Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles

© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k

Geometry, stochastic calculus and quantum fields in a non-commutative space-time

The algebras of non-relativistic and of classical mechanics are unstable algebraic structures. Their deformation towards stable structures leads, respectively, to relativity and to quantum mechanics. Likewise, the combined relativistic quantum mechanics algebra is also unstable. Its stabilization requires the non-commutativity of the space-time coordinates and the existence of a fundamental length constant. The new relativistic quantum mechanics algebra has important consequences on the geometry of space-time, on quantum stochastic calculus and on the construction of quantum fields. Some of these effects are studied in this paper.Comment: 36 pages Latex, 1 eps figur

Soft singularity and the fundamental length

It is shown that some regular solutions in 5D Kaluza-Klein gravity may have interesting properties if one from the parameters is in the Planck region. In this case the Kretschman metric invariant runs up to a maximal reachable value in nature, i.e. practically the metric becomes singular. This observation allows us to suppose that in this situation the problems with such soft singularity will be much easier resolved in the future quantum gravity then by the situation with the ordinary hard singularity (Reissner-Nordstr\"om singularity, for example). It is supposed that the analogous consideration can be applied for the avoiding the hard singularities connected with the gauge charges.Comment: 5 page

Efeito de alguns aditivos sobre a qualidade e valor nutritivo da silagem de capim-elefante.

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Perspectives on Quantum Gravity Phenomenology

The idea that quantum gravity manifestations would be associated with a violation of Lorentz invariance is very strongly bounded and faces serious theoretical challenges. Other related ideas seem to be drowning in interpretational quagmires. This leads us to consider alternative lines of thought for such phenomenological search. We discuss the underlying viewpoints and briefly mention their possible connections with other current theoretical ideas.Comment: Latex, 23 page

Experimental polarization encoded quantum key distribution over optical fibres with real-time continuous birefringence compensation

In this paper we demonstrate an active polarization drift compensation scheme for optical fibres employed in a quantum key distribution experiment with polarization encoded qubits. The quantum signals are wavelength multiplexed in one fibre along with two classical optical side channels that provide the control information for the polarization compensation scheme. This set-up allows us to continuously track any polarization change without the need to interrupt the key exchange. The results obtained show that fast polarization rotations of the order of 40*pi rad/s are effectively compensated for. We demonstrate that our set-up allows continuous quantum key distribution even in a fibre stressed by random polarization fluctuations. Our results pave the way for Bell-state measurements using only linear optics with parties separated by long-distance optical fibres

Stratification of the orbit space in gauge theories. The role of nongeneric strata

Gauge theory is a theory with constraints and, for that reason, the space of physical states is not a manifold but a stratified space (orbifold) with singularities. The classification of strata for smooth (and generalized) connections is reviewed as well as the formulation of the physical space as the zero set of a momentum map. Several important features of nongeneric strata are discussed and new results are presented suggesting an important role for these strata as concentrators of the measure in ground state functionals and as a source of multiple structures in low-lying excitations.Comment: 22 pages Latex, 1 figur

Calagem e adubação para pastagens na região do cerrado.

Calagem e adubação para o estabelecimento. Exigência de fertilidade do solo das principais gramíneas e leguminosas forrageiras. Calagem. Adubação. Calagem e Adubação para manutenção. Considerados finais.bitstream/item/72180/1/cirtec-37.pdf2. ed. rev.CNPGC

On the regular-geometric-figure solution to the N-body problem

The regular-geometric-figure solution to the $N$-body problem is presented in a very simple way. The Newtonian formalism is used without resorting to a more involved rotating coordinate system. Those configurations occur for other kinds of interactions beyond the gravitational ones for some special values of the parameters of the forces. For the harmonic oscillator, in particular, it is shown that the $N$-body problem is reduced to $N$ one-body problems.Comment: To appear in Eur. J. Phys. (5 pages

Avaliação de forrageiras tropicais submetidas à irrigação e doses de nitrogênio e potássio, em condições de Cerrado.

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