Hubungan antara Sikap Konsumen dan Norma Subjektif dengan Minat Nasabah untuk Bertransaksi Logam Mulia di Pegadaian Syariah (Studi Kasus : Pegadaian Syariah Cabang Kramat Raya, Jakarta )

The purpose of this study was to determine whether the belief factor, the evaluation results, subjective norm and motivation have a correlation consumer interest in “logam mulia” sharia pawnshop transaction. Analytical techniques used in this study is correlation. Samples used in this study as many as 91 respondents. The results of this study showed that consumer interest to conduct transactions in “logam mulia” sharia pawnshop transaction is not related to his conviction, while the evaluation of results, subjective norms, and motivation have a positive relationship with consumer interest in “logam mulia” sharia pawnshop transaction

Influence of an Internal Trifluoromethyl Group on the Rhodium(II)-Catalyzed Reactions of Vinyldiazocarbonyl Compounds

Incorporation of a trifluoromethyl group into the structure of 4-(alkoxycarbonyl)­vinyldiazocarbonyl compounds greatly decreases the tendency of the carbenoid intermediates formed during Rh­(II)-catalyzed reactions to undergo <i>intermolecular</i> processes. Instead, they are prone to experience <i>intramolecular</i> [1,5]- and [1,3]-electrocyclizations to produce reactive cyclopropenes and furans, and these are capable of further transformations

Influence of an Internal Trifluoromethyl Group on the Rhodium(II)-Catalyzed Reactions of Vinyldiazocarbonyl Compounds

Incorporation of a trifluoromethyl group into the structure of 4-(alkoxycarbonyl)­vinyldiazocarbonyl compounds greatly decreases the tendency of the carbenoid intermediates formed during Rh­(II)-catalyzed reactions to undergo <i>intermolecular</i> processes. Instead, they are prone to experience <i>intramolecular</i> [1,5]- and [1,3]-electrocyclizations to produce reactive cyclopropenes and furans, and these are capable of further transformations

Influence of an Internal Trifluoromethyl Group on the Rhodium(II)-Catalyzed Reactions of Vinyldiazocarbonyl Compounds

Incorporation of a trifluoromethyl group into the structure of 4-(alkoxycarbonyl)­vinyldiazocarbonyl compounds greatly decreases the tendency of the carbenoid intermediates formed during Rh­(II)-catalyzed reactions to undergo <i>intermolecular</i> processes. Instead, they are prone to experience <i>intramolecular</i> [1,5]- and [1,3]-electrocyclizations to produce reactive cyclopropenes and furans, and these are capable of further transformations

Light-Induced Reactions of Diazotetrahydrofuranone without Elimination of Nitrogen: Experimental and Mechanistic Study

The energies and lifetimes of the excited states (S₁, S₂, S₅, T₁) of a diazotetrahydrofuranone were determined using experimental and computational methods. It was shown that direction of the diazoketone photochemical transformations without elimination of nitrogen is determined by multiplicity and energy of the excited state, generated by UV irradiation of diazo compound: isomerization to α-ketodiazirine proceeds from the singlet S₁ state, whereas the alternative process of C–H insertion with hydrazone formation occurs through the triplet T₁ state. The most probable excited state that leads to elimination of nitrogen and Wolff rearrangement is one of the highest singlet excited states of diazotetrahydrofuranone