Properties and Analysis of Thermally Aged Poly(ethylene oxide)

Recent studies have been performed into the use of polyethylene oxide (PEO) as a model system for observing the fundamental effects of adding micro and nano sized fillers to create polymeric composite systems. Many factors contribute to the successful creation of such a composite system, including dispersion of the filler and treatment of the material during creation. For example, while producing thin films of the materials for testing, high temperatures were used for short periods of time in open air to press the samples into small discs. It is well known that prolonged high temperature exposure can alter the chemistry and structure of polymeric materials and that small variations in the original chemistry, such as longer molecular weights or introduction of fillers, can reduce or possibly accelerate this 'ageing' effect. From these previous investigations many property changes were observed during addition of filler or variation of molecular weight, therefore to accurately attribute these changes to a cause the thermal ageing of the material should be observed. This investigation looks at the same 3 molecular weight PEO systems as those used in the previous investigations and analyses them for their vulnerability to thermal ageing. One thermally aged sample is then taken and tested alongside an unaged sample to observe the effects that the process has on the properties. This includes rheology in solution, differential scanning calorimetry (DSC), AC electrical breakdown, dielectric spectroscopy and Fourier transform infra-red (FTIR). By observing the property changes of aged samples it is possible to better understand the thermal ageing process occurring and possibly a way to reduce the effect, along with considering the effect with regard to the behaviour of the previously tested composite samples

The linear rms-flux relation in an Ultraluminous X-ray Source

We report the first detection of a linear correlation between rms variability amplitude and flux in the Ultraluminous X-ray source NGC 5408 X-1. The rms-flux relation has previously been observed in several Galactic black hole X-ray binaries (BHBs), several Active Galactic Nuclei (AGN) and at least one neutron star X-ray binary. This result supports the hypothesis that a linear rms-flux relation is common to all luminous black hole accretion and perhaps even a fundamental property of accretion flows about compact objects. We also show for the first time the cross-spectral properties of the variability of this ULX, comparing variations below and above 1 keV. The coherence and time delays are poorly constrained but consistent with high coherence between the two bands, over most of the observable frequency range, and a significant time delay (with hard leading soft variations). The magnitude and frequency dependence of the lags are broadly consistent with those commonly observed in BHBs, but the direction of the lag is reversed. These results indicate that ULX variability studies, using long X-ray observations, hold great promise for constraining the processes driving ULXs behaviour, and the position of ULXs in the scheme of black hole accretion from BHBs to AGN.Comment: 4 Pages, 3 figures, accepted for publication by MNRAS

Sexuality at the Bar: An Empirical Exploration into the Experiences of LGBT+ Barristers in England & Wales

The Bar of England & Wales is an historic, traditional institution of courtroom advocates and specialist advisers that can trace its origins back to the 13th century. As a field of study, there is comparatively little academic work on barristers. Where work has been done on the Bar, and in relation to diversity at the Bar, this has tended to focus either wholly or primarily on women barristers and suggests patterns of inequality, exclusion and forms of direct and indirect discrimination. Like the other branches of the legal profession in England and Wales, the Bar does not reflect the society it serves. In their world-first research, ‘Sexuality at the Bar’, Mason and Vaughan show a variety of complex practices which govern where (and when and how) LGBT+ members of the Bar feel comfortable being open about their sexuality as well as highlighting a significant number of LGBT+ barristers who have experienced work related bullying and/or discrimination. Their work also suggests an increasing role for Bar-specific LGBT+ networks and the value of LGBT+ role models, both at the Bar and in the judiciary

Visualising London's Suburbs

2 - 4 April 200

Do the suburbs exist? Discovering complexity and specificity in suburban built form

In human geography cities are routinely acknowledged as complex and dynamic built environments. This description is rarely extended to the suburbs, which are generally regarded as epiphenomena of the urbs and therefore of little intrinsic theoretical interest in themselves. This article presents a detailed critique of this widely held assumption by showing how the idea of 'the suburban' as an essentially non-problematic domain has been perpetuated from a range of contrasting disciplinary perspectives, including those that directly address suburban subject matter. The result has been that attempts to articulate the complex social possibilities of suburban space are easily caught between theories of urbanisation that are insensitive to suburban specificity and competing representations of the suburb that rarely move beyond the culturally specific to consider their generic significance. This article proposes that the development of a distinctively suburban theory would help to undermine one-dimensional approaches to the built environment by focusing on the relationship between social organisation and the dynamics of emergent built form

A multi-disciplinary perspective on the built environment: Space Syntax and cartography – the communication challenge

8-11 June 2009

A complete sample of Seyfert galaxies selected at 1/4 keV

We have used the ROSAT Bright Source Catalogue to extract a complete sample of sources selected in the band from 0.1-0.4 keV. This 1/4 keV-selected sample is comprised of 54 Seyfert galaxies, 25 BL Lacertae objects, 4 clusters and 27 Galactic stars or binaries. Seyfert-type galaxies with ``ultrasoft'' X-ray spectra can very often be classed optically as Narrow-line Seyfert 1s (NLS1s). Such objects are readily detected in 1/4 keV surveys; the sample reported here contains 20 NLS1s, corresponding to a 40% fraction of the Seyferts. Optical spectra of the Seyfert galaxies were gathered for correlative analysis, which confirmed the well-known relations between X-ray slope and optical spectral properties (e.g., [O III]/H-beta ratio; Fe II strength, H-beta width). The various intercorrelations are most likely driven, fundamentally, by the shape of the photoionising continuum in Seyfert nuclei. We argue that a steep X-ray spectrum is a better indicator of an ``extreme'' set of physical properties in Seyfert galaxies than is the narrowness of the optical H-beta line. (Abridged)Comment: 17 pages, 4 figures, accepted for publication in MNRA

Extensive X-ray variability studies of NGC 7314 using long XMM-Newton observations

We present a detailed X-ray variability study of the low mass Active Galactic Nuclei (AGN) NGC 7314 using the two newly obtained XMM-Newton observations ($140$ and $130$ ks), together with two archival data sets of shorter duration ($45$ and $84$ ks). The relationship between the X-ray variability characteristics and other physical source properties (such as the black hole mass) are still relatively poorly defined, especially for low-mass AGN. We perform a new, fully analytical, power spectral density (PSD) model analysis method, which will be described in detail in a forthcoming paper, that takes into consideration the spectral distortions, caused by red-noise leak. We find that the PSD in the $0.5-10$ keV energy range, can be represented by a bending power-law with a bend around $6.7\times10^{-5}$ Hz, having a slope of $0.51$ and $1.99$ below and above the bend, respectively. Adding our bend time-scale estimate, to an already published ensemble of estimates from several AGN, supports the idea that the bend time-scale depends linearly only on the black hole mass and not on the bolometric luminosity. Moreover, we find that as the energy range increases, the PSD normalization increases and there is a hint that simultaneously the high frequency slope becomes steeper. Finally, the X-ray time-lag spectrum of NGC 7314 shows some very weak signatures of relativistic reflection, and the energy resolved time-lag spectrum, for frequencies around $3\times10^{-4}$ Hz, shows no signatures of X-ray reverberation. We show that the previous claim about ks time-delays in this source, is simply an artefact induced by the minuscule number of points entering during the time-lag estimation in the low frequency part of the time-lag spectrum (i.e. below $10^{-4}$ Hz).Comment: Accepted for publication in MNRAS. The paper is 21 pages long and contains 15 figures and 3 table