6 research outputs found
Electrochemical Oxidative Fluorination of an Oxide Perovskite
We report on the electrochemical fluorination of the A-site vacant perovskite ReO3 using high-temperature solid-state cells as well as room-temperature liquid electrolytes. Using galvanostatic oxidation and electrochemical impedance spectroscopy, we find that ReO3 can be oxidized by approximately 0.5 equiv of electrons when in contact with fluoride-rich electrolytes. Results from our density functional theory calculations clearly rule out the most intuitive mechanism for charge compensation, whereby F-ions would simply insert onto the A-site of the perovskite structure. Operando X-ray diffraction, neutron total scattering measurements, X-ray spectroscopy, and solid-state 19F NMR with magic-angle spinning were, therefore, used to explore the mechanism by which fluoride ions react with the ReO3 electrode during oxidation. Taken together, our results indicate that a complex structural transformation occurs following fluorination to stabilize the resulting material. While we find that this process of fluorinating ReO3 appears to be only partially reversible, this work demonstrates a practical electrolyte and cell design that can be used to evaluate the mobility of small anions like fluoride that is robust at room temperature and opens new opportunities for exploring the electrochemical fluorination of many new materials
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Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO2
Resonant inelastic X-ray scattering (RIXS) at the O K-edge is considered a prime technique to identify bulk oxidized oxygen formation, but its fundamental interpretation is not straightforward. In this study, we intentionally induce RIXS signatures of oxidized oxygen upon beam exposure in LiAlO2 polymorphs that are easily distinguished because of their wide band gaps. After careful consideration of beam exposure effects on Li[Li0.144Ni0.136Mn0.544Co0.136]O2 (LR-NMC), we conclude that oxidized oxygen features are inherent at high states of charge and are lost upon aggressive beam exposure. The extracted oxidized oxygen line shapes from our X-ray irradiation studies for both LiAlO2 (induced) and LR-NMC (inherent) are found to have an additional oxidized oxygen RIXS feature not observed in O2 gas studies. This study highlights the unique insight of O K-edge RIXS into determining the nature and stability of oxidized oxygen states
Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage
Intercalation chemistry has dominated electrochemical energy storage for decades, and storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art intercalation cathodes for Li-ion batteries operate within the limits of transition metal cation electrochemistry, but the discovery of anion-redox processes in recent decades suggests rich opportunities for substantially increasing stored energy densities. The diversity of compounds that exhibit anion redox in the solid state has inspired the exploration of new materials for next-generation cathodes. In this Review, we outline the mechanisms proposed to contribute to anion redox and the accompanying kinetic pathways that can occur in layered transition metal oxides. We discuss the crucial role of structural changes at both the atomic and mesoscopic scales with an emphasis on their impact on electrochemical performance. We emphasize the need for an integrated approach to studying the evolution of both the bulk structure and electrode–electrolyte interphase by combining characterization with computation. Building on the fundamental understanding of electrochemical reaction mechanisms, we discuss engineering strategies such as composition design, surface protection and structural control to achieve stable anion redox for next-generation energy storage devices
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Revisiting the charge compensation mechanisms in LiNi0.8Co0.2-: YAlyO2 systems
Oxygen participation, arising from increased transition metal-oxygen covalency during delithiation, is considered essential for the description of charge compensation in conventional layered oxides. The advent of high-resolution mapping of the O K-edge resonant inelastic X-ray scattering (RIXS) provides an opportunity to revisit the onset and extent of oxygen participation. Combining RIXS with an array of structural and electronic probes for the family of Ni-rich LiNi0.8Co0.2-yAlyO2cathodes, we identify common charge compensation regimes that are assigned to formal transition metal redox (<4.25 V) and oxygen participation through covalency (>4.25 V). From O K-edge RIXS maps, we find the emergence of a sharp RIXS feature in these systems when approaching full delithiation, which has previously been associated with lattice oxidized oxygen in alkali-rich systems. The lack of transition metal redox signatures and strong covalency at these high degrees of delithiation suggest this RIXS feature is similarly attributed to lattice oxygen charge compensation as in the alkali-rich systems. The RIXS feature's evolution with state of charge in conventional layered oxides is evidence that this feature reflects the depopulation of occupied O 2p states associated with oxygen participation