Preliminary results on the Extinction and Night Sky Background in UBV on La Silla and ALMA site

We report on measurements of the extinction in the U, B & V bands and of the NSB (Night Sky Background) during 2 dark periods on La Silla Observatory and at 4000-5000m on the ALMA site using an UV optimized 25 cm portable telescope.Comment: 9 pages, 15 figure

Overtones of interlayer shear modes in the phonon-assisted emission spectrum of hexagonal boron nitride

We address the intrinsic optical properties of hexagonal boron nitride in deep ultraviolet. We show that the fine structure of the phonon replicas arises from overtones involving up to six low-energy interlayer shear modes. These lattice vibrations are specific to layered compounds since they correspond to the shear rigid motion between adjacent layers, with a characteristic energy of about 6-7 meV. We obtain a quantitative interpretation of the multiplet observed in each phonon replica under the assumption of a cumulative Gaussian broadening as a function of the overtone index, and with a phenomenological line broadening taken identical for all phonon types. We show from our quantitative interpretation of the full emission spectrum above 5.7 eV that the energy of the involved phonon mode is 6.8±0.5 meV, in excellent agreement with temperature-dependent Raman measurements of the low-energy interlayer shear mode in hexagonal boron nitride. We highlight the unusual properties of this material where the optical response is tailored by the phonon group velocities in the middle of the Brillouin zone. © 2017 American Physical Society.Peer reviewe

Boron and nitrogen isotope effects on hexagonal boron nitride properties

The unique physical, mechanical, chemical, optical, and electronic properties of hexagonal boron nitride (hBN) make it a promising two-dimensional material for electronic, optoelectronic, nanophotonic, and quantum devices. Here we report on the changes in hBN's properties induced by isotopic purification in both boron and nitrogen. Previous studies on isotopically pure hBN have focused on purifying the boron isotope concentration in hBN from its natural concentration (approximately 20 at$\%$ $^{10}$B, 80 at$\%$ $^{11}$B) while using naturally abundant nitrogen (99.6 at$\%$ $^{14}$N, 0.4 at$\%$ $^{15}$N), i.e. almost pure $^{14}$N. In this study, we extend the class of isotopically-purified hBN crystals to $^{15}$N. Crystals in the four configurations, namely h$^{10}$B$^{14}$N, h$^{11}$B$^{14}$N, h$^{10}$B$^{15}$N, and h$^{11}$B$^{15}$N, were grown by the metal flux method using boron and nitrogen single isotope ($>99\%$) enriched sources, with nickel plus chromium as the solvent. In-depth Raman and photoluminescence spectroscopies demonstrate the high quality of the monoisotopic hBN crystals with vibrational and optical properties of the $^{15}$N-purified crystals at the state of the art of currently available $^{14}$N-purified hBN. The growth of high-quality h$^{10}$B$^{14}$N, h$^{11}$B$^{14}$N, h$^{10}$B$^{15}$N, and h$^{11}$B$^{15}$N opens exciting perspectives for thermal conductivity control in heat management, as well as for advanced functionalities in quantum technologies.Comment: 13 pages, 7 figure

Direct band-gap crossover in epitaxial monolayer boron nitride

Hexagonal boron nitride is a large band-gap insulating material which complements the electronic and optical properties of graphene and the transition metal dichalcogenides. However, the intrinsic optical properties of monolayer boron nitride remain largely unexplored. In particular, the theoretically expected crossover to a direct-gap in the limit of the single monolayer is presently not con_rmed experimentally. Here, in contrast to the technique of exfoliating few-layer 2D hexagonal boron nitride, we exploit the scalable approach of high-temperature molecular beam epitaxy to grow high-quality monolayer boron nitride on graphite substrates. We combine deep-ultraviolet photoluminescence and reectance spectroscopy with atomic force microscopy to reveal the presence of a direct gap of energy 6.1 eV in the single atomic layers, thus con_rming a crossover to direct gap in the monolayer limit

Isoelectronic traps in heavily doped GaAs:(In,N)

International audienceGaAs samples doped with low indium and nitrogen contents were investigated by continuous-wave (CWPL) and time-resolved photoluminescence (TRPL) at low temperature (10 K). The simultaneous incorporation of doping amounts of both indium and nitrogen elements in GaAs creates new isoelectronic traps that are not present in indium-free GaAs:N. These traps are built from nitrogen-related defects of GaAs:N now perturbated by one additional indium atom. They are believed to involve a preferential orientation of the In atom and of one N atom in near-neighbor positions. The experiments are consistent with the assumption that the clusters are perturbed by a single In atom but that a definitive assignment cannot be given without addition theoretical modeling. Optical feature characteristics of the exciton bound to these kinds of isoelectronic traps are reported: (i) the exciton fine structure with dipole-forbidden and dipole-allowed states and (ii) the train of phonon replicas that is typical of isoelectronic traps. The observation of the tine structure of the trapped excitons is made possible because of the thermodynamic equilibrium between the two populations of excitons (dipole-allowed and dipole-forbidden states) in the conditions of our measurement. It gives us a direct measurement of the short-range exchange interaction (∼0.7 meV). The TRPL experiments allow us to characterize the exciton recombination dynamics for the different isoelectronic traps and notably the transfer mechanisms of excitons among these various traps

Photo-induced droop in blue to red light emitting InGaN/GaN single quantum wells structures

International audienceThe variation of the internal quantum efficiency (IQE) of single InGaN quantum well structures emitting from blue to red is studied as a function of the excitation power density and the temperature. By changing the well width, the indium content, and adding a strain compensation AlGaN layer, we could tune the intrinsic radiative recombination rate by changing the quantum confined Stark effect, and we could modify the carrier localization. Strong quantum confined Stark effect and carrier localization induce an increase in the carrier density and then favor Auger non-radiative recombination in the high excitation range. In such high excitation conditions with efficient Auger recombination, the variation of the IQE with the photo-excitation density P is ruled by a universal power law independent of the design: IQE = IQEMAX – a log10P with a close to 1/3. The temperature dependences of the different recombination mechanisms are determined. At low temperature, both quantum confined Stark effect and carrier localization trigger electron-electron repulsions and therefore the onset of the Auger effect. The increase in the value of coefficient C with changing temperature reveals indirect Auger recombination that relates to the interactions of the carriers with other phonons than the longitudinal optical one

Observation and modeling of the time-dependent descreening of internal electric field in a wurtzite GaN/Al0.15Ga0.85N quantum well after high photoexcitation

We use the intense, 5-ns-long, excitation pulses provided by the fourth harmonic of a neodymium-doped yttrium aluminum garnet (Nd:YAG) laser to induce a strong high-energy shift of the photoluminescence of a 7.8-nm-wide GaN/Al0.15Ga0.85N single quantum well. We follow the complex relaxation dynamics of the energy and of the intensity of this emission, by using a time-resolved photoluminescence setup. We obtain excellent agreement between our experimental results and those of our finite-element modeling of the time-dependent energy and oscillator strength. The model, based on a self-consistent solution of the Schrodinger and Poisson equations, accounts for the three important sources of energy shifts: (1) the screening of the electric field present along the growth axis of the well, by accumulation of electron-hole dipoles, (2) the band-gap renormalization induced by many-body interactions, and (3) the filling of the conduction and valence bands