Analyses of moisture in polymers and composites

A suitable method for the direct measurement of moisture concentrations after humidity/thermal exposure on state of the art epoxy and polyimide resins and their graphite and glass fiber reinforcements was investigated. Methods for the determination of moisture concentration profiles, moisture diffusion modeling and moisture induced chemical changes were examined. Carefully fabricated, precharacterized epoxy and polyimide neat resins and their AS graphite and S glass reinforced composites were exposed to humid conditions using heavy water (D20), at ambient and elevated temperatures. These specimens were fixtured to theoretically limit the D20 permeation to a unidirectional penetration axis. The analytical techniques evaluated were: (1) laser pyrolysis gas chromatography mass spectrometry; (2) solids probe mass spectrometry; (3) laser pyrolysis conventional infrared spectroscopy; and (4) infrared imaging thermovision. The most reproducible and sensitive technique was solids probe mass spectrometry. The fabricated exposed specimens were analyzed for D20 profiling after humidity/thermal conditioning at three exposure time durations

An analogue of Ryser's Theorem for partial Sudoku squares

In 1956 Ryser gave a necessary and sufficient condition for a partial latin rectangle to be completable to a latin square. In 1990 Hilton and Johnson showed that Ryser's condition could be reformulated in terms of Hall's Condition for partial latin squares. Thus Ryser's Theorem can be interpreted as saying that any partial latin rectangle $R$ can be completed if and only if $R$ satisfies Hall's Condition for partial latin squares. We define Hall's Condition for partial Sudoku squares and show that Hall's Condition for partial Sudoku squares gives a criterion for the completion of partial Sudoku rectangles that is both necessary and sufficient. In the particular case where $n=pq$, $p|r$, $q|s$, the result is especially simple, as we show that any $r \times s$ partial $(p,q)$-Sudoku rectangle can be completed (no further condition being necessary).Comment: 19 pages, 10 figure

Locked oscillator phase modulator, appendix d final report

Design parameters for linear phase modulation of locked oscillato

Pm receiver rf test console, appendix f final rep

Technical description of phase-modulation receiver developed in radio-frequency console progra

An inelastic analysis of a welded aluminum joint

Butt-weld joints are most commonly designed into pressure vessels which then become as reliable as the weakest increment in the weld chain. In practice, weld material properties are determined from tensile test specimen and provided to the stress analyst in the form of a stress versus strain diagram. Variations in properties through the thickness of the weld and along the width of the weld have been suspect but not explored because of inaccessibility and cost. The purpose of this study is to investigate analytical and computational methods used for analysis of welds. The weld specimens are analyzed using classical elastic and plastic theory to provide a basis for modeling the inelastic properties in a finite-element solution. The results of the analysis are compared to experimental data to determine the weld behavior and the accuracy of prediction methods. The weld considered in this study is a multiple-pass aluminum 2219-T87 butt weld with thickness of 1.40 in. The weld specimen is modeled using the finite-element code ABAQUS. The finite-element model is used to produce the stress-strain behavior in the elastic and plastic regimes and to determine Poisson's ratio in the plastic region. The value of Poisson's ratio in the plastic regime is then compared to experimental data. The results of the comparisons are used to explain multipass weld behavior and to make recommendations concerning the analysis and testing of welds

Thermally stable laminating resins Final report

Polyimide resin and resin reinforced composite