344 research outputs found
Effect of pressure on the Raman modes of antimony
The effect of pressure on the zone-center optical phonon modes of antimony in
the A7 structure has been investigated by Raman spectroscopy. The A_g and E_g
frequencies exhibit a pronounced softening with increasing pressure, the effect
being related to a gradual suppression of the Peierls-like distortion of the A7
phase relative to a cubic primitive lattice. Also, both Raman modes broaden
significantly under pressure. Spectra taken at low temperature indicate that
the broadening is at least partly caused by phonon-phonon interactions. We also
report results of ab initio frozen-phonon calculations of the A_g and E_g mode
frequencies. Presence of strong anharmonicity is clearly apparent in calculated
total energy versus atom displacement relations. Pronounced nonlinearities in
the force versus displacement relations are observed. Structural instabilities
of the Sb-A7 phase are briefly addressed in the Appendix.Comment: 10 pages, 8 figure
C,N-chelated diaminocarbene platinum(II) complexes derived from 3,4-diaryl-1H-pyrrol-2,5-diimines and cis-dichlorobis(isonitrile)platinum(II):Synthesis, cytotoxicity, and catalytic activity in hydrosilylation reactions
The reaction of 3,4-diaryl-1H-pyrrol-2,5-diimines with cis-dichlorobis(isonitrile)platinum(II) affords the C,N-chelated diaminocarbene platinum(II) complexes, which have been fully characterized including molecular spectroscopy, single crystal X-ray diffraction and DFT calculations. The obtained platinum(II) complexes are effective catalysts for the hydrosilylation of alkynes and alkenes. Thus, the reaction of phenylacetylene with triethoxysilane leads to the formation of α- and β-(E)-vinylsilanes, generating TON's in the range of 103 to 104 and TOF's in the range of 102 to 103 h−1. Also, the cross-linked silicones, possessing the luminescence properties, were obtained by the hydrosilylation reaction of vinyl- and hydride-containing polysiloxanes. Additionally, the efficiency of diaminocarbene platinum(II) complexes against CH1/PA-1, SW480, and A549 cancer cell lines has been demonstrated by in vitro cytotoxicity studies.peerReviewe
scattering S wave from the data on the reaction
The results of the recent experiments on the reaction
performed at KEK, BNL, IHEP, and CERN are analyzed in detail. For the I=0
S wave phase shift and inelasticity a new set
of data is obtained. Difficulties emerging when using the physical solutions
for the S and D wave amplitudes extracted with the partial wave
analyses are discussed. Attention is drawn to the fact that, for the
invariant mass, m, above 1 GeV, the other solutions, in principle,
are found to be more preferred. For clarifying the situation and further
studying the resonance thorough experimental investigations of the
reaction in the m region near the threshold
are required.Comment: 17 pages, 5 figure
High pressure transport properties of the topological insulator Bi2Se3
We report x-ray diffraction, electrical resistivity, and magnetoresistance
measurements on Bi2Se3 under high pressure and low temperature conditions.
Pressure induces profound changes in both the room temperature value of the
electrical resistivity as well as the temperature dependence of the
resistivity. Initially, pressure drives Bi2Se3 towards increasingly insulating
behavior and then, at higher pressures, the sample appears to enter a fully
metallic state coincident with a change in the crystal structure. Within the
low pressure phase, Bi2Se3 exhibits an unusual field dependence of the
transverse magnetoresistance that is positive at low fields and becomes
negative at higher fields. Our results demonstrate that pressures below 8 GPa
provide a non-chemical means to controllably reduce the bulk conductivity of
Bi2Se3
Effective State Metamorphosis in Semi-Classical Loop Quantum Cosmology
Modification to the behavior of geometrical density at short scales is a key
result of loop quantum cosmology, responsible for an interesting phenomenology
in the very early universe. We demonstrate the way matter with arbitrary scale
factor dependence in Hamiltonian incorporates this change in its effective
dynamics in the loop modified phase. For generic matter, the equation of state
starts varying near a critical scale factor, becomes negative below it and
violates strong energy condition. This opens a new avenue to generalize various
phenomenological applications in loop quantum cosmology. We show that different
ways to define energy density may yield radically different results, especially
for the case corresponding to classical dust. We also discuss implications for
frequency dispersion induced by modification to geometric density at small
scales.Comment: Revised version; includes expanded discussion of natural
trans-Planckian modifications to frequency dispersion and robustness to
quantization ambiguities. To appear in Class. Quant. Gra
Mathematical Modeling of a Solar Arrays Deploying Process at Ground Tests
This paper focuses on the creating of a mathematical model of a solar array deploying process during ground tests. Lagrange equation was used to obtain the math model. The distinctive feature of this mathematical model is the possibility of taking into account the gravity compensation system influence on the construction in the deploying process and the aerodynamic resistance during ground tests
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