FTIR characterization ans chemo-mechanical distinction of reted kenaf fibres

Inadequate information on the binding characteristics of kenaf biomass at the molecular level has adversely affected the modifications of its cellulose-hemicellulose-lignin structure. This study was undertaken to assess the characteristic features and chemo-mechanical properties of kenaf fibres retted under three different media namely: tank, stream and ribbon. Fourier transform infra-red (FTIR) spectra analysis as well as the ASTM standard for tensile tests were applied. The results showed that the broad bands occurred at the range of 3312- 3420 cm−1 for all the retted fibres were due to the presence of hydroxyl (–OH) group while the peaks were obtained at 1635.76, 1635.34, and 1730.69 cm−1 for stream, tank and ribbon retted fibres respectively. However, tank retted fibres had the most broad band intensity at 3419.78cm-1 while ribbon fibres had the highest absorption peak of 1730.69cm-1 corresponding to C=O stretching of the acetyl group in hemi-cellulose. Stream retted Kenaf fibres had the highest tensile strength followed by the tank retted fibres while ribbon fibres had the least. Furthermore, there was no significant difference between stream and tank retted Kenaf fibres in terms of tensile modulus and this was significantly higher than that of ribbon fibre. The α-cellulose content of stream retted fibres was slightly higher than that of ribbon fibres while tank retted fibres had the least. From the results, tank retted Kenaf fibre was ranked as ‘the best fibre’ with the most intensive broad bands and least in lignin and hemi-cellulose content which were regarded as the impurities, gummy and waxy materials, responsible for an easy deformation of the fibre cellular  networks

Physicochemical comsposition of Kenaf (Hibiscus cannabinus L.) seed under different storage temperature

Kenaf is an annual plant grown for its fibre which basically depend on the seed viability, for its maximum growth and production. The seed viability and vigor in turn depend on storage condition. There is insufficient information on physicochemical composition of kenaf seed in relation to seed viability. The present study was performed to know the physicochemical composition of the kenaf seed at different storage temperature in other to improve upon rapid loss of seed viability in kenaf. Four varieties of kenaf seed were obtained from I.A.R. & T seed unit. The seeds were stored at 00C (Unviable seed), 2.20C (Lower temperature), 350C (Ambient temperature), 280C (Cold room temperature which serve as control) for period of 8 months. Seed germination test and weight was performed  before and after the experiment.  Proximate analysis (Crude protein, Moisture, Carbohydrate, Ash, Crude fibre, Crude fat) and Phytochemicals (Total phenolics, Steroid and Total Flavonoids were also determined). The result shows that there is significant difference in all the parameters studied, for all the storage temperatures as compared with the control (280C) among the varieties except from ifeken 100 where the was no significant difference in Crude fibre and Ash  content for seed under ambient temperature as compared with the control. However, the level of tolerance to different storage temperature among the varieties following the order Ifeken 400 >Tianung 2 > Cuba 108>Ifeken 100.Keywords: Kenaf, Storage, Seed germination, Seed weight, Temparature, Seed viability, Proximate, Flavonoid, Phenolics

FTIR characterization ans chemo-mechanical distinction of reted kenaf fibres

Inadequate information on the binding characteristics of kenaf biomass at the molecular level has adversely affected the modifications of its cellulose-hemicellulose-lignin structure. This study was undertaken to assess the characteristic features and chemo-mechanical properties of kenaf fibres retted under three different media namely: tank, stream and ribbon. Fourier transform infra-red (FTIR) spectra analysis as well as the ASTM standard for tensile tests were applied. The results showed that the broad bands occurred at the range of 3312- 3420 cm−1 for all the retted fibres were due to the presence of hydroxyl (–OH) group while the peaks were obtained at 1635.76, 1635.34, and 1730.69 cm−1 for stream, tank and ribbon retted fibres respectively. However, tank retted fibres had the most broad band intensity at 3419.78cm-1 while ribbon fibres had the highest absorption peak of 1730.69cm-1 corresponding to C=O stretching of the acetyl group in hemi-cellulose. Stream retted Kenaf fibres had the highest tensile strength followed by the tank retted fibres while ribbon fibres had the least. Furthermore, there was no significant difference between stream and tank retted Kenaf fibres in terms of tensile modulus and this was significantly higher than that of ribbon fibre. The α-cellulose content of stream retted fibres was slightly higher than that of ribbon fibres while tank retted fibres had the least. From the results, tank retted Kenaf fibre was ranked as ‘the best fibre’ with the most intensive broad bands and least in lignin and hemi-cellulose content which were regarded as the impurities, gummy and waxy materials, responsible for an easy deformation of the fibre cellular networks