Manual sampling and tank size effects on the calibration curve of plot sediment storage tanks

In many experimental soil erosion plots, runoff is collected and carried by a conveyance system to a sequence of storage tanks. If the soil loss is measured by collecting, after mixing, samples of the stored suspension, then a calibration curve between the actual mean concentration (C) and the measured concentration (Cm) in the storage tank occurs. The aim of this article was to evaluate experimentally the factors affecting the relationship between C and Cm. For a sandy loam soil, the replicated measurements of Cm (20 samples) for two values of the actual concentration (C = 5 and 25 g/L) showed that the variability of the measurements of Cm is low and confirmed the reliability of a calibration curve obtained by a single series of runs. Results from experiments carried out with a clay soil to compare the calibration curves obtained by four field workers suggested that the maximum uncertainty in the soil loss measurement due to the choice of the calibration curve should not exceed 100% of the true value. Moreover, the slope of the calibration curve was independent of both the water level in the tank and the field worker. Finally, a comparison among the calibration curves of a prototype tank and some model tanks was carried out for both a sandy loam and a clay soil in order to establish a scaled−up relationship among tanks of different size. Soil−specific and theoretically based scaled−up relationships were deduced

The stereoselectivities of tributyltin hydride-mediated reductions of 5-bromo-D-glucuronides to L-iduronides are dependent on the anomeric substituent: syntheses and DFT calculations

One of the shortest synthetic routes to L-iduronic acid derivatives is via free radical reduction of the C-5 bromide of the corresponding protected D-glucuronic acid derivative. The epimerization of such C-5 bromides to the L-ido derivatives via reaction with tributyltin hydride was investigated. It was found that the stereoselectivity of the reaction was dependent on the anomeric substituent. If the substituent was fluoride the L-ido product was obtained exclusively in 65-72% yield whereas the O-methyl or O-acetyl derivatives led to isomeric mixtures of both the L-ido and D-gluco products in different ratios depending on the reaction conditions. DFT calculations were performed to determine the stereoelectronic factors that favour formation of the L-ido isomer from the fluoride and suggest the selectivity is due to a transition state gauche effect and an Sn-F interaction

Sequent depth ratio of B jumps on smooth and rough beds

A hydraulic B-jump has the toe section located on a positively sloping upstream channel and the roller end on a downstream horizontal channel. This paper analyses the B-jump on a rough bed, such as at the transition from a block ramp to the stilling basin. Laboratory measurements of the sequent depth were carried out using three different channel slopes for the rough bed and a single slope for the smooth bed. A solution useful for estimating the sequent depth ratio in a rectangular channel for different relative roughness and bed slope is proposed and positively tested by the present measurements. This solution can also be used to estimate the sequent depth ratio of classical hydraulic jumps or B-jumps on smooth and rough beds

Development of a colorimetric assay for heparanase activity suitable for kinetic analysis and inhibitor screening

The role that heparanase plays during metastasis and angiogenesis in tumors makes it an attractive target for cancer therapeutics. Despite this enzyme’s significance, most of the assays developed to measure its activity are complex. Moreover, they usually rely on labeling variable preparations of the natural substrate heparan sulfate, making comparisons across studies precarious. To overcome these problems, we have developed a convenient assay based on the cleavage of the synthetic heparin oligosaccharide fondaparinux. The assay measures the appearance of the disaccharide product of heparanase-catalyzed fondaparinux cleavage colorimetrically using the tetrazolium salt WST-1. Because this assay has a homogeneous substrate with a single point of cleavage, the kinetics of the enzyme can be reliably characterized, giving a Km of 46 μM and a kcat of 3.5 s−1 with fondaparinux as substrate. The inhibition of heparanase by the published inhibitor, PI-88, was also studied, and a Ki of 7.9 nM was determined. The simplicity and robustness of this method, should, not only greatly assist routine assay of heparanase activity but also could be adapted for high-throughput screening of compound libraries, with the data generated being directly comparable across studies

Lexical emergentism and the "frequency-by-regularity" interaction

In spite of considerable converging evidence of the role of inflectional paradigms in word acquisition and processing, little efforts have been put so far into providing detailed, algorithmic models of the interaction between lexical token frequency, paradigm frequency, paradigm regularity. We propose a neurocomputational account of this interaction, and discuss some theoretical implications of preliminary experimental results

Flow resistance law in channel with flexible submerged vegetation

In this paper, experimental data collected in a straight flume having a bed covered by grasslike vegetation have been used to analyze flow resistance for flexible submerged elements. At first, the measurements are used to test the applicability of Kouwen’s method. Then, a calibration of two coefficients appearing in the semilogarithmic flow resistance equation is carried out. Finally, applying the P-theorem and the incomplete self-similarity condition, a flow resistance equation linking the friction factor with the shear Reynolds number, the depth-vegetation height ratio and the inflection degree is deduced

Sequent depth ratio of B-jumps on smooth and rough beds

A hydraulic B-jump has the toe section located on a positively sloping upstream channel and the roller end on a downstream horizontal channel. This paper analyses the B-jump on a rough bed, such as at the transition from a block ramp to the stilling basin. Laboratory measurements of the sequent depth were carried out using three different channel slopes for the rough bed and a single slope for the smooth bed. A solution useful for estimating the sequent depth ratio in a rectangular channel for different relative roughness and bed slope is proposed and positively tested by the present measurements. This solution can also be used to estimate the sequent depth ratio of classical hydraulic jumps or B-jumps on smooth and rough beds

T2HSOM: Understanding the Lexicon by Simulating Memory Processes for Serial Order

Over the last several years, both theoretical and empirical approaches to lexical knowledge and encoding have prompted a radical reappraisal of the traditional dichotomy between lexicon and grammar. The lexicon is not simply a large waste basket of exceptions and sub-regularities, but a dynamic, possibly redundant repository of linguistic knowledge whose principles of relational organization are the driving force of productive generalizations. In this paper, we overview a few models of dynamic lexical organization based on neural network architectures that are purported to meet this challenging view. In particular, we illustrate a novel family of Kohonen self-organizing maps (T2HSOMs) that have the potential of simulating competitive storage of symbolic time series while exhibiting interesting properties of morphological organization and generalization. The model, tested on training samples of as morphologically diverse languages as Italian, German and Arabic, shows sensitivity to manifold types of morphological structure and can be used to bootstrap morphological knowledge in an unsupervised way

Reading as Active Sensing: A Computational Model of Gaze Planning in Word Recognition

We offer a computational model of gaze planning during reading that consists of two main components: a lexical representation network, acquiring lexical representations from input texts (a subset of the Italian CHILDES database), and a gaze planner, designed to recognize written words by mapping strings of characters onto lexical representations. The model implements an active sensing strategy that selects which characters of the input string are to be fixated, depending on the predictions dynamically made by the lexical representation network. We analyze the developmental trajectory of the system in performing the word recognition task as a function of both increasing lexical competence, and correspondingly increasing lexical prediction ability. We conclude by discussing how our approach can be scaled up in the context of an active sensing strategy applied to a robotic setting

Verifica delle equazioni disponibili per la stima della potenza cinetica delle precipitazioni naturali

Nella memoria sono riportati i risultati delle indagini condotte utilizzando le distribuzioni dimensionali delle gocce di pioggia (DSD) rilevate mediante un disdrometro ottico installato, nel periodo Giugno 2006 - Marzo 2014, presso il Dipartimento di Scienze Agrarie e Forestali dell’Università degli Studi di Palermo e nel periodo Luglio 2015-Gennaio 2016 presso la stazione sperimentale di El Teularet in Spagna. Dopo aver aggregato le DSD per classi di intensità differenti in ampiezza, è stata determinata la potenza cinetica associando a ciascun diametro della DSD aggregata la relativa velocità di caduta calcolata mediante una relazione reperita in letteratura. I valori di potenza cinetica così determinati sono stati utilizzati per testare l’applicabilità delle relazioni potenza cinetica-intensità della precipitazione proposte da Wischmeier and Smith (1978) e da Brown and Foster (1987). Le misure di potenza cinetica, dimostrano l’esistenza di un valore soglia di intensità di precipitazione superato il quale il diametro mediano volumetrico e, di conseguenza, la potenza cinetica, possono essere assunti costanti. Questi risultati costituiscono una verifica dell’approccio di Wischmeier e Smith (1978)