Geotraceability and life cycle assessment in environmental life cycle management: towards sustainability.

Sustainability is an emerging concept in product chains and integrates environmental, social, and economic aspects during the product's life cycle. Recently, the demand for environmental quality has required information about the products' life cycle. Life Cycle Assessment (LCA) includes the inventory analysis, where the products´life cycle are systematized, and the Life Cycle Impact Assessment, when the environmental impacts potentials are calculated. A powerful tool to describe the history, use, and lication of a product in called geotraceability..

Internal structure of nanoparticles of Al generated by laser ablation in liquid ethanol

Al NPs are synthesized by laser ablation of a bulk Al target immersed into liquid ethanol saturated with hydrogen at atmospheric pressure. The nanoparticles possess a well-distinguished core-shell structure. High Resolution Transmission Electron Microscopy shows several layers inside the Al nanoparticle: oxide layer, amorphous Al, single crystal Al, and a cavity in the center. Formation of the cavity is attributed to the sharp increase of hydrogen dissolution in Al upon its melting and its eventual release after the solidification

La perspectiva filosófica de un concepto: una analogía de Bachelard

Es nuestra intención en este trabajo, construir las imágenes analógicas que implícitamente están bocetadas en "La filosofía del no" de Bachelard, tratando de mostrar a un Bachelard analógico al momento de exponer sus ideas, mostrándonos como la ciencia misma ha recurrido a imágenes que al destruirlas condujeron al pensamiento científico a descubrir sus leyes orgánicas. Así vemos como Bachelard si bien marca una ruptura entre las imágenes, metáforas y analogías de la experiencia cotidiana, nos muestra la necesidad de recurrir a ellas por parte de la ciencia, la cuál crea formas realistas y racionales de sus objetos que le otorgan una razón polémica. La historia de la imaginería científica conforma un plan estratégico pedagógico ineluctable para el crecimiento científico (Bachelard, 2003:115)

An implicit method for radiative transfer with the diffusion approximation in SPH

An implicit method for radiative transfer in SPH is described. The diffusion approximation is used, and the hydrodynamic calculations are performed by a fully three--dimensional SPH code. Instead of the energy equation of state for an ideal gas, various energy states and the dissociation of hydrogen molecules are considered in the energy calculation for a more realistic temperature and pressure determination. In order to test the implicit code, we have performed non--isothermal collapse simulations of a centrally condensed cloud, and have compared our results with those of finite difference calculations performed by MB93. The results produced by the two completely different numerical methods agree well with each other.Comment: 25 pages, 9 figure

Impact behavior of injected PP/nanoclay parts

This work attempts to contribute to bridge the gap between scientific challenges and industrial stakes regarding PP/nanoclay composites. Pieces of nanocomposites were obtained by direct injection of commercial PP mixed with a commercial MB of PP with 50% of organoclay, with a double-gated hot runner mould, which produced mouldings with a weld line. The moulding microstructure was assessed by POM and XRD, while the distribution and exfoliation grade of clay was evaluated by TEM and XRD. The typical skin-core structure was found, with a skin thickness wider in bulk than in weld line zones. Regarding clay platelets mostly intercalated structures were seen. The impact properties at room temperature were assessed by means of tensile and biaxial tests. Properties were monitored at different sites of the mouldings. At the weld line zone less energy was consumed under tensile conditions and exhibited higher apparent impact toughness under biaxial conditions than the bulk zone. Visual inspection of biaxially impacted samples showed that the orientation of polymer molecules and clay platelets induced by melt flow prevailed, and the weld line was not the determinant of the toughness of the mouldings. An optimum in impact performance was found for moulding with 3% of clay, since at larger clay contents platelets agglomerated and acted as stress raisers

Uni- and biaxial impact behavior of double-gated nanoclay-reinforced polypropylene injection moldings

Polypopylene/nanoclay three-dimensional parts were produced without intermediate steps by direct injection molding to explore the influence of flow features and nanoclay incorporation in their impact performance. The nanocomposite was obtained by direct compounding of commercial PP with nanoclay masterbatch. The as-molded morphology was analyzed by X-ray and TEM analyses in terms of skin-core structure and nanoclay particle dispersion. The nanoclay particles induced the reduction of b-form spherulites, a known toughener. The impact behavior was assessed in tensile and biaxial modes. The PP nanocomposite molding toughness was practically unaffected by the processing melt temperature and flow rate. Conversely the nanoclay presence is influent in the impact performance. Under biaxial stress impact, the regions close to weld lines are tougher than the bulk and the fracture develops with main crack paths along the flow direction and the weld line. Cracking along the weld line results from less macromolecular interpenetration and chain entanglement, and unfavorable nanoparticle orientation. It seems that a failure mechanism which involves nanoclay delamination and multiple matrix crazing explains the toughening of PP in the directions where the nanoparticle orientation with respect to loading is adequate.Contract grant sponsors: CONICET, ANPCyT from Argentina, MINCyT (Argentina) - FCT (Portugal), Universities Nacional de Mar del Plata and Minho

Tuning complex shapes in Pt(0) nanoparticles : from cubic dendrites to five-fold stars

A platinum star performance: Quasi-single-crystalline Pt nanoparticles with peculiar morphologies—cubic dendrites, planar tripods, and fivefold stars—were synthesized in high yield. Shape selectivity was achieved by finely tuning the growth kinetics under a dihydrogen atmosphere

Stat3 controls tubolointerstitial communication during CKD

Functional Genomics of Systemic Disorder