A Search for Fluctuation-Dissipation Theorem Violations in Spin-Glasses from Susceptibility Data

We propose an indirect way of studying the fluctuation-dissipation relation in spin-glasses that only uses available susceptibility data. It is based on a dynamic extension of the Parisi-Toulouse approximation and a Curie-Weiss treatment of the average magnetic couplings. We present the results of the analysis of several sets of experimental data obtained from various samples.Comment: 7 pages, 4 figure

Reconstructing World Politics: Norms, Discourse, and Community

This Article argues that the conventional (rationalist) approach to world politics characterized by political bargain cannot fully capture the new social reality under the contemporary global ambience where ideational factors such as ideas, values, culture, and norms have become more salient and influential not only in explaining but also in prescribing state behaviors. After bringing rationalism’s paradigmatic limitations into relief, the Article offers a sociological framework that highlights a reflective, intersubjective communication among states and consequent norm-building process. Under this new paradigm, one can understand an international organization as a “community” (Gemeinschaft), not as a mere contractual instrument of its contracting parties (Gesellschaft). The Article applies the new paradigm to the World Trade Organization (WTO) as it describes the WTO’s institutional evolution from a power-oriented, tariff-reducing contract to a norm-oriented world trade community

Response properties in a model for granular matter

We investigate the response properties of granular media in the framework of the so-called {\em Random Tetris Model}. We monitor, for different driving procedures, several quantities: the evolution of the density and of the density profiles, the ageing properties through the two-times correlation functions and the two-times mean-square distance between the potential energies, the response function defined in terms of the difference in the potential energies of two replica driven in two slightly different ways. We focus in particular on the role played by the spatial inhomogeneities (structures) spontaneously emerging during the compaction process, the history of the sample and the driving procedure. It turns out that none of these ingredients can be neglected for the correct interpretation of the experimental or numerical data. We discuss the problem of the optimization of the compaction process and we comment on the validity of our results for the description of granular materials in a thermodynamic framework.Comment: 22 pages, 35 eps files (21 figures

Real-time electron nanoscopy of photovoltaic absorber formation from kesterite nanoparticles

Cu2ZnSnS4 nanocrystals are annealed in a Se-rich atmosphere inside a transmission electron microscope. During the heating phase, a complete S-Se exchange reaction occurs while the cation sublattice and morphology of the nanocrystals are preserved. At the annealing temperature, growth of large Cu2ZnSnSe4 grains with increased cation ordering is observed in real-time. Thisyields an annealing protocol which is transferred to an industrially-similar solar cell fabrication process resulting in a 33% increase in the device open circuit voltage. The approach can be applied to improve the performance of any photovoltaic technology that requires annealing because of the criticality of the process step

Understanding the role of crystallographic shear on the electrochemical behavior of niobium oxyfluorides

The effects of shear planes in perovskite materials have been studied in order to identify their role in the electrochemical behavior of Li⁺ intercalation hosts. These planes modulate the structural stability and ionic transport pathways and therefore play an intimate role in the characteristics and performance of shear compounds. Herein, two Nb-based compounds, NbO₂F and Nb₃O₇F, were chosen as representative perovskite and shear derivatives respectively to investigate the role of crystallographic shear. A series of operando measurements, including X-ray diffraction and X-ray absorption spectroscopy, in conjunction with structural analysis, Raman spectroscopy, and detailed electrochemical studies identified the effect of shear planes. It was found that shear planes led to increased structural stability during Li⁺ (de)intercalation with shear layers being maintained, while perovskite layers were seen to degrade rapidly. However, disordering in the shear plane stacking introduced during delithiation ultimately led to poor capacity retention despite structural maintenance as Li⁺ diffusion channels are disrupted