Analyses of moisture in polymers and composites

A suitable method for the direct measurement of moisture concentrations after humidity/thermal exposure on state of the art epoxy and polyimide resins and their graphite and glass fiber reinforcements was investigated. Methods for the determination of moisture concentration profiles, moisture diffusion modeling and moisture induced chemical changes were examined. Carefully fabricated, precharacterized epoxy and polyimide neat resins and their AS graphite and S glass reinforced composites were exposed to humid conditions using heavy water (D20), at ambient and elevated temperatures. These specimens were fixtured to theoretically limit the D20 permeation to a unidirectional penetration axis. The analytical techniques evaluated were: (1) laser pyrolysis gas chromatography mass spectrometry; (2) solids probe mass spectrometry; (3) laser pyrolysis conventional infrared spectroscopy; and (4) infrared imaging thermovision. The most reproducible and sensitive technique was solids probe mass spectrometry. The fabricated exposed specimens were analyzed for D20 profiling after humidity/thermal conditioning at three exposure time durations

An analogue of Ryser's Theorem for partial Sudoku squares

In 1956 Ryser gave a necessary and sufficient condition for a partial latin rectangle to be completable to a latin square. In 1990 Hilton and Johnson showed that Ryser's condition could be reformulated in terms of Hall's Condition for partial latin squares. Thus Ryser's Theorem can be interpreted as saying that any partial latin rectangle $R$ can be completed if and only if $R$ satisfies Hall's Condition for partial latin squares. We define Hall's Condition for partial Sudoku squares and show that Hall's Condition for partial Sudoku squares gives a criterion for the completion of partial Sudoku rectangles that is both necessary and sufficient. In the particular case where $n=pq$, $p|r$, $q|s$, the result is especially simple, as we show that any $r \times s$ partial $(p,q)$-Sudoku rectangle can be completed (no further condition being necessary).Comment: 19 pages, 10 figure

Locked oscillator phase modulator, appendix d final report

Design parameters for linear phase modulation of locked oscillato

Pm receiver rf test console, appendix f final rep

Technical description of phase-modulation receiver developed in radio-frequency console progra

Thermally stable laminating resins Final report

Polyimide resin and resin reinforced composite

Nighttime observations of thunderstorm electrical activity from a high altitude airplane

Nocturnal thunderstorms were observed from above and features of cloud structure and lightning which are not generally visible from the ground are discussed. Most, lightning activity seems to be associated with clouds with strong convective cauliflower tops. In both of the storms lightning channels were visible in the clear air above the cloud. It is shown that substances produced by thunderstorm electrical discharges can be introduced directly into the stratosphere. The cause and nature of the discharges above the cloud are not clear. They may be produced by accumulations of space charge in the clear air above the cloud. The discharges may arise solely because of the intense electric fields produced by charges within the cloud. In the latter case the ions introduced by these discharges will increase the electrical conductivity of the air above the cloud and increase the conduction current that flows from the cloud to the electrosphere. More quantitative data at higher resolution may show significant spectral differences between cloud to ground and intracloud strokes. It is shown that electric field change data taken with an electric field change meter mounted in an airplane provide data on lightning discharges from above that are quite similar to those obtained from the ground in the past. The optical signals from dart leaders, from return strokes, and from continuing currents are recognizable, can be used to provide information on the fine structure of lightning, and can be used to distinguish between cloud to ground and intracloud flashes

An experimental feasibility study for the preparation of thermo-oxidatively stable Pyrrone laminates

Synthesis of Pyrrone laminates from sulfone dianhydrid