Photoelectrocatalytic performances of nanostructured/decorated TiO 2 electrodes: Effect of wavelength and cell configuration

The behaviour of TiO2 based electrodes was investigated during the photoelectrocatalytic water splitting process. TiO2 nanotubes and compact oxide structures were obtained by electrochemical oxidation of Ti foils. A subsequent hydrothermal process carried out at both the nanotubular and compact oxide structures allowed decorating the structure by TiO2 nanoparticles. The synthesized TiO2 samples worked as photoanodes both in a bulk three electrode cell and in a thin gap cell. The results from measurements of the photocurrent and from electrochemical impedance spectroscopy were used to highlight a combined effect of the wavelength of the incident light and the kind of cell configuration, on the global performance of the systems. The results indicate that the decoration process does not result only in a simple increase of the specific surface, but it also determines a different concentration of the bulk and superficial sites in the electrode. The different response of the sites at different wavelengths, along with the accessibility of the electrolyte to the porous structure are evocated to justify the experimental behaviour observed

The Neutral Hydrogen Distribution in Merging Galaxies: Differences between Stellar and Gaseous Tidal Morphologies

We have mapped the neutral atomic gas (HI) in the three disk-disk merger systems NGC 520, Arp 220, and Arp 299. These systems differ from the majority of the mergers mapped in HI, in that their stellar and gaseous tidal features do not coincide. In particular, they exhibit large stellar tidal features with little if any accompanying neutral gas and large gas-rich tidal features with little if any accompanying starlight. On smaller scales, there are striking anti-correlations where the gaseous and stellar tidal features appear to cross. We explore several possible causes for these differences, including dust obscuration, ram pressure stripping, and ionization effects. No single explanation can account for all of the observed differences. The fact that each of these systems shows evidence for a starburst driven superwind expanding in the direction of the most striking anti-correlations leads us to suggest that the superwind is primarily responsible for the observed differences, either by sweeping the features clear of gas via ram pressure, or by excavating a clear sightline towards the starburst and allowing UV photons to ionize regions of the tails.Comment: 16 pages, 5 figures, uses emulateapj.sty. To appear in the March 2000 issue of AJ. Version with full resolution figures is available via http://www.cv.nrao.edu/~jhibbard/HIdisp/HIdisp.htm

Inspire

In lieu of an abstract, below is the essay\u27s first paragraph. Writing about inspiration is a daunting task, not the least because the word itself has been overused to the point of oblivion. The temptation to include wonderful anecdotes of kind acts is great, but seems somehow to just borrow others’ inspiration. Works of art, music and literature are described as “inspired,” as are our responses to them. Clothiers, the auto industry, even furnishing gurus claim inspiration as their products’ genesis. Even broadcast news is compelled to include inspiring moments for their viewers by highlighting members of the community (or the nation or globe) who have done more, shared more, given more of themselves in an uncommon manner or for an unusual cause. These can bring a tear or a smile, but rarely do they truly inspire, in the sense of prompting similar action or commitment. Is this the true significance of the word, or has that been thoroughly obfuscated by its easy application to those caught in the midst of any emotional situation

Teacher Malpractice

Over the years, many classroom teachers in public schools have assumed\u27that as employees of local school boards, they were not subject to tort liability for injuries suffered by their students. Only those teachers who have found themselves a party to litigation involving an injured student ever fully recognized just how legally vulnerable teachers are to such actions

NLO Corrections to the kernel of the BKP-equations

We present results for the NLO kernel of the BKP equations for composite states of three reggeized gluons in the Odderon channel, both in QCD and in N=4 SYM. The NLO kernel consists of the NLO BFKL kernel in the color octet representation and the connected $3\to3$ kernel, computed in the tree approximation.Comment: 28 pages, 7 figure

The Wolf-Rayet population of Westerlund 1

New NTT/SOFI near-IR narrow-band imaging and spectroscopy reveals an additional four Wolf-Rayet (WR) stars in the massive cluster Westerlund 1, bringing the total WR population to 24. Sixteen of the WR stars in Wd1 have been classified WN5–11, while eight are WC8–9. An observed WR to RSG/YHG ratio of ∼3 suggests an age of 4.5–5.0 Myr, with WR stars descended from 40–55MSolar progenitors. On the basis of dust and hard X-ray emission, we estimate that 40–65% are probable members of massive star binary systems