PROVENANCE AND AGE CONSTRAINTS OF THE RIPHEAN SANDSTONES FROM THE IVANOVSKY GRABEN (THE KOLA PENINSULA) BASED ON THE U-Pb LA-ICP-MS DATING AND RAMAN SPECTROSCOPY OF DETRITAL ZIRCON

The results of U-Pb LA-ICP-MS dating of 150 detrital zircon grains from the Precambrian (Riphean?) sandstones of the Kildin group on the coast of the Ivanovka Bay (northeastern Kola Peninsula) are presented. A group of three youngest grains yielded constraint on the sandstone maximum depositional age of 1179±45 Ma. Detrital zircon age distribution is dominated by three maximums of 1.9, 2.4 and 2.7 Ga. The authors consider two complementary scenarios of interpretation of the data obtained. The first scenario involves the contribution of distant provenance out of granitoids in the Lapland-Kola orogen (~1.9 Ga) and adjacent areas of the Kola-Karelia region (~2.7 Ga), Imandra-Varzuga structure (~2.4 Ga), and Sveconorwegian belt (~1.2 Ga); the off-Baltic (Greenland?) sources of the detrital zircon also cannot be excluded. According to the second scenario, the Ivanovsky graben received zircons also from the proximal sources – sialic complexes formed upon melting of granite-gneiss substratum of the upper crust of the Murmansk craton during largescale episodic mafic magmatism 1.86, 2.50 and 2.68 Ga. The Raman spectroscopy showed that about 25 % of the analyzed detrital zircon grains experienced a 1.4-Ga-old thermal effect which did not lead to Pb losses but partially restored the crystalline structure of zircon. This result can be used as an additional constraint in the detailed provenance analysis of the northeastern East European Platform sedimentary basins and is indicative of 1.4-Ga-old large-scale magmatic events related to the breakup of the supercontinent Nuna

Inclination shallowing in the Permian/Triassic boundary sedimentary sections of the Middle Volga region in light of the new paleomagnetic data

© 2017, Pleiades Publishing, Ltd. One of the key challenges which are traditionally encountered in studying the paleomagnetism of terrigenous sedimentary strata is the necessity to allow for the effect of shallowing of paleomagnetic inclinations which takes place under the compaction of the sediment at the early stages of diagenesis and most clearly manifests itself in the case of midlatitude sedimentation. Traditionally, estimating the coefficient of inclination flattening (f) implies routine re-deposition experiments and studying their magnetic anisotropy (Kodama, 2012), which is not possible in every standard paleomagnetic laboratory. The Elongation–Inclination (E–I) statistical method for estimating the coefficient of inclination shallowing, which was recently suggested in (Tauxe and Kent, 2004), does not require the investigation of the rock material in a specially equipped laboratory but toughens the requirements on the paleomagnetic data and, primarily, regarding the volume of the data, which significantly restricts the possibilities of the post factum estimation and correction for inclination shallowing. In this work, we present the results of the paleomagnetic reinvestigation of the Puchezh and Zhukov ravine (ravine) reference sections of the Upper Permian and Lower Triassic rocks in the Middle Volga region. The obtained paleomagnetic data allowed us to estimate the coefficient of inclination shallowing f by the E–I method: for both sections, it is f = 0.9. This method was also used by us for the paleomagnetic data that were previously obtained for the Permian–Triassic rocks of the Monastyrskii ravine (Monastirskoje) section (Gialanella et al., 1997), where the inclination shallowing coefficient was estimated at f = 0.6

Origin of false components of NRM during conventional stepwise thermal demagnetization

© 2017 Many Permian-Triassic dolerite samples from the Siberian Trap Large Igneous Province exposed to conventional stepwise thermal demagnetization at 250-450 °C display mid-temperature remanence (MTC) directed opposite to the high-temperature NRM component. Alternating field (A.C.) demagnetization fails to isolate the antipodal component, but it appears during continuous thermal demagnetization, though in a different temperature range. Laboratory experiments and simulations prove that MTC remanence is an artifact resulting from magnetic memory of self-reversing titanomagnetite grains oxidized at low temperature. This effect can deform the results stepwise thermal cleaning and be responsible for misleading patterns of paleomagnetic directions. Given that oxidized titanomagnetite grains are widespread in volcanic rocks, we suggest to identify true paleodirections by combined continuous and stepwise thermal demagnetization. The extension of our model to the case of NRM2 overprint directed at some angle to partially reversed primary NRM1 component accounts for the difference between the results of stepwise and continuous thermal demagnetization observed in samples of the Steens Mountain basalt (USA)

GEOMAGNETIC EXCURSION RECORD PRESERVED IN THE SPELEOTHEM FROM WESTERN CAUCASUS: FIRST DATA

The study of the geomagnetic field evolution on minor timescales, in particular of such significant events as geomagnetic reversals and excursions, has acquired particular relevance nowadays due to the increased attention of mankind to the environment. The question of how exactly abrupt changes in the characteristics of the geomagnetic field affect the climate and biosphere remains largely debatable; the idea of the speed and dynamics of these changes is also very vague. "Classical" geological objects and existing methods provide limited opportunities for highly detailed reconstructions of geomagnetic field variations; therefore, paleomagnetologists are looking for new objects and approaches to solve this problem. The research that we have begun involves the use – for the first time in Russia – of speleothems to study secular variations of the geomagnetic field.This brief communication presents paleomagnetic records of two drill-cores from the flowstone from Vorontsovskaya cave, located on the western flank of the Caucasus Mountains in the valley of the river Kudepsta. Preliminary results indicate the presence of a geomagnetic excursion record in both drill-cores. Further study of the samples from Vorontsovskaya cave will make it possible to compare the discovered event with known excursions, as well as to clarify its age, duration, and dynamics

Magnetic stratigraphy of the Ordovician in the lower reach of the Kotuy River: the age of the Bysy-Yuryakh stratum and the rate of geomagnetic reversals on the eve of the superchron

© 2017, Pleiades Publishing, Ltd. Until recently, the existing data prevented the geophysicists from accurately dating the Bysy-Yuryakh stratum, which outcrops in the middle reach of the Kotuy River, constraining the time of its formation to a wide interval from the end of the Late Cambrian to the beginning of the Silurian. The obtained paleomagnetic data unambiguously correlate the Bysy-Yuryakh stratum to the Nyaian regional stage and constrain its formation, at least a considerable part of it, by the Tremadocian. This result perfectly agrees with the data on the Bysy-Yuryakh conodonts studied in this work and yields a spectacular example of the successful application of paleomagnetic studies in solving important tasks of stratigraphy and, correspondingly, petroleum geology. Within the Bysy-Yuryakh stratum, we revealed a large normal-polarity interval corresponding to the long ( > 1 Ma) period when the geomagnetic reversals were absent. This result, in combination with the data for the Tremadocian and Middle–Upper Cambrian sequences of the other regions, indicates that (1) the rate of occurrence of the geomagnetic reversals on the eve of the Ordovician Moyero superchron of reversed polarity was at most one reversal per Ma; (2) the superchron does not switch on instantaneously but is preceded by a certain gradual change in the operation conditions of the dynamo mechanism which, inter alia, manifests itself by the reduction of the frequency of geomagnetic reversals with the approach of the superchron. This finding supports the views according to which a process preparing the establishment of the superchrons takes place at the core–mantle boundary

Magnetic stratigraphy of the Ordovician in the lower reach of the Kotuy River: the age of the Bysy-Yuryakh stratum and the rate of geomagnetic reversals on the eve of the superchron

© 2017, Pleiades Publishing, Ltd. Until recently, the existing data prevented the geophysicists from accurately dating the Bysy-Yuryakh stratum, which outcrops in the middle reach of the Kotuy River, constraining the time of its formation to a wide interval from the end of the Late Cambrian to the beginning of the Silurian. The obtained paleomagnetic data unambiguously correlate the Bysy-Yuryakh stratum to the Nyaian regional stage and constrain its formation, at least a considerable part of it, by the Tremadocian. This result perfectly agrees with the data on the Bysy-Yuryakh conodonts studied in this work and yields a spectacular example of the successful application of paleomagnetic studies in solving important tasks of stratigraphy and, correspondingly, petroleum geology. Within the Bysy-Yuryakh stratum, we revealed a large normal-polarity interval corresponding to the long ( > 1 Ma) period when the geomagnetic reversals were absent. This result, in combination with the data for the Tremadocian and Middle–Upper Cambrian sequences of the other regions, indicates that (1) the rate of occurrence of the geomagnetic reversals on the eve of the Ordovician Moyero superchron of reversed polarity was at most one reversal per Ma; (2) the superchron does not switch on instantaneously but is preceded by a certain gradual change in the operation conditions of the dynamo mechanism which, inter alia, manifests itself by the reduction of the frequency of geomagnetic reversals with the approach of the superchron. This finding supports the views according to which a process preparing the establishment of the superchrons takes place at the core–mantle boundary

Controlled oxidation of cobalt nanoparticles to obtain Co/CoO/Co3O4 composites with different Co content

The paper studies patterns of interaction of electroexplosive Co nanoparticles with air oxygen during heating. The characteristics of Co nanoparticles and composite Co/CoO/Co3O4 nanoparticles formed as a result of oxidation were studied using transmission electron microscopy, X-ray phase analysis, thermogravimetric analysis, differential scanning calorimetry, and vibrating sample magnetometry. It was established that nanoparticles with similar morphology in the form of hollow spheres with different content of Co, CoO, and Co3O4 can be produced by varying oxidation temperatures. The influence of the composition of composite nanoparticles on their magnetic characteristics is shown

U-Pb LA-ICP-MS DATING OF DETRITAL ZIRCON FROM UPPER PERMIAN SANDSTONE OF THE BOYEVAYA GORA SECTION (ORENBURG REGION, SOUTHERN CIS-URALS)

The first results of U-Pb LA-ICP-MS dating of 150 detrital zircon grains from the Upper Permian sandstone of the Boyevaya Gora section (Orenburg region, the Southern Cis-Urals) are presented. 95 conditional zircon U-Pb isotopic dates form two age peaks – 381 and 529 Ma. It is assumed that clastic material entered the sedimentation basin mainly due to erosion of the Early Hercynian Ural complexes and relics of the Protouralian-Timanian orogen

ИСТОЧНИКИ СНОСА И ОГРАНИЧЕНИЕ ВОЗРАСТА РИФЕЙСКИХ ПЕСЧАНИКОВ ИВАНОВСКОГО ГРАБЕНА КОЛЬСКОГО ПОЛУОСТРОВА ПО РЕЗУЛЬТАТАМ U-Pb LA-ICP-MS ДАТИРОВАНИЯ И РАМАНОВСКОЙ СПЕКТРОСКОПИИ ОБЛОМОЧНОГО ЦИРКОНА

The results of U-Pb LA-ICP-MS dating of 150 detrital zircon grains from the Precambrian (Riphean?) sandstones of the Kildin group on the coast of the Ivanovka Bay (northeastern Kola Peninsula) are presented. A group of three youngest grains yielded constraint on the sandstone maximum depositional age of 1179±45 Ma. Detrital zircon age distribution is dominated by three maximums of 1.9, 2.4 and 2.7 Ga. The authors consider two complementary scenarios of interpretation of the data obtained. The first scenario involves the contribution of distant provenance out of granitoids in the Lapland-Kola orogen (~1.9 Ga) and adjacent areas of the Kola-Karelia region (~2.7 Ga), Imandra-Varzuga structure (~2.4 Ga), and Sveconorwegian belt (~1.2 Ga); the off-Baltic (Greenland?) sources of the detrital zircon also cannot be excluded. According to the second scenario, the Ivanovsky graben received zircons also from the proximal sources – sialic complexes formed upon melting of granite-gneiss substratum of the upper crust of the Murmansk craton during largescale episodic mafic magmatism 1.86, 2.50 and 2.68 Ga. The Raman spectroscopy showed that about 25 % of the analyzed detrital zircon grains experienced a 1.4-Ga-old thermal effect which did not lead to Pb losses but partially restored the crystalline structure of zircon. This result can be used as an additional constraint in the detailed provenance analysis of the northeastern East European Platform sedimentary basins and is indicative of 1.4-Ga-old large-scale magmatic events related to the breakup of the supercontinent Nuna.Приводятся первые результаты U-Pb LA-ICP-MS изотопного датирования 150 зерен обломочного циркона из докембрийских (рифейских?) песчаников кильдинской серии губы Ивановской северо-востока Кольского полуострова. По группе из трех самых молодых зерен получено нижнее ограничение на время накопления песчаников – 1179±45 млн лет. В распределении возрастов зерен циркона доминируют три максимума – 1.9, 2.4 и 2.7 млрд лет. Авторы рассматривают два взаимодополняющих варианта интерпретации полученных данных. Первый вариант предполагает вклад удаленных источников сноса – гранитоидов Лапландско-Кольского орогена (~1.9 млрд лет) и сопряженных с ними областей Карельско-Кольского региона (~2.7 млрд лет), Имандра-Варзугской структуры (~2.4 млрд лет), Свеконорвежского пояса (~1.2 млрд лет); вероятны также и внебалтийские (гренландские?) источники. Согласно второму варианту, в Ивановский грабен циркон поступал, в том числе, из проксимальных источников – сиалических комплексов, сформированных при плавлении гранитогнейсов верхней коры Мурманского кратона в ходе эпизодов масштабного базитового магматизма 1.86, 2.50 и 2.68 млрд лет назад. Методом рамановской спектроскопии показано, что примерно 25 % проанализированных зерен обломочного циркона около 1.4 млрд лет назад испытали воздействие термального события, не приведшего к потерям Pb, но частично восстановившего кристаллическую структуру циркона. Этот результат может использоваться как дополнительное ограничение при проведении детального анализа питающих провинций осадочных бассейнов северо-восточной части Восточно-Европейской платформы и указывает на масштабность проявления магматических событий около 1.4 млрд лет назад, связанных с распадом суперконтинента Нуна