1,285 research outputs found
Bistable hysteresis and resistance switching in hydrogen gold junctions
Current-voltage characteristics of H2-Au molecular junctions exhibit
intriguing steps around a characteristic voltage of 40 mV. Surprisingly, we
find that a hysteresis is connected to these steps with a typical time scale >
10 ms. This time constant scales linearly with the power dissipated in the
junction beyond an ofset power P_s = IV_s. We propose that the hysteresis is
related to vibrational heating of both the molecule in the junction and a set
of surrounding hydrogen molecules. Remarkably, we can engineer our junctions
such that the hysteresis' characteristic time becomes >days. We demonstrate
that reliable switchable devices can be built from such junctions.Comment: Submitted to Phys. Rev. Let
Bulk and Surface Nucleation Processes in Ag2S Conductance Switches
We studied metallic Ag formation inside and on the surface of Ag2S thin
films, induced by the electric field created with a STM tip. Two clear regimes
were observed: cluster formation on the surface at low bias voltages, and full
conductance switching at higher bias voltages (V > 70mV). The bias voltage at
which this transition is observed is in agreement with the known threshold
voltage for conductance switching at room temperature. We propose a model for
the cluster formation at low bias voltage. Scaling of the measured data with
the proposed model indicates that the process takes place near steady state,
but depends on the STM tip geometry. The growth of the clusters is confirmed by
tip retraction measurements and topography scans. This study provides improved
understanding of the physical mechanisms that drive conductance switching in
solid electrolyte memristive devices.Comment: In press for PR
Opportunities and limitations of transition voltage spectroscopy: a theoretical analysis
In molecular charge transport, transition voltage spectroscopy (TVS) holds
the promise that molecular energy levels can be explored at bias voltages lower
than required for resonant tunneling. We investigate the theoretical basis of
this novel tool, using a generic model. In particular, we study the length
dependence of the conducting frontier orbital and of the 'transition voltage'
as a function of length. We show that this dependence is influenced by the
amount of screening of the electrons in the molecule, which determines the
voltage drop to be located at the contacts or across the entire molecule. We
observe that the transition voltage depends significantly on the length, but
that the ratio between the transition voltage and the conducting frontier
orbital is approximately constant only in strongly screening (conjugated)
molecules. Uncertainty about the screening within a molecule thus limits the
predictive power of TVS. We furthermore argue that the relative length
independence of the transition voltage for non-conjugated chains is due to
strong localization of the frontier orbitals on the end groups ensuring binding
of the rods to the metallic contacts. Finally, we investigate the
characteristics of TVS in asymmetric molecular junctions. If a single level
dominates the transport properties, TVS can provide a good estimate for both
the level position and the degree of junction asymmetry. If more levels are
involved the applicability of TVS becomes limited.Comment: 8 pages, 12 figure
Electrical conductance of molecular junctions by a robust statistical analysis
We propose an objective and robust method to extract the electrical
conductance of single molecules connected to metal electrodes from a set of
measured conductance data. Our method roots in the physics of tunneling and is
tested on octanedithiol using mechanically controllable break junctions. The
single molecule conductance values can be deduced without the need for data
selection.Comment: 4 figure
Multidetector CT in children: current concepts and dose reduction strategies
The recent technical development of multidetector CT (MDCT) has contributed to a substantial increase in its diagnostic applications and accuracy in children. A major drawback of MDCT is the use of ionising radiation with the risk of inducing secondary cancer. Therefore, justification and optimisation of paediatric MDCT is of great importance in order to minimise these risks (“as low as reasonably achievable” principle). This review will focus on all technical and non-technical aspects relevant for paediatric MDCT optimisation and includes guidelines for radiation dose level-based CT protocols
The role of Joule heating in the formation of nanogaps by electromigration
We investigate the formation of nanogaps in gold wires due to
electromigration. We show that the breaking process will not start until a
local temperature of typically 400 K is reached by Joule heating. This value is
rather independent of the temperature of the sample environment (4.2-295 K).
Furthermore, we demonstrate that the breaking dynamics can be controlled by
minimizing the total series resistance of the system. In this way, the local
temperature rise just before break down is limited and melting effects are
prevented. Hence, electrodes with gaps < 2 nm are easily made, without the need
of active feedback. For optimized samples, we observe quantized conductance
steps prior the gap formation.Comment: including 7 figure
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