Properties of HxTaS2

The preparation of Hx TaS2 (0 \u3c x \u3c 0.87) is described. The compounds are only marginally stable at room temperature, slowly evolving H2S and H2 (and possibly Hp in air). Magnetic susceptibility data show that a low temperature transformation in 2H ... TaS2 (at so•K) is suppressed with the addition of hydrogen, and· at the same time the superconducting transition temperature T c rises from 0.8 to ~4.2•K at x = 0.11. Heat capacity measurements near this concentration show the superconductivity to be a bulk effect. Finally, by correlation of this data with susceptibility and T c measurements in other intercalation compounds, we suggest that the rise of T c (at low electron transfer) is due to suppression of the low temperature transformation and not due to an excitonic mechanism of superconductivity

Web Browsing Behavior Analysis and Interactive Hypervideo

© ACM, 2013. This is the author's version of the work. It is posted here by permission of ACM for your personal use. Not for redistribution. The definitive version was published in, ACM Transactions on the Web, Vol. 7, No. 4, Article 20, Publication date: October 2013.http://doi.acm.org/ 10.1145/2529995.2529996[EN] Processing data on any sort of user interaction is well known to be cumbersome and mostly time consuming. In order to assist researchers in easily inspecting fine-grained browsing data, current tools usually display user interactions as mouse cursor tracks, a video-like visualization scheme. However, to date, traditional online video inspection has not explored the full capabilities of hypermedia and interactive techniques. In response to this need, we have developed SMT 2ǫ, a Web-based tracking system for analyzing browsing behavior using feature-rich hypervideo visualizations. We compare our system to related work in academia and the industry, showing that ours features unprecedented visualization capabilities. We also show that SMT 2ǫ efficiently captures browsing data and is perceived by users to be both helpful and usable. A series of prediction experiments illustrate that raw cursor data are accessible and can be easily handled, providing evidence that the data can be used to construct and verify research hypotheses. Considering its limitations, it is our hope that SMT 2ǫ will assist researchers, usability practitioners, and other professionals interested in understanding how users browse the Web.This work was partially supported by the MIPRCV Consolider Ingenio 2010 program (CSD2007-00018) and the TIN2009-14103-C03-03 project. It is also supported by the 7th Framework Program of the European Commision (FP7/2007-13) under grant agreement No. 287576 (CasMaCat).Leiva Torres, LA.; Vivó Hernando, RA. (2013). Web Browsing Behavior Analysis and Interactive Hypervideo. ACM Transactions on the Web. 7(4):20:1-20:28. https://doi.org/10.1145/2529995.2529996S20:120:287

Comercio, comerciantes y revolución en el Río de la Plata : Siglo XVIII - principios del siglo XIX

El objetivo de este texto es ordenar algunas preguntas que me hago en torno al lugar del comercio en la crisis de comienzos del siglo XIX en el Río de la Plata. Mucho se ha escrito sobre la aspiración al liberalismo económico por parte de un sector de la oligarquía rioplatense en tanto que una de las “causas” (para algunos la principal) de la revolución de independencia.Facultad de Humanidades y Ciencias de la Educació

Comercio, comerciantes y revolución en el Río de la Plata : Siglo XVIII - principios del siglo XIX

El objetivo de este texto es ordenar algunas preguntas que me hago en torno al lugar del comercio en la crisis de comienzos del siglo XIX en el Río de la Plata. Mucho se ha escrito sobre la aspiración al liberalismo económico por parte de un sector de la oligarquía rioplatense en tanto que una de las “causas” (para algunos la principal) de la revolución de independencia.Facultad de Humanidades y Ciencias de la Educació

Impact of biological agents on postsurgical complications in inflammatory bowel disease: A multicentre study of Geteccu

Background: The impact of biologics on the risk of postoperative complications (PC) in inflammatory bowel disease (IBD) is still an ongoing debate. This lack of evidence is more relevant for ustekinumab and vedolizumab. Aims: To evaluate the impact of biologics on the risk of PC. Methods: A retrospective study was performed in 37 centres. Patients treated with biologics within 12 weeks before surgery were considered “exposed”. The impact of the exposure on the risk of 30-day PC and the risk of infections was assessed by logistic regression and propensity score-matched analysis. Results: A total of 1535 surgeries were performed on 1370 patients. Of them, 711 surgeries were conducted in the exposed cohort (584 anti-TNF, 58 vedolizumab and 69 ustekinumab). In the multivariate analysis, male gender (OR: 1.5; 95% CI: 1.2–2.0), urgent surgery (OR: 1.6; 95% CI: 1.2–2.2), laparotomy approach (OR: 1.5; 95% CI: 1.1–1.9) and severe anaemia (OR: 1.8; 95% CI: 1.3–2.6) had higher risk of PC, while academic hospitals had significantly lower risk. Exposure to biologics (either anti-TNF, vedolizumab or ustekinumab) did not increase the risk of PC (OR: 1.2; 95% CI: 0.97–1.58), although it could be a risk factor for postoperative infections (OR 1.5; 95% CI: 1.03–2.27). Conclusions: Preoperative administration of biologics does not seem to be a risk factor for overall PC, although it may be so for postoperative infections

Diffusion-based structural connectivity patterns of multiple sclerosis phenotypes

Background: We aimed to describe the severity of the changes in brain diffusion-based connectivity as multiple sclerosis (MS) progresses and the microstructural characteristics of these networks that are associated with distinct MS phenotypes.Methods: Clinical information and brain MRIs were collected from 221 healthy individuals and 823 people with MS at 8 MAGNIMS centres. The patients were divided into four clinical phenotypes: clinically isolated syndrome, relapsing-remitting, secondary progressive and primary progressive. Advanced tractography methods were used to obtain connectivity matrices. Then, differences in whole-brain and nodal graph-derived measures, and in the fractional anisotropy of connections between groups were analysed. Support vector machine algorithms were used to classify groups.Results: Clinically isolated syndrome and relapsing-remitting patients shared similar network changes relative to controls. However, most global and local network properties differed in secondary progressive patients compared with the other groups, with lower fractional anisotropy in most connections. Primary progressive participants had fewer differences in global and local graph measures compared with clinically isolated syndrome and relapsing-remitting patients, and reductions in fractional anisotropy were only evident for a few connections. The accuracy of support vector machine to discriminate patients from healthy controls based on connection was 81%, and ranged between 64% and 74% in distinguishing among the clinical phenotypes.Conclusions: In conclusion, brain connectivity is disrupted in MS and has differential patterns according to the phenotype. Secondary progressive is associated with more widespread changes in connectivity. Additionally, classification tasks can distinguish between MS types, with subcortical connections being the most important factor