct and unrelated to Anderson localization, but realizes early seminal ideas of Anderson himself, concerning the interplay of disorder and lattice deformations

Emergent Bloch excitations in Mott matter

We develop a unified theoretical picture for excitations in Mott systems, portraying both the heavy quasiparticle excitations and the Hubbard bands as features of an emergent Fermi liquid state formed in an extended Hilbert space, which is nonperturbatively connected to the physical system. This observation sheds light on the fact that even the incoherent excitations in strongly correlated matter often display a well-defined Bloch character, with pronounced momentum dispersion. Furthermore, it indicates that the Mott point can be viewed as a topological transition, where the number of distinct dispersing bands displays a sudden change at the critical point. Our results, obtained from an appropriate variational principle, display also remarkable quantitative accuracy. This opens an exciting avenue for fast realistic modeling of strongly correlated materials

Universality of modulation length (and time) exponents

We study systems with a crossover parameter lambda, such as the temperature T, which has a threshold value lambda* across which the correlation function changes from exhibiting fixed wavelength (or time period) modulations to continuously varying modulation lengths (or times). We report on a new exponent, nuL, characterizing the universal nature of this crossover. These exponents, similar to standard correlation length exponents, are obtained from motion of the poles of the momentum (or frequency) space correlation functions in the complex k-plane (or omega-plane) as the parameter lambda is varied. Near the crossover, the characteristic modulation wave-vector KR on the variable modulation length "phase" is related to that on the fixed modulation length side, q via |KR-q|\propto|T-T*|^{nuL}. We find, in general, that nuL=1/2. In some special instances, nuL may attain other rational values. We extend this result to general problems in which the eigenvalue of an operator or a pole characterizing general response functions may attain a constant real (or imaginary) part beyond a particular threshold value, lambda*. We discuss extensions of this result to multiple other arenas. These include the ANNNI model. By extending our considerations, we comment on relations pertaining not only to the modulation lengths (or times) but also to the standard correlation lengths (or times). We introduce the notion of a Josephson timescale. We comment on the presence of "chaotic" modulations in "soft-spin" and other systems. These relate to glass type features. We discuss applications to Fermi systems - with particular application to metal to band insulator transitions, change of Fermi surface topology, divergent effective masses, Dirac systems, and topological insulators. Both regular periodic and glassy (and spatially chaotic behavior) may be found in strongly correlated electronic systems.Comment: 22 pages, 15 figure