Energy transfer in finite-size exciton-phonon systems : confinement-enhanced quantum decoherence

Based on the operatorial formulation of the perturbation theory, the exciton-phonon problem is revisited for investigating exciton-mediated energy flow in a finite-size lattice. Within this method, the exciton-phonon entanglement is taken into account through a dual dressing mechanism so that exciton and phonons are treated on an equal footing. In a marked contrast with what happens in an infinite lattice, it is shown that the dynamics of the exciton density is governed by several time scales. The density evolves coherently in the short-time limit whereas a relaxation mechanism occurs over intermediated time scales. Consequently, in the long-time limit, the density converges toward a nearly uniform distributed equilibrium distribution. Such a behavior results from quantum decoherence that originates in the fact that the phonons evolve differently depending on the path followed by the exciton to tunnel along the lattice. Although the relaxation rate increases with the temperature and with the coupling, it decreases with the lattice size, suggesting that the decoherence is inherent to the confinement

Thermal Casimir drag in fluctuating classical fields

A uniformly moving inclusion which locally suppresses the fluctuations of a classical thermally excited field is shown to experience a drag force which depends on the dynamics of the field. It is shown that in a number of cases the linear friction coefficient is dominated by short distance fluctuations and takes a very simple form. Examples where this drag can occur are for stiff objects, such as proteins, nonspecifically bound to more flexible ones such as polymers and membranes.Comment: 4 pages RevTex, 2 figure

Aging phenomena in spin glass and ferromagnetic phases: domain growth and wall dynamics

We compare aging in a disordered ferromagnet and in a spin glass, by studying the different phases of a reentrant system. We have measured the relaxation of the low-frequency ac susceptibility, in both the ferromagnetic and spin-glass phases of a CdCr_{1.9}In_{0.1}S_4 sample. A restart of aging processes when the temperature is lowered (`chaos-like' effect) is observed in both phases. The memory of previous aging at a higher temperature can be retrieved upon re-heating, but in the ferromagnetic phase it can rapidly be erased by the growth of ferromagnetic domains. We interpret the behaviour observed in the ferromagnetic phase in terms of a combination of domain growth and pinned wall reconformations, and suggest that aging in spin glasses is dominated by such wall reconformation processes.Comment: SPEC, CEA Saclay, 91191 Gif sur Yvette Cedex, France, to appear in Europhys. Lett. (2000

Composition and concentration anomalies for structure and dynamics of Gaussian-core mixtures

We report molecular dynamics simulation results for two-component fluid mixtures of Gaussian-core particles, focusing on how tracer diffusivities and static pair correlations depend on temperature, particle concentration, and composition. At low particle concentrations, these systems behave like simple atomic mixtures. However, for intermediate concentrations, the single-particle dynamics of the two species largely decouple, giving rise to the following anomalous trends. Increasing either the concentration of the fluid (at fixed composition) or the mole fraction of the larger particles (at fixed particle concentration) enhances the tracer diffusivity of the larger particles, but decreases that of the smaller particles. In fact, at sufficiently high particle concentrations, the larger particles exhibit higher mobility than the smaller particles. Each of these dynamic behaviors is accompanied by a corresponding structural trend that characterizes how either concentration or composition affects the strength of the static pair correlations. Specifically, the dynamic trends observed here are consistent with a single empirical scaling law that relates an appropriately normalized tracer diffusivity to its pair-correlation contribution to the excess entropy.Comment: 5 pages, 4 figure

Impact of surface roughness on diffusion of confined fluids

Using event-driven molecular dynamics simulations, we quantify how the self diffusivity of confined hard-sphere fluids depends on the nature of the confining boundaries. We explore systems with featureless confining boundaries that treat particle-boundary collisions in different ways and also various types of physically (i.e., geometrically) rough boundaries. We show that, for moderately dense fluids, the ratio of the self diffusivity of a rough wall system to that of an appropriate smooth-wall reference system is a linear function of the reciprocal wall separation, with the slope depending on the nature of the roughness. We also discuss some simple practical ways to use this information to predict confined hard-sphere fluid behavior in different rough-wall systems

Structural precursor to the metal-insulator transition in V_2O_3

The temperature dependence of the local structure of V_2O_3 in the vicinity of the metal to insulator transition (MIT) has been investigated using hard X-ray absorption spectroscopy. It is shown that the vanadium pair distance along the hexagonal c-axis changes abruptly at the MIT as expected. However, a continuous increase of the tilt of these pairs sets in already at higher temperatures and reaches its maximum value at the onset of the electronic and magnetic transition. These findings confirm recent theoretical results which claim that electron-lattice coupling is important for the MIT in V_2O_3. Our results suggest that interactions in the basal plane play a decisive role for the MIT and orbital degrees of freedom drive the MIT via changes in hybridization.Comment: 6 pages, 5 figures, 2 table