Effect of dopant on ion-dynamics of sodium ion-based flexible polyblend electrolyte for electrochemical device application

This work examines the impact of NaNO3 salt on a NaAlg: PVA blend polymer, focusing on charge carrier properties, such as number density (n), mobility (μ), and diffusion coefficient (D). It is found that the addition of NaNO3 increased the room temperature conductivity from (6.12±0.15) × 10−8 S cm−1 (PNN0, salt-free) to (6.50±0.03) × 10−6 S cm−1 (PNN15, 15 wt. NaNO3), influenced by increasing n compared to µ. Temperature-dependent conductivity revealed a significant influence of both n and μ on electrolyte conductivity, and the ion dynamics were explored using various formalisms. XRD studies showed reduced crystallinity owing to the interaction of Na+ and NO3− with -OH groups, as confirmed by IR spectroscopy. Scanning electron microscopy confirmed salt deposits at higher concentrations. However, sufficient mechanical strength was observed for the optimally conducting sample. Obtained results showed the potential applications of the sample in electrochemical devices

Ionic conductivity enhancement of PVA: carboxymethyl cellulose poly-blend electrolyte films through the doping of NaI salt

In this paper, we report the effect of doping sodium iodide (NaI) salt into a polymer blend matrix of sodium carboxymethyl cellulose (NaCMC) and poly(vinyl alcohol) (PVA). Solution casting approach was used to prepare solid polymer electrolyte (SPE) films. The films were characterized by Fourier-transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), electrical impedance spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). XRD showed that NaI incorporation decreased the crystallinity of NaCMC/PVA-based SPE. FTIR technique confirmed the complexation of salt with polymer matrix due to the formation of the coordination bond between Na+ and –OH group and hydrogen bond between I− and –CH group. The sample with 30 wt% NaI showed the highest conductivity of 2.52 × 10–3 S cm−1, strongly influenced by the highest charge concentration (n), not its mobility (μ). DSC analysis revealed an increase in glass transition temperature (Tg) with increasing salt content. TGA studies showed a decrease in thermal stability with salt inclusion. The transference number was found to be 0.99 for the highest conducting sample showing the primary charge carriers are ions. The highest conducting sample exhibited a mechanical strength of 15.42 MPa at room temperature, and it has been used to fabricate a battery to evaluate its suitability in energy storage devices

Correlations between the dopant concentration and ion transport properties of plasticized NaCMC-Pectin polyblend electrolyte membranes for electrochemical device applications

This study explores the structural and electrical properties of sodium carboxymethyl cellulose (NaCMC)–pectin (PC)–glycerol–NH4Br electrolyte films and investigates their potential applications in proton batteries. Plasticized solid polymer electrolyte (SPEs) films were fabricated using the solution casting method. The interaction between the salt and polymer blends was verified using Fourier-transform infrared (FTIR) analysis. Incorporation of various salt concentrations (up to 25 wt%) was found to enhance the amorphous phase of the polymer blend, as evidenced by X-ray diffraction (XRD) results. Additionally, the decrease in the glass transition temperature, as confirmed by DSC analysis, indicates that the inclusion of both plasticizer and salt contributed to this effect. An electrolyte with 25% wt. of NH4Br has the highest room temperature conductivity of 4.68 ×10−4 S cm−1. This electrolyte was employed to fabricate the proton battery for energy storage application.Internal Grant Agency of TBU in Zlin, (IGA/CPS/2023/002); Ministerstvo Školství, Mládeže a Tělovýchovy, MŠMT, (RP/CPS/2022/002)Ministry of Education, Youth, and Sports of the Czech Republic [RP/CPS/2022/002]; In- ternal Grant Agency of TBU in Zlin [IGA/CPS/2023/002

Modification in the microstructure of sodium carboxymethylcellulose/polyvinyl alcohol polyblend films through the incorporation of NaNO3 for energy storage applications

In this work, the effect of NaNO3 salt concentration (0, 5, 10, 15, 20, 25, and 30 wt.%) on the structural, electrical, and mechanical properties of Na-carboxymethyl cellulose/polyvinyl alcohol polyblend electrolyte films has been studied. X-ray diffraction showed an increase in the amorphous phase of the polymer blend with increasing salt concentration up to samples containing 20 wt.% of NaNO3 supported by the scanning electron microscope studies. Fourier-transform infrared analysis confirmed the complexation of the salt via coordinate bond/hydrogen bond with –OH and –CH groups of the polymer blend. The (Formula presented.) of the samples have been found to increase with salt concentration indicating transient cross-links. Nyquist plot fitting has been performed to evaluate the transport properties; hence carrier concentration influences ionic conductivity. The sample complexed with 20 wt.% of NaNO3 revealed the highest room temperature conductivity of 1.75 × 10−4 S cm−1, among all other samples with suitable mechanical strength to be incorporated into energy storage devices. The highest conducting electrolyte has been incorporated into a primary battery to showcase its potential application in energy storage devices

Insight into the Effect of Glycerol on Dielectric Relaxation and Transport Properties of Potassium-Ion-Conducting Solid Biopolymer Electrolytes for Application in Solid-State Electrochemical Double-Layer Capacitor

The increased interest in the transition from liquid to solid polymer electrolytes (SPEs) has driven enormous research in the area polymer electrolyte technology. Solid biopolymer electrolytes (SBEs) are a special class of SPEs that are obtained from natural polymers. Recently, SBEs have been generating much attention because they are simple, inexpensive, and environmentally friendly. In this work, SBEs based on glycerol-plasticized methylcellulose/pectin/potassium phosphate (MC/PC/K3PO4) are investigated for their potential application in an electrochemical double-layer capacitor (EDLC). The structural, electrical, thermal, dielectric, and energy moduli of the SBEs were analyzed via X-ray diffractometry (XRD), Fourier transforms infrared spectroscopy (FTIR), electrochemical impedance spectroscopy (EIS), transference number measurement (TNM), and linear sweep voltammetry (LSV). The plasticizing effect of glycerol in the MC/PC/K3PO4/glycerol system was confirmed by the change in the intensity of the samples’ FTIR absorption bands. The broadening of the XRD peaks demonstrates that the amorphous component of SBEs increases with increasing glycerol concentration, while EIS plots demonstrate an increase in ionic conductivity with increasing plasticizer content owing to the formation of charge-transfer complexes and the expansion of amorphous domains in polymer electrolytes (PEs). The sample containing 50% glycerol has a maximal ionic conductivity of about 7.5 × 10−4 scm−1, a broad potential window of 3.99 V, and a cation transference number of 0.959 at room temperature. Using the cyclic voltammetry (CV) test, the EDLC constructed from the sample with the highest conductivity revealed a capacitive characteristic. At 5 mVs−1, a leaf-shaped profile with a specific capacitance of 57.14 Fg−1 was measured based on the CV data

Substantial Proton Ion Conduction in Methylcellulose/Pectin/Ammonium Chloride Based Solid Nanocomposite Polymer Electrolytes: Effect of ZnO Nanofiller

In this research, nanocomposite solid polymer electrolytes (NCSPEs) comprising methylcellulose/pectin (MC/PC) blend as host polymer, ammonium chloride (NH4Cl) as an ion source, and zinc oxide nanoparticles (ZnO NPs) as nanofillers were synthesized via a solution cast methodology. Techniques such as Fourier transform infrared (FTIR), electrical impedance spectroscopy (EIS), and linear sweep voltammetry (LSV) were employed to characterize the electrolyte. FTIR confirmed that the polymers, NH4Cl salt, and ZnO nanofiller interact with one another appreciably. EIS demonstrated the feasibility of achieving a conductivity of 3.13 × 10−4 Scm−1 for the optimum electrolyte at room temperature. Using the dielectric formalism technique, the dielectric properties, energy modulus, and relaxation time of NH4Cl in MC/PC/NH4Cl and MC/PC/NH4Cl/ZnO systems were determined. The contribution of chain dynamics and ion mobility was acknowledged by the presence of a peak in the imaginary portion of the modulus study. The LSV measurement yielded 4.55 V for the comparatively highest conductivity NCSPE