Time-resolved characterization of a pulsed discharge in a stationary bubble

In recent years, plasma generation in water has been proposed for the application of water treatment. The process efficiency is believed to be improved by the introduction of bubbles in the plasma active region. For further optimization, the initiating and developmental mechanisms of plasma inside bubbles need to be understood to a greater extent. In order to meet this necessity, we investigated pulsed electrical discharge inside a stationary bubble in water. This paper deals with the evolution of the discharge and of the bubble shape during discharge, investigated by electrical characterization and fast imaging. Only several microseconds after the application of the voltage pulse, plasma light is observed. Different phases are observed during plasma formation. The plasma is strongest at the bubble surface, causing the surrounding water to evaporate. This leads to both the formation of propagating streamers into the water and the expansion and collapse of the bubble. These observations show that plasma inside a bubble has the strongest activity at the bubble surface, making it attractive for water treatment

Hydrogen peroxide generation by DC and pulsed underwater discharge in air bubbles

The generation of H(2)O(2) in underwater discharge in air bubbles is studied with consideration of the influence of electrodes polarity, input power, solution conductivity and the inter-electrode distance. The efficiency of hydrogen peroxide generation strongly depends on the polarity, input power and the inter-electrode distance. Discharges in air bubbles with water as a cathode have significantly higher energy yield of hydrogen peroxide in comparison with negative DC or pulsed discharges. The generation of hydrogen peroxide by DC discharge increases with decrease in the inter-electrode distance, but it is opposite for pulsed discharges. Different efficiency of H(2)O(2) production is explained based on physical processes which result to formation of OH radicals

Under water discharge in bubbles in very low conductive solutions

This contribution presents experimental results obtained with underwater electric discharge created in rising gas bubbles. This discharge configuration is relatively new, and combines both gas and liquid phase discharges. The properties and mechanism of bubble discharge generation were investigated using a single pulsed high voltage. The electric discharge was generated in a pin-to-plate electrode configuration submerged in deionized water with conductivity of 2.0–5.0 μS/m. The gas bubbles were formed by injecting the gas through a glass filter disc at the bottom of the water tank. Air and helium were used as inlet gas. A spark gap pulse generator triggered the single negative high voltage pulses with rise times below 10 ns and peak voltages of 15–20 kV. The bubble position at the moment of high voltage application was accidental. The measured spectra were qualitatively reproducible, but significant quantitative differences were observed. We observed two types of discharge inside the bubble: delayed and direct spark discharge. The emission spectra of these two discharge kinds were qualitatively very similar

Applications of plasma-liquid systems : a review

Plasma-liquid systems have attracted increasing attention in recent years, owing to their high potential in material processing and nanoscience, environmental remediation, sterilization, biomedicine, and food applications. Due to the multidisciplinary character of this scientific field and due to its broad range of established and promising applications, an updated overview is required, addressing the various applications of plasma-liquid systems till now. In the present review, after a brief historical introduction on this important research field, the authors aimed to bring together a wide range of applications of plasma-liquid systems, including nanomaterial processing, water analytical chemistry, water purification, plasma sterilization, plasma medicine, food preservation and agricultural processing, power transformers for high voltage switching, and polymer solution treatment. Although the general understanding of plasma-liquid interactions and their applications has grown significantly in recent decades, it is aimed here to give an updated overview on the possible applications of plasma-liquid systems. This review can be used as a guide for researchers from different fields to gain insight in the history and state-of-the-art of plasma-liquid interactions and to obtain an overview on the acquired knowledge in this field up to now

Influence of air diffusion on the OH radicals and atomic O distribution in an atmospheric Ar (bio)plasma jet

Treatment of samples with plasmas in biomedical applications often occurs in ambient air. Admixing air into the discharge region may severely affect the formation and destruction of the generated oxidative species. Little is known about the effects of air diffusion on the spatial distribution of OH radicals and O atoms in the afterglow of atmospheric-pressure plasma jets. In our work, these effects are investigated by performing and comparing measurements in ambient air with measurements in a controlled argon atmosphere without the admixture of air, for an argon plasma jet. The spatial distribution of OH is detected by means of laser-induced fluorescence diagnostics (LIF), whereas two-photon laser-induced fluorescence (TALIF) is used for the detection of atomic O. The spatially resolved OH LIF and O TALIF show that, due to the air admixture effects, the reactive species are only concentrated in the vicinity of the central streamline of the afterglow of the jet, with a characteristic discharge diameter of similar to 1.5 mm. It is shown that air diffusion has a key role in the recombination loss mechanisms of OH radicals and atomic O especially in the far afterglow region, starting up to similar to 4mm from the nozzle outlet at a low water/oxygen concentration. Furthermore, air diffusion enhances OH and O production in the core of the plasma. The higher density of active species in the discharge in ambient air is likely due to a higher electron density and a more effective electron impact dissociation of H2O and O-2 caused by the increasing electrical field, when the discharge is operated in ambient air

Degradation of AB25 dye in liquid medium by atmospheric pressure non-thermal plasma and plasma combination with photocatalyst TiO2

In this work, degradation of the anthraquinonic dye Acid Blue 25 by non-thermal plasma at atmospheric pressure with and without photocatalyst is investigated. Titanium dioxide (TiO2) is used as a photocatalyst. The dye degradation by plasma in the presence of TiO2 is investigated as a function of TiO2 concentration, dye concentration and pH. The degradation rate is higher in acidic solutions with pH of 2 to 4.3, especially at pH 2, and decreases to 0.38 mg L-1 min(-1) with the increase of pH from 2 to 5.65. A similar effect is observed in basic media, where a higher degradation rate is found at pH = 10.3. The degradation rate increases in the presence of TiO2 compared to the discharge without photocatalysis. The results show that the degradation of the dye increases in the presence of TiO2 until the catalyst load reaches 0.5 g L-1 after which the suppression of AB25 degradation is observed. The results indicate that the tested advanced oxidation processes are very effective for the degradation of AB25 in aqueous solutions