Una máscara teatral de doble cara preservada en el museo de Lipari (Mesina): estudio y reconstrucción 3d mediante equipo portátil

[EN] The new tools for 3D survey and modelling (as portable scanners and software packages), often in combination with diagnostics, are nowadays able to provide indispensable elements for the study of archaeological artefacts; their applications to museum’s heritage can be also useful to integrate the traditional graphic documentation and contribute to enhancement and dissemination. This paper shows the benefit of using the aforementioned tools to study the peculiar clay mask No. 11114-E, discovered in 1973 in the Greek necropolis of Lipára, inside tomb No. 1558. The specimen, now exhibited in the Classical Section of the Aeolian Museum, is considered unique both in the Aeolian Islands and in the ancient Greek world, as it is the only one merging two half faces attributable to different characters. This feature, unknown at the time of discovery, has been highlighted in 2018, thanks to a restoration intervention by which a hard concretion layer covering a large portion of the mask surface was removed, bringing to light a smiling young half-face next to an old one with Silenic features. In 2019, the mask was surveyed in situ through a portable and performing laser-scanner arm (the QuantumTM FaroArm by FARO) to produce a high-resolution 3D model useful to enhance the reading of the two halves (not evident enough, due to its state of preservation). The data processing was performed using the Geomagic Wrap software, able to align and merge multiple scans into a single model and to export results in multiple formats, easily shareable and viewable in free software or via the web. Finally, thanks to this method, the successful generation of a digital replica was performed; the resulting replica is useful for dissemination and as a support for the hypothetical reconstruction of the two prototypes taken as models by the craftsman who created the mask.Highlights:A 'mobile laboratory’ consisting of portable equipment has been set up to perform 3D metric surveys on a selection of artefacts preserved at the Museum of Lipari.By means of an ultra-precision laser-scanner arm, a 3D survey on a miniaturistic double-faced mask, belonging to the classical theatrical terracotta, has been performed.A geometrically accurate and realistic 3D final model has been created. This helped the study and reconstruction of the two characters composing the mask.[ES] Las nuevas herramientas para el levantamiento y el modelado en 3D (como son los escáneres portátiles y los paquetes de software), a menudo en combinación con equipos diagnósticos, pueden hoy en día proporcionar elementos indispensables para el estudio de objetos arqueológicos; sus aplicaciones al patrimonio del museo también pueden ser útiles para integrar la documentación gráfica tradicional y contribuir a su mejora y divulgación. Este artículo se refiere al estudio de un hallazgo peculiar procedente de la necrópolis griega de Lipára: la máscara de arcilla nº. 11114-E, descubierta en 1973 en el interior de la tumba nº. 1558 y ahora exhibida en la Sección Clásica del Museo Eólica. El espécimen se considera único, tanto en las Islas Eolias como en el mundo griego antiguo, ya que es la única que fusiona dos mitades atribuibles a diferentes personajes. Esta característica, desconocida en el momento del descubrimiento, se ha destacado en 2018, gracias a la intervención de restauración mediante la cual se ha eliminado una capa dura que cubre gran parte de la superficie de la máscara, sacando a la luz una media cara sonriente y joven, junto a una cara que muestra indicadores de vejez con rasgos selénicos. En 2019, la máscara se levantó in situ con un brazo de escáner láser portátil y funcional (FaroArm QuantumTM de FARO), con el objetivo de generar un modelo 3D de alta resolución útil que mejorara la lectura de las dos mitades (no visible debido a su estado de conservación). El procesamiento de datos se ha llevado a cabo empleando el software Geomagic Wrap capaz de alinear y fusionar múltiples escaneados en un solo modelo y exportarlo en múltiples formatos, fácilmente compartibles y visibles en software libre o vía web. Este método permitió, finalmente, la generación de una réplica digital que podría servir tanto para su divulgación, como de soporte que permita la reconstrucción hipotética de los dos prototipos que presumiblemente fueron de modelo para el artesano al crear la máscara.The writing of this paper was supported by the project “IDEHA-Innovation for Data Elaboration in Heritage Areas” (DUS.AD017.087).Giuffrida, D.; Mollica Nardo, V.; Adinolfi, O.; Mastelloni, MA.; Ponterio, RC. (2021). A theatrical double-faced mask preserved at the Museum of Lipari (Messina): study and 3D reconstruction through portable equipment. Virtual Archaeology Review. 12(24):39-48. https://doi.org/10.4995/var.2021.13916OJS39481224Alby, E., Vigouroux, E., & Elter, R. (2019). Implementation of survey and three-dimensional monitoring of archaeological excavations of the Khirbat al-Dusaq site, Jordan. 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Poly[(μ4-decanedioato)cobalt(II)]

In the title compound, [Co(C10H16O4)]n, the CoII atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of CoII atoms, one with the CoII atoms lying parallel to (100) [Co...Co = 4.653 (1) Å], the other lying parallel to (010) [Co...Co = 4.764 (1) Å]

{2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ2N,N′}(η3-prop-2-enyl)palladium(II) hexafluorophosphate

The title compound, [Pd(C3H5)(C17H15N3S2)]PF6, is built up by a [(η3-allyl)Pd]2+ fragment coordinated by a 2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The PdII atom is tetracoordinated in a strongly distorted square-planar environment mainly determined by the η3-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H...F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes

Functionalization of mesoporous silica nanoparticles through one-pot co-condensation in w/o emulsion

In this work, three different functionalized mesoporous silica nanoparticles (MSNs) were synthesized through the co-condensation synthesis in oil/water emulsion. Hexadecyltrimethoxysilane, triethoxy-3-(2-imidazolin-1-yl)propylsilane and (3-mercaptopropyl)triethoxysilane were used as organo-substituted silica precursors with variable molar ratio with respect to tetraethylorthosilicate (TEOS, 1:4, 1:9, 1:19). The occurred functionalization was investigated by Infrared Spectroscopy and FT-Raman and 29Si {1H} CP-MAS-NMR spectroscopy. Results show that the three materials were successfully functionalized. The influence of the different pendant groups and their concentration on the mesostructured pore organization of the obtained nanoparticles respect to the non-functionalized mesoporous silica was evaluated by means of Transmission Electron Microscopy and N2 sorption measurements. Bulky aliphatic C16 chains, especially in higher concentration, causes severe changes in mesoporous structure, leading to a more heterogeneous material. The imidazoline groups, instead, change the mesostructured morphology of the pores to an irregular but more interconnected one, while the presence of mercaptopropyl groups does not bring significant modifications. The different structural modifications in pore morphology observed between the samples is due to the different interactions between derivatized silica precursors and the components of the emulsion.SCOPUS: ar.jinfo:eu-repo/semantics/publishe

Tetrakis(μ-4-chlorobenzoato-κ2O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu)

In the centrosymmetric dinuclear title CuII complex, [Cu2(C7H4ClO2)(C2H5OH)2], the Cu—Cu distance is 2.5905 (4) Å. The two metal atoms are bridged by four 4-chlorobenzoate ligands and each has an ethanol molecule in the axial position of the overall octahedral coordination environment. The crystal packing features O—H...O hydrogen bonds

SERS and DFT study of indigo adsorbed on silver nanostructured surface

Surface-enhanced Raman spectroscopy has emerged as a widely used tool in the identification of organic dyes in works of art. Indigo is among the most used organic pigment, its identification can therefore give important information about the provenience and the making of the investigated work of art. In this work, we combine Surface Enhanced Raman Spectroscopy (SERS) experiments with density functional theory (DFT) computations of the Raman frequencies of indigo and an indigo molecule adsorbed onto a silver surface made of 16 silver atoms. The SERS spectrum of a molecule adsorbed on a metallic surface, in fact, can differ from the corresponding Raman one. The knowledge and the comprehension of the SERS spectrum then are mandatory in dyes identification. Experimental SERS spectra were acquired using ad hoc SERS active substrates consisting of pulsed laser ablated silver nanoparticles deposited onto a polishing sheet. The polishing sheet surface roughness is able to remove some pigments grains from the surface of a work of art without damage. DFT calculations provide a good description of the observed SERS spectra, in particular, the indigo-Ag16 structure gives a better description with respect to structures where only one or two silver atoms attached to the indigo molecule are considered

Chemometric Tools to Point Out Benchmarks and Chromophores in Pigments through Spectroscopic Data Analyses

Spectral preprocessing data and chemometric tools are analytical methods widely applied in several scientific contexts i.e., in archaeometric applications. A systematic classification of natural powdered pigments of organic and inorganic nature through Principal Component Analysis with a multi-instruments spectroscopic study is presented here. The methodology allows the access to elementary and molecular unique benchmarks to guide and speed up the identification of an unknown pigment and its recipe. This study is conducted on a set of 48 powdered pigments and tested on a real-case sample from the wall painting in S. Maria Delle Palate di Tusa (Messina, Italy). Four spectroscopic techniques (X-ray Fluorescence, Raman, Attenuated Total Reflectance and Total Reflectance Infrared Spectroscopies) and six different spectrometers are tested to evaluate the impact of different setups. The novelty of the work is to use a systematic approach on this initial dataset using the entire spectroscopic energy range without any windows selection to solve problems linked with the manipulation of large analytes/materials to find an indistinct property of one or more spectral bands opening new frontiers in the dataset spectroscopic analyses

The Church of S. Maria Delle Palate in Tusa (Messina, Italy): Digitization and Diagnostics for a New Model of Enjoyment

Cultural places represent the tangible part of the identity and historical heritage of a civilization as well as an extraordinary driving force for the economic development of a country. Within its huge asset, Italy counts a wide number of archaeological sites and monuments which, despite their cultural value, are totally cut off from the most important cultural routes. This paper aims to demonstrate how specific actions of digitization can contribute to valorize (restoring a cultural value) ‘marginal’ landmarks, promoting their knowledge and inclusion. The case study described is represented by the Church of “Santa Maria delle Palate”, located inside the well-known Archaeological Park of Halaesa Arconidea (Tusa, ME). The church, built in 1551 and subject to several renovations throughout the centuries, has been investigated as part of an interdisciplinary training and skill transfer project carried out by a CNR-IPCF research team. During the activities, the group of trainees approached a multi-analytic method for the study of many Sicilian places using different techniques such as laser scanning, photogrammetry, thermography and spectroscopy and collecting a large amount of information and data. In 2019, the building in question was the object of a complete architectural survey in order to obtain an accurate digital replica; moreover, the wall painting representing St. Francis, preserved in the southern nave, was investigated through non-invasive investigations (IR-imaging, XRF and Raman spectrometry) with the intention of collecting information about its state of preservation and nature of pigments used and help the restoration work, which would have been carried out in the following months. The result of the work is a combined “digital archive” useful not only for the purposes of conservation, monitoring and dissemination, but as a container of information enjoyable at different levels of depth. In addition to the scientific outcomes achieved for the study of the painting, relevant from the historical and artistic point of view, we must underline the importance of the work for the implementation of a web-based platform where expert and inexpert users can virtually access the church virtual tour and search for specialized contents (e.g., measures, analyzes results). Media such as this are finally demonstrated to be able to promote the inclusion (e.g., for people unable to reach the place or with reducing mobility) and accessibility to cultural places during ordinary (maintenance, closure) or extraordinary events (pandemic)

Binding of Arsenic by Common Functional Groups: An Experimental and Quantum-Mechanical Study

Arsenic is a well-known contaminant present in different environmental compartments and in human organs and tissues. Inorganic As(III) represents one of the most dangerous arsenic forms. Its toxicity is attributed to its great affinity with the thiol groups of proteins. Considering the simultaneous presence in all environmental compartments of other common functional groups, we here present a study aimed at evaluating their contribution to the As(III) complexation. As(III) interactions with four (from di- to hexa-) carboxylic acids, five (from mono- to penta-) amines, and four amino acids were evaluated via experimental methods and, in simplified systems, also by quantum-mechanical calculations. Data were analyzed also with respect to those previously reported for mixed thiol-carboxylic ligands to evaluate the contribution of each functional group (-SH, -COOH, and -NH2) toward the As(III) complexation. Formation constants of As(III) complex species were experimentally determined, and data were analyzed for each class of ligand. An empirical relationship was reported, taking into account the contribution of each functional group to the complexation process and allowing for a rough estimate of the stability of species in systems where As(III) and thiol, carboxylic, or amino groups are involved. Quantum-mechanical calculations allowed for the evaluation and the characterization of the main chelation reactions of As(III). The potential competitive effects of the investigated groups were evaluated using cysteine, a prototypical species possessing all the functional groups under investigation. Results confirm the higher binding capabilities of the thiol group under different circumstances, but also indicate the concrete possibility of the simultaneous binding of As(III) by the thiol and the carboxylic groups