574 research outputs found
Simulation study of pressure and temperature dependence of the negative thermal expansion in Zn(CN)(2)
12 pages, 16 figures12 pages, 16 figures12 pages, 16 figures12 pages, 16 figure
Conformations in crystals and solutions of d(CACGTG), d(CCGCGG) and d(GGCGCC) studied by vibrational spectroscopy
Crystals of self camplementary DMA hexamers dCCACGTG>, dCCCGCGG> and d were grown bf vapour dlffuslon technlque and studled by mlcroRaman and mlcroiR spectroscop es. The ollgonucleotldes were studled ln parallel ln solutlon by vlbratlonal spectroscopy. A B->Z transltlon was detected by Raman spectroscopy cl.lrlng the crystalllzatlon procese for dCCACGTG>. Vlbratlonal spectroscopy shows that the dCGGCGCC> crystals adopt a B geametry. On the contrary the d sequence whlch ls shown to be able to undergo ln solutlon or ln fllms qulte easlly the B->Z transltlon, remalns trapped ln crystals ln a geametry whlch may correspond to an lntermedlate conformatlon often proposed ln modele of the B->Z transltlon. The crystals used ln thls study were characterlzed by X-ray dlffractlon. The unlt cell and space group have been determlned
Weak ferromagnetism with very large canting in a chiral lattice: (pyrimidine)2FeCl2
The transition metal coordination compound (pyrimidine)2FeCl2 crystallizes in
a chiral lattice, space group I 4_1 2 2 (or I4_3 2 2). Combined magnetization,
Mossbauer spectroscopy and powder neutron diffraction studies reveal that it is
a canted antiferromagnet below T_N = 6.4 K with an unusually large canting of
the magnetic moments of 14 deg. from their general antiferromagnetic alignment,
one of the largest reported to date. This results in weak ferromagnetism with a
ferromagnetic component of 1 mu_B. The large canting is due to the interplay
between the antiferromagnetic exchange interaction and the local single-ion
anisotropy in the chiral lattice. The magnetically ordered structure of
(pyrimidine)2FeCl2, however, is not chiral. The implications of these findings
for the search of molecule based materials exhibiting chiral magnetic ordering
is discussed.Comment: 6 pages, 5 figure
Novel mechanism of photoinduced reversible phase transitions in molecule-based magnets
A novel microscopic mechanism of bi-directional structural changes is
proposed for the photo-induced magnetic phase transition in Co-Fe Prussian blue
analogues on the basis of ab initio quantum chemical cluster calculations. It
is shown that the local potential energies of various spin states of Co are
sensitive to the number of nearest neighbor Fe vacancies. As a result, the
forward and backward structural changes are most readily initiated by
excitation of different local regions by different photons. This mechanism
suggests an effective strategy to realize photoinduced reversible phase
transitions in a general system consisting of two local components.Comment: 4 pages, LaTex, 3 figures, to appear in Phys. Rev. Let
Backreaction from non-conformal quantum fields in de Sitter spacetime
We study the backreaction on the mean field geometry due to a non-conformal
quantum field in a Robertson-Walker background. In the regime of small mass and
small deviation from conformal coupling, we compute perturbatively the
expectation value of the stress tensor of the field for a variety of vacuum
states, and use it to obtain explicitly the semiclassical gravity solutions for
isotropic perturbations around de Sitter spacetime, which is found to be
stable. Our results show clearly the crucial role of the non-local terms that
appear in the effective action: they cancel the contribution from local terms
proportional to the logarithm of the scale factor which would otherwise become
dominant at late times and prevent the existence of a stable self-consistent de
Sitter solution. Finally, the opposite regime of a strongly non-conformal field
with a large mass is also considered.Comment: 31 page
Tuning the magnetic ground state of a novel tetranuclear Nickel(II) molecular complex by high magnetic fields
Electron spin resonance and magnetization data in magnetic fields up to 55 T
of a novel multicenter paramagnetic molecular complex [L_2Ni_4(N_3)(O_2C
Ada)_4](Cl O_4) are reported. In this compound, four Ni centers each having a
spin S = 1 are coupled in a single molecule via bridging ligands (including a
\mu_4-azide) which provide paths for magnetic exchange. Analysis of the
frequency and temperature dependence of the ESR signals yields the relevant
parameters of the spin Hamiltonian, in particular the single ion anisotropy gap
and the g factor, which enables the calculation of the complex energy spectrum
of the spin states in a magnetic field. The experimental results give
compelling evidence for tuning the ground state of the molecule by magnetic
field from a nonmagnetic state at small fields to a magnetic one in strong
fields owing to the spin level crossing at a field of ~25 T.Comment: revised version, accepted for publication in Physical Review
Exact non-singular waves in the anti-de Sitter universe
A class of radiative solutions of Einstein's field equations with a negative
cosmological constant and a pure radiation is investigated. The space-times,
which generalize the Defrise solution, represent exact gravitational waves
which interact with null matter and propagate in the anti-de Sitter universe.
Interestingly, these solutions have homogeneous and non-singular wave-fronts
for all freely moving observers. We also study properties of sandwich and
impulsive waves which can be constructed in this class of space-times.Comment: 15 pages, 3 figures, To appear in Gen. Rel. Gra
General-relativistic Model of Magnetically Driven Jet
The general scheme for the construction of the general-relativistic model of
the magnetically driven jet is suggested. The method is based on the usage of
the 3+1 MHD formalism. It is shown that the critical points of the flow and the
explicit radial behavior of the physical variables may be derived through the
jet ``profile function."Comment: 12 pages, LaTex, no figure
Low-Temperature Properties of Quasi-One-Dimensional Molecule-Based Ferromagnets
Quantum and thermal behaviors of low-dimensional mixed-spin systems are
investigated with particular emphasis on the design of molecule-based
ferromagnets. One can obtain a molecular ferromagnet by assembling molecular
bricks so as to construct a low-dimensional system with a magnetic ground state
and then coupling the chains or the layers again in a ferromagnetic fashion.
Two of thus-constructed quasi-one-dimensional bimetallic compounds are
qualitatively viewed within the spin-wave treatment, one of which successfully
grows into a bulk magnet, while the other of which ends in a singlet ground
state. Then, concentrating on the ferrimagnetic arrangement on a two-leg ladder
which is well indicative of general coupled-chain ferrimagnets, we develop the
spin-wave theory and fully reveal its low-energy structure. We inquire further
into the ferromagnetic aspect of the ferrimagnetic ladder numerically
calculating the sublattice magnetization and the magnetic susceptibility. There
exists a moderate coupling strength between the chains in order to obtain the
most ferromagnetic ferrimagnet.Comment: 10 pages, 7 figures embedded, to be published in J. Phys. Soc. Jpn.
Vol.70, No.5 (2001
Stochastic semiclassical fluctuations in Minkowski spacetime
The semiclassical Einstein-Langevin equations which describe the dynamics of
stochastic perturbations of the metric induced by quantum stress-energy
fluctuations of matter fields in a given state are considered on the background
of the ground state of semiclassical gravity, namely, Minkowski spacetime and a
scalar field in its vacuum state. The relevant equations are explicitly derived
for massless and massive fields arbitrarily coupled to the curvature. In doing
so, some semiclassical results, such as the expectation value of the
stress-energy tensor to linear order in the metric perturbations and particle
creation effects, are obtained. We then solve the equations and compute the
two-point correlation functions for the linearized Einstein tensor and for the
metric perturbations. In the conformal field case, explicit results are
obtained. These results hint that gravitational fluctuations in stochastic
semiclassical gravity have a ``non-perturbative'' behavior in some
characteristic correlation lengths.Comment: 28 pages, RevTeX, no figure
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